

FOLLOWUS
a.School of Materials Science and Engineering, Shenyang University of Chemical Technology, Shenyang 110142, China
b.School of Chemistry & Chemical Engineering, Anhui University of Technology, Maanshan 143032, China
c.Department of Polymer Science and Engineering, Kyungpook National University, South Korea
13080896558@163.com (B.C.)
polyhx@ciac.ac.cn (H.X.Z.)
kbyoon@knu.ac.kr (K.B.Y.)
Received:25 December 2018,
Revised:2019-1-25,
Accepted:12 February 2019,
Online First:26 March 2019,
Published:2019-07
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Citation: Chen, B.; Ni, B. J.; Fu, M. X.; Zhong, H.; Jiang, W. F.; Liu, S. Y.; Zhang, H. X.; Yoon, K. B. Effect of molybdenum disulfide exfoliation conditions on the mechanical properties of epoxy nanocomposites. Chinese J. Polym. Sci. 2019, 37, 687–692
Bin Chen, Bao-Jia Ni, Meng-Xiang Fu, et al. Effect of Molybdenum Disulfide Exfoliation Conditions on the Mechanical Properties of Epoxy Nanocomposites[J]. Chinese Journal of Polymer Science, 2019, 37(7): 687-692.
Citation: Chen, B.; Ni, B. J.; Fu, M. X.; Zhong, H.; Jiang, W. F.; Liu, S. Y.; Zhang, H. X.; Yoon, K. B. Effect of molybdenum disulfide exfoliation conditions on the mechanical properties of epoxy nanocomposites. Chinese J. Polym. Sci. 2019, 37, 687–692 DOI: 10.1007/s10118-019-2239-7.
Bin Chen, Bao-Jia Ni, Meng-Xiang Fu, et al. Effect of Molybdenum Disulfide Exfoliation Conditions on the Mechanical Properties of Epoxy Nanocomposites[J]. Chinese Journal of Polymer Science, 2019, 37(7): 687-692. DOI: 10.1007/s10118-019-2239-7.
In this work
the MoS
2
fillers were prepared through chemical exfoliation method and used as fillers to fabricate epoxy (EP)/MoS
2
nanocomposites. The effects of molybdenum disulfide (MoS
2
) intercalation conditions on the properties of EP/MoS
2
nanocomposites were investigated. As the intercalation time was prolonged
the surface of MoS
2
exhibited a totally crumpled structure and more functional groups formed. Because of the higher functional group concentration
the interfacial adhesion force between EP and MoS
2
was enhanced. With the addition of 1.0 wt% exfoliated MoS
2
fillers
the tensile strength and tensile modulus of EP were even improved ~500% and ~6800%
respectively. Therefore
this work provides a facile way to produce high-performance EP nanocomposites.
Li, A.; Xu, W.; Wang, G.; Wang, X . Novel strategy for molybdenum disulfide nanosheets grown on titanate nanotubes for enhancing the flame retardancy and smoke suppression of epoxy resin . J. Appl. Polym. Sci. , 2017 . 135 46064 DOI: 10.1002/app.46064 http://doi.org/10.1002/app.46064 .
Qiang, H.; Liu, M.; Chen, J.; Wan, Q.; Tian, J.; Long, H.; Jiang, R.; Wen, Y.; Zhang, X.; Wei, Y . Facile preparation of MoS 2 based polymer composites via mussel inspired chemistry and their high efficiency for removal of organic dyes . Appl. Surf. Sci. , 2017 . 419 35 - 44 . DOI: 10.1016/j.apsusc.2017.05.006 http://doi.org/10.1016/j.apsusc.2017.05.006 .
Zhang, H. X.; Ko, E. B.; Park, J. H.; Moon, Y. K.; Park, B. S.; Zhang, X. Q.; Yoon, K. B . Preparation and properties of polyethylene/dodecanethiol-MoS 2 nanocomposites with dodecanethiol-MoS 2 /MgCl 2 -supported Ziegler-Natta catalyst via an in situ polymerization method . Polymer , 2017 . 108 223 - 229 . DOI: 10.1016/j.polymer.2016.11.069 http://doi.org/10.1016/j.polymer.2016.11.069 .
Xuan, D.; Zhou, Y.; Nie, W.; Chen, P . Sodium alginate-assisted exfoliation of MoS 2 and its reinforcement in polymer nanocomposites . Carbohydr. Polym. , 2017 . 155 40 - 48 . DOI: 10.1016/j.carbpol.2016.08.052 http://doi.org/10.1016/j.carbpol.2016.08.052 .
Sorrentino, A.; Altavilla, C.; Merola, M.; Senatore, A.; Ciambelli, P.; Iannace, S . Nanosheets of MoS 2 -oleylamine as hybrid filler for self-lubricating polymer composites: Thermal, tribological, and mechanical properties . Polym. Compos. , 2015 . 36 1124 - 1134 . DOI: 10.1002/pc.v36.6 http://doi.org/10.1002/pc.v36.6 .
O’Neill, A.; Khan, U.; Coleman, J. N . Preparation of high concentration dispersions of exfoliated MoS 2 with increased flake size . Chem. Mater. , 2012 . 24 2414 - 2421 . DOI: 10.1021/cm301515z http://doi.org/10.1021/cm301515z .
Castellanos-Gomez, A.; Poot, M.; Steele, G. A.; Hs, V. D. Z.; Agraït, N.; Rubio-Bollinger, G . Elastic properties of freely suspended MoS 2 nanosheets . Adv. Mater. , 2012 . 24 772 - 775 . DOI: 10.1002/adma.201103965 http://doi.org/10.1002/adma.201103965 .
Thakur, V. K.; Thakur, M. K . Processing and characterization of natural cellulose fibers/thermoset polymer composites . Carbohydr. Polym. , 2014 . 109 102 - 117 . DOI: 10.1016/j.carbpol.2014.03.039 http://doi.org/10.1016/j.carbpol.2014.03.039 .
Nichols, M. E.; Gerlock, J. L . Rates of photooxidation induced crosslinking and chain scission in thermoset polymer coatings II. Effect of hindered amine light stabilizer and ultraviolet light absorber additives . Polym. Degrad. Stab. , 2000 . 69 197 - 207 . DOI: 10.1016/S0141-3910(00)00061-6 http://doi.org/10.1016/S0141-3910(00)00061-6 .
Gorowara, R. L.; Kosik, W. E.; Mcknight, S. H.; Mccullough, R. L . Molecular characterization of glass fiber surface coatings for thermosetting polymer matrix/glass fiber composites . Compos. Part A-Appl. Sci. Manuf. , 2001 . 32 323 - 329 . DOI: 10.1016/S1359-835X(00)00112-3 http://doi.org/10.1016/S1359-835X(00)00112-3 .
Brennan, B.; Spencer, S. J.; Belsey, N. A.; Faris, T.; Cronin, H.; Silva, S. R. P.; Sainsbury, T.; Gilmore, I. S.; Stoeva, Z.; Pollard, A. J . Structural, chemical and electrical characterisation of conductive graphene-polymer composite films . Appl. Surf. Sci. , 2017 . 403 403 - 412 . DOI: 10.1016/j.apsusc.2017.01.132 http://doi.org/10.1016/j.apsusc.2017.01.132 .
Dong, H.; Yi, X.; Au, X.; Zhang, C.; Yan, L.; Deng, H . Development of interleaved fibre-reinforced thermoset polymer matrix composites . Acta Materiae Compositae Sinica , 2014 . 31 273 - 285 . .
Wang, J.; Zhang, D.; Zhang, Y.; Cai, W.; Yao, C.; Hu, Y.; Hu, W . Construction of multifunctional boron nitride nanosheet towards reducing toxic volatiles (CO and HCN) generation and fire hazard of thermoplastic polyurethane . J. Hazard. Mater. , 2019 . 362 482 - 494 . DOI: 10.1016/j.jhazmat.2018.09.009 http://doi.org/10.1016/j.jhazmat.2018.09.009 .
Wu, K.; Song, L.; Hu, Y.; Lu, H.; Kandola, B. K.; Kandare, E . Synthesis and characterization of a functional polyhedral oligomeric silsesquioxane and its flame retardancy in epoxy resin . Prog. Org. Coat. , 2009 . 65 490 - 497 . DOI: 10.1016/j.porgcoat.2009.04.008 http://doi.org/10.1016/j.porgcoat.2009.04.008 .
Ying, L.; Mao, S . Study on the properties and application of epoxy resin/polyurethane semi‐interpenetrating polymer networks . J. Appl. Polym. , 1996 . 61 2059 - 2063 . DOI: 10.1002/(ISSN)1097-4628 http://doi.org/10.1002/(ISSN)1097-4628 .
Lakouraj, M. M.; Rahpaima, G.; Zare, E. N. . Effect of functionalized magnetite nanoparticles and diaminoxanthone on the curing, thermal degradation kinetic and corrosion property of diglycidyl ether of bisphenol A-based epoxy resin . Chinese J. Polym. Sci. , 2014 . 32 1489 - 1499 . DOI: 10.1007/s10118-014-1535-5 http://doi.org/10.1007/s10118-014-1535-5 .
Yan, H.; Jing, D. Q.; Hou, X. L . Chemical degradation of amine-cured DGEBA epoxy resin in supercritical 1-propanol for recycling carbon fiber from composites . Chinese J. Polym. Sci. , 2014 . 32 1550 - 1563 . DOI: 10.1007/s10118-014-1519-5 http://doi.org/10.1007/s10118-014-1519-5 .
Azeez, A. A.; Rhee, K. Y.; Park, S. J.; Hui, D . Epoxy clay nanocomposites-Processing, properties and applications: A review . Compos. Part B-Eng. , 2013 . 45 308 - 320 . DOI: 10.1016/j.compositesb.2012.04.012 http://doi.org/10.1016/j.compositesb.2012.04.012 .
Jiang, X.; Sun, Y.; Zhang, H.; Hou, L . Preparation and characterization of quaternized poly(vinyl alcohol)/chitosan/MoS 2 composite anion exchange membranes with high selectivity . Carbohydr. Polym. , 2017 . 180 96 - 103 . DOI: 10.1016/j.carbpol.2017.10.023 http://doi.org/10.1016/j.carbpol.2017.10.023 .
Feng, X.; Wen, P.; Cheng, Y.; Liu, L.; Tai, Q.; Hu, Y.; Liew, K. M . Defect-free MoS 2 nanosheets: Advanced nanofillers for polymer nanocomposites . Compos. Part A-Appl. Sci. Manuf. , 2016 . 81 61 - 68 . DOI: 10.1016/j.compositesa.2015.11.002 http://doi.org/10.1016/j.compositesa.2015.11.002 .
Wang, X.; Xing, W.; Feng, X.; Yu, B.; Song, L.; Guan, H. Y.; Hu, Y . Enhanced mechanical and barrier properties of polyurethane nanocomposite films with randomly distributed molybdenum disulfide nanosheets . Compos. Sci. Technol. , 2016 . 127 142 - 148 . DOI: 10.1016/j.compscitech.2016.02.029 http://doi.org/10.1016/j.compscitech.2016.02.029 .
Matusinovic, Z.; Shukla, R.; Manias, E.; Hogshead, C. G.; Wilkiea, C. A . Polystyrene/molybdenum disulfide and poly(methyl methacrylate)/molybdenum disulfide nanocomposites with enhanced thermal stability . Polym. Degrad. Stab. , 2012 . 97 2481 - 2486 . DOI: 10.1016/j.polymdegradstab.2012.07.004 http://doi.org/10.1016/j.polymdegradstab.2012.07.004 .
Wang, J.; Ma, C.; Mu, X.; Cai, W.; Liu, L.; Zhou, X.; Hu, W.; Hu, Y . Construction of multifunctional MoSe 2 hybrid towards the simultaneous improvements in fire safety and mechanical property of polymer . J. Hazard. Mater. , 2018 . 352 36 - 46 . DOI: 10.1016/j.jhazmat.2018.03.003 http://doi.org/10.1016/j.jhazmat.2018.03.003 .
Zhou, K.; Liu, J.; Gui, Z.; Hu, Y.; Jiang, S . The influence of melamine phosphate modified MoS 2 on the thermal and flammability of poly(butylene succinate) composites: The influence of melamine phosphate modified MoS 2 . Polym. Adv. Technol. , 2016 . 27 1397 - 1400 . DOI: 10.1002/pat.v27.10 http://doi.org/10.1002/pat.v27.10 .
Zeng, G.; Liu, M.; Liu, X.; Huang, Q.; Xu, D.; Mao, L.; Huang, H.; Deng, F.; Zhang, X.; Wei, Y . Mussel inspired preparation of MoS 2 based polymer nanocomposites: The case of polyPEGMA . Appl. Surf. Sci. , 2016 . 387 399 - 405 . DOI: 10.1016/j.apsusc.2016.05.093 http://doi.org/10.1016/j.apsusc.2016.05.093 .
Zhou, K.; Liu, J.; Shi, Y.; Jiang, S.; Wang, D.; Hu, Y.; Gui, Z . MoS 2 nanolayers grown on carbon nanotubes: An advanced reinforcement for epoxy composites . ACS Appl. Mater. Interface , 2015 . 7 6070 - 6081 . DOI: 10.1021/acsami.5b00762 http://doi.org/10.1021/acsami.5b00762 .
Eksik, O.; Gao, J.; Shojaee, S. A.; Thomas, A.; Chow, P.; Bartolucci, S. F.; Lucca, D. A.; Koratkar, N . Epoxy nanocomposites with two-dimensional transition metal dichalcogenide additives . ACS Nano , 2014 . 8 5282 - 5289 . DOI: 10.1021/nn5014098 http://doi.org/10.1021/nn5014098 .
Chen, B.; Ni, B. J.; Liu, W. T.; Ye, Q. Y.; Liu, S. Y.; Zhang, H. X.; Yoon, K. B . Mechanical properties of epoxy nanocomposites filled with melamine functionalized molybdenum disulfide . RSC Adv. , 2018 . 8 20450 - 20455 . DOI: 10.1039/C8RA02689K http://doi.org/10.1039/C8RA02689K .
Divigalpitiya, W. M. R.; Frindt, R. F.; Morrison, S. R . Inclusion systems of organic molecules in restacked single-layer molybdenum disulfide . Science , 1989 . 246 369 - 71 . DOI: 10.1126/science.246.4928.369 http://doi.org/10.1126/science.246.4928.369 .
Divigalpitiya, W. M. R.; Morrison, S. R.; Frindt, R. F . Thin oriented films of molybdenum disulphide . Thin Solid Films , 1990 . 186 177 - 192 . DOI: 10.1016/0040-6090(90)90511-B http://doi.org/10.1016/0040-6090(90)90511-B .
Gönen, M.; Egbuchunam, T. O.; Balköse, D.; İnal, F.; Ülkü, S . Preparation and characterization of magnesium stearate, cobalt stearate, and copper stearate and their effects on poly(vinyl chloride) dehydrochlorination . J. Vinyl Addit. Technol. , 2014 . 47 131 - 137 . DOI: 10.1002/vnl.21384 http://doi.org/10.1002/vnl.21384 .
Guo, Y.; Wang, Z.; Shao, H.; Jiang, X . Hydrothermal synthesis of highly fluorescent carbon nanoparticles from sodium citrate and their use for the detection of mercury ions . Carbon , 2013 . 52 583 - 589 . DOI: 10.1016/j.carbon.2012.10.028 http://doi.org/10.1016/j.carbon.2012.10.028 .
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