Synthesis and Physico-chemical Properties of (Co)polymers of 2-[(2<italic style="font-style: italic">E</italic>)-1-methyl-2-buten-1-yl]aniline and Aniline

A. Andriianova; A. Shigapova; Y. Biglova; R. Salikhov; I. Abdrakhmanov; A. Mustafin

doi:10.1007/s10118-019-2261-9

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Synthesis and Physico-chemical Properties of (Co)polymers of 2-[(2E)-1-methyl-2-buten-1-yl]aniline and Aniline

ARTICLE | Updated：2021-02-18

- Synthesis and Physico-chemical Properties of (Co)polymers of 2-[(2E)-1-methyl-2-buten-1-yl]aniline and Aniline
- Chinese Journal of Polymer Science Vol. 37, Issue 8, Pages: 774-782(2019)
- Affiliations：
  
  a.Ufa Institute of Chemistry, Russian Academy of Sciences, October Av, 71, Ufa, 450054, Russia
  b.Bashkir State University, Z. Validi St, 32, Ufa, 450076, Russia
- Author bio：
  
  an.chem17@gmail.com
- Funds：
- DOI：10.1007/s10118-019-2261-9
  CLC：
- Received：16 January 2019，
  
  Revised：2019-3-1，
  
  Accepted：21 March 2019，
  
  Online First：08 May 2019，
  
  Published：2019-08
- Accepted：
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Citation: Andriianova, A.; Shigapova, A.; Biglova, Y.; Salikhov, R.; Abdrakhmanov, I.; Mustafin, A. Synthesis and physico-chemical properties of (co)polymers of 2-[(2, E,)-1-methyl-2-buten-1-yl]aniline and aniline. Chinese J. Polym. Sci. 2019, 37, 774–782

A. Andriianova, A. Shigapova, Y. Biglova, et al. Synthesis and Physico-chemical Properties of (Co)polymers of 2-[(2E)-1-methyl-2-buten-1-yl]aniline and Aniline[J]. Chinese Journal of Polymer Science, 2019, 37(8): 774-782. DOI: 10.1007/s10118-019-2261-9.
Citation: Andriianova, A.; Shigapova, A.; Biglova, Y.; Salikhov, R.; Abdrakhmanov, I.; Mustafin, A. Synthesis and physico-chemical properties of (co)polymers of 2-[(2, E,)-1-methyl-2-buten-1-yl]aniline and aniline. Chinese J. Polym. Sci. 2019, 37, 774–782 DOI： 10.1007/s10118-019-2261-9.

A. Andriianova, A. Shigapova, Y. Biglova, et al. Synthesis and Physico-chemical Properties of (Co)polymers of 2-[(2E)-1-methyl-2-buten-1-yl]aniline and Aniline[J]. Chinese Journal of Polymer Science, 2019, 37(8): 774-782. DOI: 10.1007/s10118-019-2261-9. DOI：

摘要

Abstract

A new soluble polymer on 2-[(2

)-1-methyl-2-buten-1-yl]aniline and its copolymers with aniline basis have been synthesized in various molar ratios. For all samples

the electrical conductivity

morphology

solubility

electrochemical properties

as well as spectral and molecular mass characteristics have been studied

and a comparative analysis with polyaniline has been carried out. The substituent introduced into the aniline aromatic ring significantly improves the solubility in typical organic solvents of a high molecular weight product. The morphology of the test compounds depends on the co-monomer ratio. As the content of the substituted aniline in the initial mixture increases

the morphology of the polymer changes from the inherent polyaniline fibrous microstructure to the globular one with irregular substituted polyaniline shapes and sizes. Electrochemical study of the samples revealed that the higher the oxidation potential

the wider the band gap (ranging from 2.00 to 2.15). The electrical conductivity decreases in proportion to the increase in the substituted aniline concentration of the initial co-monomer mixture and amounts to 12.5–35.7 × 10

nSm.

关键词

Keywords

references

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Synthesis and Physico-chemical Properties of (Co)polymers of 2-[(2E)-1-methyl-2-buten-1-yl]aniline and Aniline

DOI：10.1007/s10118-019-2261-9

摘要

Abstract

关键词

Keywords

references