Fabrication of 6FDA-HFBAPP Polyimide Asymmetric Hollow Fiber Membranes and Their CO<sub>2</sub>/CH<sub>4</sub> Separation Properties

Cong-Jun Gan; Xiao-Chen Xu; Xue-Wei Jiang; Feng Gan; Jie Dong; Xin Zhao; Qing-Hua Zhang

doi:10.1007/s10118-019-2255-7

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Fabrication of 6FDA-HFBAPP Polyimide Asymmetric Hollow Fiber Membranes and Their CO₂/CH₄ Separation Properties

ARTICLE | Updated：2021-02-18

- Fabrication of 6FDA-HFBAPP Polyimide Asymmetric Hollow Fiber Membranes and Their CO₂/CH₄ Separation Properties
- Chinese Journal of Polymer Science Vol. 37, Issue 8, Pages: 815-826(2019)
- Affiliations：
  
  State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, College of Materials Science and Engineering, Donghua University, Shanghai 201620, China
- Author bio：
  
  xzhao@dhu.edu.cn (X.Z.)
  qhzhang@dhu.edu.cn (Q.H.Z.)
- Funds：
- DOI：10.1007/s10118-019-2255-7
  CLC：
- Received：17 January 2019，
  
  Revised：2019-3-6，
  
  Accepted：14 March 2019，
  
  Online First：23 April 2019，
  
  Published：2019-08
- Accepted：
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Citation: Gan, C. J.; Xu, X. C.; Jiang, X. W.; Gan, F.; Dong, J.; Zhao, X.; Zhang, Q. H. Fabrication of 6FDA-HFBAPP polyimide asymmetric hollow fiber membranes and their CO₂/CH₄ separation properties. Chinese J. Polym. Sci. 2019, 37, 815–826 DOI: 10.1007/s10118-019-2255-7.

Cong-Jun Gan, Xiao-Chen Xu, Xue-Wei Jiang, et al. Fabrication of 6FDA-HFBAPP Polyimide Asymmetric Hollow Fiber Membranes and Their CO₂/CH₄ Separation Properties[J]. Chinese Journal of Polymer Science, 2019, 37(8): 815-826. DOI: 10.1007/s10118-019-2255-7.
Citation: Gan, C. J.; Xu, X. C.; Jiang, X. W.; Gan, F.; Dong, J.; Zhao, X.; Zhang, Q. H. Fabrication of 6FDA-HFBAPP polyimide asymmetric hollow fiber membranes and their CO₂/CH₄ separation properties. Chinese J. Polym. Sci. 2019, 37, 815–826 DOI: 10.1007/s10118-019-2255-7. DOI：

Cong-Jun Gan, Xiao-Chen Xu, Xue-Wei Jiang, et al. Fabrication of 6FDA-HFBAPP Polyimide Asymmetric Hollow Fiber Membranes and Their CO₂/CH₄ Separation Properties[J]. Chinese Journal of Polymer Science, 2019, 37(8): 815-826. DOI: 10.1007/s10118-019-2255-7. DOI：

摘要

Abstract

In this work

poly(amide acid) solution

the precursor of polyimide

was synthesized by the reaction of 4

4′-(hexafluoroisopropylidene)diphthalicanhydride and 2

2-bis[4-(4-aminophenoxy)phenyl]-hexafluoropropanane in the solvent of

-methyl-2-pyrrolidone (NMP) and tetrahydrofuran (THF). Then

hollow fiber membranes for high flux gas separation were prepared by dry-jet wet spinning using the precursor solution of poly(amide acid) as the spinning dope and a subsequent imidization process. Silicone rubber was further coated outside the obtained hollow fiber membranes to repair the defects on the denser layer. The effects of internal

external coagulation bath ratios with air gap

and coating solution concentrations on the morphologies

structures

and separation performance of the membranes were studied. Results showed that the sponge-like support layer was formed when the content of NMP was increased from 50% to 90% in the internal coagulation bath. The outer surface of the membrane became denser when the water content in the external coagulation bath increased from 40% to 100%

and the separation coefficient of CO

/CH

increased by 2 times. This value could reach up to 1.4 when the air gap was 6 cm. With tuning the mass fraction of silicone rubber as 5%

hollow fiber composite membranes with uniform coating layer and an improved separation coefficient of 5.4 could be obtained.

关键词

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references

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Fabrication of 6FDA-HFBAPP Polyimide Asymmetric Hollow Fiber Membranes and Their CO2/CH4 Separation Properties

DOI：10.1007/s10118-019-2255-7

摘要

Abstract

关键词

Keywords

references

Fabrication of 6FDA-HFBAPP Polyimide Asymmetric Hollow Fiber Membranes and Their CO₂/CH₄ Separation Properties