A Luminescent Thermometer Based on Linearly Thermo-responsive Copolymer and Polyoxometalates

Jin-Long Zhang; Jun-Yan Tan; Xin-Hua Wan; Jie Zhang

doi:10.1007/s10118-019-2287-z

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A Luminescent Thermometer Based on Linearly Thermo-responsive Copolymer and Polyoxometalates

ARTICLE | Updated：2021-02-18

- A Luminescent Thermometer Based on Linearly Thermo-responsive Copolymer and Polyoxometalates
- Chinese Journal of Polymer Science Vol. 37, Issue 11, Pages: 1113-1118(2019)
- Affiliations：
  
  Beijing National Laboratory for Molecular Sciences, Key Laboratory of Polymer Chemistry and Physics of Ministry of Education, Center for Soft Matter Science and Engineering, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China
- Author bio：
  
  xhwan@pku.edu.cn (X.H.W.)
  jz10@pku.edu.cn (J.Z.)
- Funds：
- DOI：10.1007/s10118-019-2287-z
  CLC：
- Received：08 March 2019，
  
  Revised：2019-1-1，
  
  Accepted：18 April 2019，
  
  Online First：19 June 2019，
  
  Published：2019-11
- Accepted：
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Zhang, J. L.; Tan, J. Y.; Wan, X. H.; Zhang, J. A luminescent thermometer based on linearly thermo-responsive copolymer and polyoxometalates. Chinese J. Polym. Sci. 2019, 37, 1113–1118.

Jin-Long Zhang, Jun-Yan Tan, Xin-Hua Wan, et al. A Luminescent Thermometer Based on Linearly Thermo-responsive Copolymer and Polyoxometalates[J]. Chinese Journal of Polymer Science, 2019, 37(11): 1113-1118.
Zhang, J. L.; Tan, J. Y.; Wan, X. H.; Zhang, J. A luminescent thermometer based on linearly thermo-responsive copolymer and polyoxometalates. Chinese J. Polym. Sci. 2019, 37, 1113–1118. DOI： 10.1007/s10118-019-2287-z.

Jin-Long Zhang, Jun-Yan Tan, Xin-Hua Wan, et al. A Luminescent Thermometer Based on Linearly Thermo-responsive Copolymer and Polyoxometalates[J]. Chinese Journal of Polymer Science, 2019, 37(11): 1113-1118. DOI： 10.1007/s10118-019-2287-z.

摘要

Abstract

A novel switchable luminescent thermometer based on thermo-responsive triblock copolymer poly(ethylene glycol)-

-poly(acrylamide-

-acrylonitrile-

-dimethylaminoethylmethacrylate) (PEO

113

-P(AAm

264

-AN

112

-DMA

)) and Eu-containing polyoxometalate (Eu-POM) was successfully constructed. The copolymer synthesized by RAFT exhibited a linear response to temperature variations in aqueous media

which was quite different from the uncharged copolymer P(AAm-

-AN) having a specific upper critical solution temperature (UCST). Eu-POM was surrounded around thermo-responsive blocks through electrostatic interactions

and its luminescence could be finely tuned due to the sensitivity of copolymer to the temperature variation. In cold water

POMs were trapped in highly hydrophobic cores

exhibiting an intense emission. With the upraising of temperature

the emission intensity presented a gradual decrease and showed a linear correlation with temperature. When the complex solution cooled down

the luminescence could also be perfectly restored. This temperature-luminescence correlation could be held for numerous trials

showing a potential application in thermometer.

关键词

Keywords

references

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