Synthesis and Properties of Reversible Disulfide Bond-based Self-healing Polyurethane with Triple Shape Memory Properties

Han Jia; Kun Chang; Shu-Ying Gu

doi:10.1007/s10118-019-2268-2

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Synthesis and Properties of Reversible Disulfide Bond-based Self-healing Polyurethane with Triple Shape Memory Properties

ARTICLE | Updated：2021-02-18

- Synthesis and Properties of Reversible Disulfide Bond-based Self-healing Polyurethane with Triple Shape Memory Properties
- Chinese Journal of Polymer Science Vol. 37, Issue 11, Pages: 1119-1129(2019)
- Affiliations：
  
  a.Department of Polymeric Materials, School of Materials Science and Engineering, Tongji University, Shanghai 201804, China
  b.Key Laboratory of Advanced Civil Engineering Materials, Ministry of Education, Tongji University, Shanghai 201804, China
- Author bio：
  
  gushuying@tongji.edu.cn
- Funds：
- DOI：10.1007/s10118-019-2268-2
  CLC：
- Received：28 February 2019，
  
  Revised：2019-3-30，
  
  Accepted：01 April 2019，
  
  Online First：21 May 2019，
  
  Published：2019-11
- Accepted：
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Jia, H.; Chang, K.; Gu, S. Y. Synthesis and properties of reversible disulfide bond-based self-healing polyurethane with triple shape memory properties. Chinese J. Polym. Sci. 2019, 37, 1119–1129.

Han Jia, Kun Chang, Shu-Ying Gu. Synthesis and Properties of Reversible Disulfide Bond-based Self-healing Polyurethane with Triple Shape Memory Properties[J]. Chinese Journal of Polymer Science, 2019, 37(11): 1119-1129.
Jia, H.; Chang, K.; Gu, S. Y. Synthesis and properties of reversible disulfide bond-based self-healing polyurethane with triple shape memory properties. Chinese J. Polym. Sci. 2019, 37, 1119–1129. DOI： 10.1007/s10118-019-2268-2.

Han Jia, Kun Chang, Shu-Ying Gu. Synthesis and Properties of Reversible Disulfide Bond-based Self-healing Polyurethane with Triple Shape Memory Properties[J]. Chinese Journal of Polymer Science, 2019, 37(11): 1119-1129. DOI： 10.1007/s10118-019-2268-2.

摘要

Abstract

A reversible disulfide bond-based self-healing polyurethane with triple shape memory properties was prepared by chain extending of random copolymer poly(lactide-

-caprolactone) (PCLA)

hexamethylene diisocyanate (HDI)

polytetrahydrofuran (PTMEG)

and 4

4′-aminophenyl disulfide. The chemical structures were characterized using

H nuclear magnetic resonance (

H-NMR) spectroscopy

Fourier transform infrared spectroscopy (FTIR)

and gel permeation chromatography (GPC). The thermal properties

self-healing properties

triple-shape memory effect

and quantitative shape memory response were evaluated by differential scanning calorimetry (DSC)

tensile tests

two-step programming process thermal mechanical experiments

and subsequent progressive thermal recovery. The self-healing mechanism and procedures were investigated using polarizing optical microscopy (POM) and an optical profiler. It was concluded that self-healing properties (up to 60%) and triple-shape memory properties around 35 and 50 °C (with shape fixation ratios of 94.3% and 98.3%

shape recovery ratios of 76.6% and 85.1%

respectively) were integrated to the shape memory polyurethane. As-prepared polyurethane is expected to have potential applications in multi-shape coatings

films

and step-by-step deploying structures.

关键词

Keywords

references

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