AIE-active Metal-organic Coordination Complexes Based on Tetraphenylethylene Unit and Their Applications

Bo Jiang; Chang-Wei Zhang; Xue-Liang Shi; Hai-Bo Yang

doi:10.1007/s10118-019-2216-1

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AIE-active Metal-organic Coordination Complexes Based on Tetraphenylethylene Unit and Their Applications

REVIEW | Updated：2021-02-18

- AIE-active Metal-organic Coordination Complexes Based on Tetraphenylethylene Unit and Their Applications
- Chinese Journal of Polymer Science Vol. 37, Issue 4, Pages: 372-382(2019)
- Affiliations：
  
  Shanghai Key Laboratory of Green Chemistry and Chemical Processes, School of Chemistry and Molecular Engineering, East China Normal University, Shanghai 200062, China
- Author bio：
  
  xlshi@chem.ecnu.edu.cn (X.L.S)
  hbyang@chem.ecnu.edu.cn (H.B.Y)
- Funds：
- DOI：10.1007/s10118-019-2216-1
  CLC：
- Received：20 November 2018，
  
  Revised：2018-12-24，
  
  Accepted：24 December 2018，
  
  Online First：15 January 2019，
  
  Published：2019-04
- Accepted：
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Citation: Jiang, B.; Zhang, C. W.; Shi, X. L.; Yang, H. B. AIE-active metal-organic coordination complexes based on tetraphenylethylene unit and their applications. Chinese J. Polym. Sci. 2019, 37, 372–382

Bo Jiang, Chang-Wei Zhang, Xue-Liang Shi, et al. AIE-active Metal-organic Coordination Complexes Based on Tetraphenylethylene Unit and Their Applications[J]. Chinese Journal of Polymer Science, 2019, 37(4): 372-382.
Citation: Jiang, B.; Zhang, C. W.; Shi, X. L.; Yang, H. B. AIE-active metal-organic coordination complexes based on tetraphenylethylene unit and their applications. Chinese J. Polym. Sci. 2019, 37, 372–382 DOI： 10.1007/s10118-019-2216-1.

Bo Jiang, Chang-Wei Zhang, Xue-Liang Shi, et al. AIE-active Metal-organic Coordination Complexes Based on Tetraphenylethylene Unit and Their Applications[J]. Chinese Journal of Polymer Science, 2019, 37(4): 372-382. DOI： 10.1007/s10118-019-2216-1.

摘要

Abstract

Tetraphenylethylene (TPE) and its derivatives

as the widely used aggregation-induced emission (AIE) fluorophores

have attracted rapidly growing interest in the fields of material science and biological technology due to their unique light-emitting mechanism—they are nearly non-emissive in dilute solution but emit brilliant fluorescence in the aggregate state because of the restriction of intramolecular motion. Coordination-driven self-assembly

which provides a highly effective method to put the individual chromophores together

is consistent with the AIE mechanism of TPE. During the past few years

some AIE-active metal-organic coordination complexes have been successfully constructed

via

coordination-driven self-assembly

and their AIE properties and applications have been investigated. In this review

we survey the recent progress on TPE-based metal-organic coordination complexes and their applications in fluorescence sensors

cell imaging

and light-emitting materials. We will introduce them from three different types of structures: metallacycles

metallacages

and metal-organic frameworks (MOFs).

关键词

Keywords

references

Datta, S.; Saha, M. L.; Stang, P. J . Hierarchical assemblies of supramolecular coordination complexes . Acc. Chem. Res. , 2018 . 51 ( 9 ): 2047 - 2063 . DOI: 10.1021/acs.accounts.8b00233 http://doi.org/10.1021/acs.accounts.8b00233 .

Cook, T. R.; Stang, P. J . Recent developments in the preparation and chemistry of metallacycles and metallacages via coordination . Chem. Rev. , 2015 . 115 ( 15 ): 7001 - 7045 . DOI: 10.1021/cr5005666 http://doi.org/10.1021/cr5005666 .

Cook, T. R.; Zheng, Y. R.; Stang, P. J . Metal-organic frameworks and self-assembled supramolecular coordination complexes: Comparing and contrasting the design, synthesis, and functionality of metal-organic materials . Chem. Rev. , 2013 . 113 ( 1 ): 734 - 777 . DOI: 10.1021/cr3002824 http://doi.org/10.1021/cr3002824 .

Chen, L. J.; Yang, H. B . Construction of stimuli-responsive functional materials via hierarchical self-assembly involving coordination interactions . Acc. Chem. Res. , 2018 . 51 ( 11 ): 2699 - 2710 . DOI: 10.1021/acs.accounts.8b00317 http://doi.org/10.1021/acs.accounts.8b00317 .

Chen, L. J.; Yang, H. B.; Shionoya, M . Chiral metallosupramolecular architectures . Chem. Soc. Rev. , 2017 . 46 ( 9 ): 2555 - 2576 . DOI: 10.1039/C7CS00173H http://doi.org/10.1039/C7CS00173H .

Wang, W.; Wang, Y. X.; Yang, H. B . Supramolecular transformations within discrete coordination-driven supramolecular architectures . Chem. Soc. Rev. , 2016 . 45 ( 9 ): 2656 - 2693 . DOI: 10.1039/C5CS00301F http://doi.org/10.1039/C5CS00301F .

Xu, L.; Wang, Y. X.; Chen, L. J.; Yang, H. B . Construction of multiferrocenyl metallacycles and metallacages via coordination-driven self-assembly: From structure to functions . Chem. Soc. Rev. , 2015 . 44 ( 8 ): 2148 - 2167 . DOI: 10.1039/C5CS00022J http://doi.org/10.1039/C5CS00022J .

Fujita, M.; Tominaga, M.; Hori, A.; Therrien, B . Coordination assemblies from a Pd(II)-cornered square complex . Acc. Chem. Res. , 2005 . 38 ( 4 ): 369 - 378 . DOI: 10.1021/ar040153h http://doi.org/10.1021/ar040153h .

Caulder, D. L.; Raymond, K. N . Supermolecules by design . Acc. Chem. Res. , 1999 . 32 ( 11 ): 975 - 982 . DOI: 10.1021/ar970224v http://doi.org/10.1021/ar970224v .

Oliveri, C. G.; Ulmann, P. A.; Wiester, M. J.; Mirkin, C. A . Heteroligated supramolecular coordination complexes formed via the halide-induced ligand rearrangement reaction . Acc. Chem. Res. , 2008 . 41 ( 12 ): 1618 - 1629 . DOI: 10.1021/ar800025w http://doi.org/10.1021/ar800025w .

Eryazici, I.; Moorefield, C. N.; Newkome, G. R . Square-planar Pd(II), Pt(II), and Au(III) terpyridine complexes: Their syntheses, physical properties, supramolecular constructs, and biomedical activities . Chem. Rev. , 2008 . 108 ( 6 ): 1834 - 1895 . DOI: 10.1021/cr0781059 http://doi.org/10.1021/cr0781059 .

Nitschke, J. R . Construction, substitution, and sorting of metallo-organic structures via subcomponent self-assembly . Acc. Chem. Res. , 2007 . 40 ( 2 ): 103 - 112 . DOI: 10.1021/ar068185n http://doi.org/10.1021/ar068185n .

Han, Y. F.; Jin, G. X . Half-sandwich iridium- and rhodiumbased organometallic architectures: Rational design, synthesis, characterization, and applications . Acc. Chem. Res. , 2014 . 47 ( 12 ): 3571 - 3579 . DOI: 10.1021/ar500335a http://doi.org/10.1021/ar500335a .

Clever, G. H.; Punt, P . Cation-anion arrangement patterns in self-assembled Pd 2 L 4 and Pd 4 L 8 coordination cages . Acc. Chem. Res. , 2017 . 50 ( 9 ): 2233 - 2243 . DOI: 10.1021/acs.accounts.7b00231 http://doi.org/10.1021/acs.accounts.7b00231 .

Mukherjee, S.; Mukherjee, P. S . Versatility of azide in serendipitous assembly of copper(II) magnetic polyclusters . Acc. Chem. Res. , 2013 . 46 ( 11 ): 2556 - 2566 . DOI: 10.1021/ar400059q http://doi.org/10.1021/ar400059q .

Yan, X.; Li, S.; Cook, T. R.; Ji, X.; Yao, Y.; Pollock, J. B.; Shi, Y.; Yu, G.; Li, J.; Huang, F.; Stang, P. J . Hierarchical self-assembly: Well-defined supramolecular nanostructures and metallohydrogels via amphiphilic discrete organoplatinum(II) metallacycles . J. Am. Chem. Soc. , 2013 . 135 ( 38 ): 14036 - 14039 . DOI: 10.1021/ja406877b http://doi.org/10.1021/ja406877b .

Pollock, J. B.; Schneider, G. L.; Cook, T. R.; Davies, A. S.; Stang, P. J . Tunable visible light emission of self-assembled rhomboidal metallacycles . J. Am. Chem. Soc. , 2013 . 135 ( 37 ): 13676 - 13679 . DOI: 10.1021/ja4079607 http://doi.org/10.1021/ja4079607 .

Yan, X.; Cook, T. R.; Pollock, J. B.; Wei, P.; Zhang, Y.; Yu, Y.; Huang, F.; Stang, P. J . Responsive supramolecular polymer metallogel constructed by orthogonal coordination-driven self-assembly and host/guest interactions . J. Am. Chem. Soc. , 2014 . 136 ( 12 ): 4460 - 4463 . DOI: 10.1021/ja412249k http://doi.org/10.1021/ja412249k .

Neti, V. S. P. K.; Saha, M. L.; Yan, X.; Zhou, Z.; Stang, P. J . Coordination-driven self-assembly of fullerene-functionalized Pt(II) metallacycles . Organometallics , 2015 . 34 ( 20 ): 4813 - 4815 . DOI: 10.1021/acs.organomet.5b00718 http://doi.org/10.1021/acs.organomet.5b00718 .

Chen, L. J.; Zhao, G. Z.; Jiang, B.; Sun, B.; Wang, M.; Xu, L.; He, J.; Abliz, Z.; Tan, H.; Li, X.; Yang, H. B . Smart stimuli-responsive spherical nanostructures constructed from supramolecular metallodendrimers via hierarchical self-assembly . J. Am. Chem. Soc. , 2014 . 136 ( 16 ): 5993 - 6001 . DOI: 10.1021/ja500152a http://doi.org/10.1021/ja500152a .

Chen, L. J.; Jiang, B.; Yang, H. B . Transformable nanostructures of cholesteryl-containing rhomboidal metallacycles through hierarchical self-assembly . Org. Chem. Front. , 2016 . 3 ( 5 ): 579 - 587 . DOI: 10.1039/C6QO00017G http://doi.org/10.1039/C6QO00017G .

Li, Z. Y.; Zhang, Y.; Zhang, C. W.; Chen, L. J.; Wang, C.; Tan, H.; Yu, Y.; Li, X.; Yang, H. B . Cross-linked supramolecular polymer gels constructed from discrete multi-pillar[5]arene metallacycles and their multiple stimuli-responsive behavior . J. Am. Chem. Soc. , 2014 . 136 ( 24 ): 8577 - 8589 . DOI: 10.1021/ja413047r http://doi.org/10.1021/ja413047r .

Jiang, B.; Zhang, J.; Ma, J.; Zheng, W.; Chen, L. J.; Sun, B.; Li, C.; Hu, B.; Tan, H.; Li, X.; Yang, H. B . Vapochromic behavior of a chair-shaped supramolecular metallacycle with ultra-stability . J. Am. Chem. Soc. , 2016 . 138 ( 3 ): 738 - 741 . DOI: 10.1021/jacs.5b11409 http://doi.org/10.1021/jacs.5b11409 .

Jiang, B.; Chen, L. J.; Zhang, Y.; Tan, H.; Xu, L.; Yang, H. B . Hierarchical self-assembly of triangular metallodendrimers into the ordered nanostructures . Chin. Chem. Lett. , 2016 . 27 ( 4 ): 607 - 612 . DOI: 10.1016/j.cclet.2016.03.017 http://doi.org/10.1016/j.cclet.2016.03.017 .

Jiang, B.; Zhang, J.; Zheng, W.; Chen, L. J.; Yin, G. Q.; Wang, Y. X.; Sun, B.; Li, X.; Yang, H. B . Construction of alkynylplatinum(II) bzimpy-functionalized metallacycles and their hierarchical self-assembly behavior in solution promoted by Pt···Pt and π-π interactions . Chem. Eur. J. , 2016 . 22 ( 41 ): 14664 - 14671 . DOI: 10.1002/chem.201601682 http://doi.org/10.1002/chem.201601682 .

Zhang, Y.; Zhou, Q. F.; Huo, G.; Yin, G. Q.; Zhao, X.; Jiang, B.; Tan, H.; Li, X.; Yang, H. B . Hierarchical self-assembly of an alkynylplatinum(ll) bzimpy-functionalized metallacage via Pt···Pt and π-π Interactions . Inorg. Chem. , 2018 . 57 ( 7 ): 3516 - 3520 . DOI: 10.1021/acs.inorgchem.7b02777 http://doi.org/10.1021/acs.inorgchem.7b02777 .

Zhang, J.; Marega, R.; Chen, L. J.; Wu, N. W.; Xu, X. D.; Muddiman, D. C.; Bonifazi, D.; Yang, H. B . Hierarchical self-assembly of supramolecular hydrophobic metallacycles into ordered nanostructures . Chem. Asian J. , 2014 . 9 ( 10 ): 2928 - 2936 . DOI: 10.1002/asia.201402410 http://doi.org/10.1002/asia.201402410 .

Wu, N. W.; Chen, L. J.; Wang, C.; Ren, Y. Y.; Li, X.; Xu, L.; Yang, H. B . Hierarchical self-assembly of a discrete hexagonal metallacycle into the ordered nanofibers and stimuli-responsive supramolecular gels . Chem. Commun. , 2014 . 50 ( 32 ): 4231 - 4233 . DOI: 10.1039/c3cc49054h http://doi.org/10.1039/c3cc49054h .

Wang, W.; Zhang, Y.; Sun, B.; Chen, L. J.; Xu, X. D.; Wang, M.; Li, X.; Yu, Y.; Jiang, W.; Yang, H. B . The construction of complex multicomponent supramolecular systems via the combination of orthogonal self-assembly and the self-sorting approach . Chem. Sci. , 2014 . 5 ( 12 ): 4554 - 4560 . DOI: 10.1039/C4SC01550A http://doi.org/10.1039/C4SC01550A .

Zhao, G. Z.; Chen, L. J.; Wang, W.; Zhang, J.; Yang, G.; Wang, D. X.; Yu, Y.; Yang, H. B . Stimuli-responsive supramolecular gels through hierarchical self-assembly of discrete rhomboidal metallacycles . Chem. Eur. J. , 2013 . 19 ( 31 ): 10094 - 10100 . DOI: 10.1002/chem.201301385 http://doi.org/10.1002/chem.201301385 .

Wang, X. Q.; Wang, W.; Yin, G. Q.; Wang, Y. X.; Zhang, C. W.; Shi, J.; Yu, Y.; Yang, H. B . Cross-linked supramolecular polymer metallogels constructed via a self-sorting strategy and their multiple stimulus-response behaviors . Chem. Commun. , 2015 . 51 ( 94 ): 16813 - 16816 . DOI: 10.1039/C5CC05625J http://doi.org/10.1039/C5CC05625J .

McConnell, A. J.; Wood, C. S.; Neelakandan, P. P.; Nitschke, J. R . Stimuli-responsive metal-ligand assemblies . Chem. Rev. , 2015 . 115 ( 15 ): 7729 - 7793 . DOI: 10.1021/cr500632f http://doi.org/10.1021/cr500632f .

Luo, J.; Xie, Z.; Lam, J. W. Y.; Cheng, L.; Chen, H.; Qiu, C.; Kwok, H. S.; Zhan, X.; Liu, D.; Tang, B. Z . Aggregation-induced emission of 1-methyl-1,2,3,4,5-pentaphenylsilole . Chem. Commun. , 2001 . ( 18 ): 1740 - 1741 . .

Mei, J.; Leung, N. L. C.; Kwok, R. T. K.; Lam, J. W. Y.; Tang, B. Z . Aggregation-induced emission: Together we shine, united we soar! . Chem. Rev. , 2015 . 115 ( 21 ): 11718 - 11940 . DOI: 10.1021/acs.chemrev.5b00263 http://doi.org/10.1021/acs.chemrev.5b00263 .

Ding, D.; Li, K.; Liu, B.; Tang, B. Z . Bioprobes based on AIE fluorogens . Acc. Chem. Res. , 2013 . 46 2441 - 2453 . DOI: 10.1021/ar3003464 http://doi.org/10.1021/ar3003464 .

Hong, Y.; Lam, J. W. Y.; Tang, B. Z . Aggregation-induce emission . Chem. Soc. Rev. , 2011 . 40 ( 11 ): 5361 - 5388 . DOI: 10.1039/c1cs15113d http://doi.org/10.1039/c1cs15113d .

Feng, G.; Liu, B . Aggregation-induced emission (AIE) dots: Emerging theranostic nanolights . Acc. Chem. Res. , 2018 . 51 ( 6 ): 1404 - 1414 . DOI: 10.1021/acs.accounts.8b00060 http://doi.org/10.1021/acs.accounts.8b00060 .

Liu, Y.; Deng, C.; Tang, L.; Qin, A.; Hu, R.; Sun, J. Z.; Tang, B. Z . Specific detection of D-glucose by a tetraphenylethene-based fluorescent sensor . J. Am. Chem. Soc. , 2011 . 133 ( 4 ): 660 - 663 . DOI: 10.1021/ja107086y http://doi.org/10.1021/ja107086y .

Wang, J.; Mei, J.; Hu, R.; Sun, J. Z.; Qin, A.; Tang, B. Z . Click synthesis, aggregation-induced emission, E / Z isomerization, self-organization, and multiple chromisms of pure stereoisomers of a tetraphenylethene-cored luminogen . J. Am. Chem. Soc. , 2012 . 134 ( 24 ): 9956 - 9966 . DOI: 10.1021/ja208883h http://doi.org/10.1021/ja208883h .

Xu, S.; Yuan, Y.; Cai, X.; Zhang, C. J.; Hu, F.; Liang, J.; Zhang, G.; Zhang, D.; Liu, B . Tuning the singlet-triplet energy gap: A unique approach to efficient photosensitizers with aggregation-induced emission (AIE) characteristics . Chem. Sci. , 2015 . 6 ( 10 ): 5824 - 5830 . DOI: 10.1039/C5SC01733E http://doi.org/10.1039/C5SC01733E .

Zhang, C. W.; Ou, B.; Jiang, S. T.; Yin, G. Q.; Chen, L. J.; Xu, L.; Li, X.; Yang, H. B . Cross-linked AIE supramolecular polymer gels with multiple stimuli-responsive behaviours constructed by hierarchical self-assembly . Polym. Chem. , 2018 . 9 ( 15 ): 2021 - 2030 . DOI: 10.1039/C8PY00226F http://doi.org/10.1039/C8PY00226F .

Zhang, C. W.; Jiang, S. T.; Yin, G. Q.; Li, X.; Zhao, X. L.; Yang H. B . Dual stimuli-responsive cross-linker AIE supramolecular polymer constructed through hierarchical self-assembly . Isr. J. Chem. , 2018 . DOI: 10.1002/ijch.201800062 http://doi.org/10.1002/ijch.201800062 .

Zheng, W.; Yang, G.; Jiang, S.; Shao, N.; Yin, G. Q.; Xu, L.; Li, X.; Chen, G.; Yang, H. B . A Tetraphenylethylene (TPE)-based supra-amphiphilic organoplatinum(II) metallacycle and its self-assembly behaviour . Mater. Chem. Front. , 2017 . 1 ( 9 ): 1823 - 1828 . DOI: 10.1039/C7QM00107J http://doi.org/10.1039/C7QM00107J .

Chen, L. J.; Ren, Y. Y.; Wu, N. W.; Sun, B.; Ma, J.; Zhang, L.; Tan, H.; Liu, M.; Li, X.; Yang, H. B . Hierarchical self-assembly of discrete organoplatinum(II) metallacycles with polysaccharide via electrostatic interactions and their application for heparin detection . J. Am. Chem. Soc. , 2015 . 137 ( 36 ): 11725 - 11735 . DOI: 10.1021/jacs.5b06565 http://doi.org/10.1021/jacs.5b06565 .

Yin, G. Q.; Wang, H.; Wag, X. Q.; Song, B.; Chen, L. J.; Wang, L.; Hao, X. Q.; Yang, H. B.; Li, X . Self-assembly of emissive supramolecular rosettes with increasing complexity using multitopic terpyridine ligands . Nat. Commun. , 2018 . 9 567 DOI: 10.1038/s41467-018-02959-w http://doi.org/10.1038/s41467-018-02959-w .

Zhang, M.; Li, S.; Yan, X.; Zhou, Z.; Saha, M. L.; Wang, Y. C.; Stang, P. J . Fluorescent metallacycle-cored polymers via covalent linkage and their use as contrast agents for cell imaging . Proc. Natl. Acad. Sci. , 2016 . 113 ( 40 ): 11100 - 11105 . DOI: 10.1073/pnas.1612898113 http://doi.org/10.1073/pnas.1612898113 .

Yan, X.; Wang, H.; Hauke, C. E.; Cook, T. R.; Wang, M.; Saha, M. L.; Zhou, Z.; Zhang, M.; Li, X.; Huang, F.; Stang, P. J . A suite of tetraphenylethylene-based discrete organoplatinum(II) metallacycles: Controllable structure and stoichiometry, aggregation-induced emission, and nitroaromatics sensing . J. Am. Chem. Soc. , 2015 . 137 ( 48 ): 15276 - 15286 . DOI: 10.1021/jacs.5b10130 http://doi.org/10.1021/jacs.5b10130 .

Yan, X.; Wang, W.; Cook, T. R.; Zhang, M.; Saha, M. L.; Zhou, Z.; Li, X.; Huang, F.; Stang, P. J . Light-emitting superstructures with anion effect: Coordination-driven self-assembly of pure tetraphenylethylene metallacycles and metallacages . J. Am. Chem. Soc. , 2016 . 138 ( 13 ): 4580 - 4588 . DOI: 10.1021/jacs.6b00846 http://doi.org/10.1021/jacs.6b00846 .

Zhou, Z.; Yan, X.; Saha, M. L.; Zhang, M.; Wang, M.; Li, X.; Stang, P. J . Immobilizing tetraphenylethylene into fused metallacycles: Shape effects on fluorescence emission . J. Am. Chem. Soc. , 2016 . 138 ( 40 ): 13131 - 13134 . DOI: 10.1021/jacs.6b07173 http://doi.org/10.1021/jacs.6b07173 .

Tian, Y.; Yan, X.; Saha, M. L.; Niu, Z.; Stang, P. J . Hierarchical self-assembly of responsive organoplatinum(II) metallacycle-TMV complexes with turn-on fluorescence . J. Am. Chem. Soc. , 2016 . 138 ( 37 ): 12033 - 12036 . DOI: 10.1021/jacs.6b07402 http://doi.org/10.1021/jacs.6b07402 .

Yu, G.; Zhang, M.; Saha, M. L.; Mao, Z.; Chen, J.; Yao, Y.; Zhou, Z.; Liu, Y.; Gao, C.; Huang, F.; Chen, X.; Stang, P. J . Antitumor activity of a unique polymer that incorporates a fluorescent self-assembled metallacycle . J. Am. Chem. Soc. , 2017 . 139 ( 44 ): 15940 - 15949 . DOI: 10.1021/jacs.7b09224 http://doi.org/10.1021/jacs.7b09224 .

Yan, X.; Cook, T. R.; Wang, P.; Huang, F.; Stang, P. J . Highly emissive platinum(II) metallacages . Nat. Chem. , 2015 . 7 342 - 348 . DOI: 10.1038/nchem.2201 http://doi.org/10.1038/nchem.2201 .

Zhang, M.; Saha, M. L.; Wang, M.; Zhou, Z.; Song, B.; Lu, C.; Yan, X.; Li, X.; Huang, F.; Yin, S.; Stang, P. J . Multicomponent platinum(II) cages with tunable emission and amino acid sensing . J. Am. Chem. Soc. , 2017 . 139 ( 14 ): 5067 - 5074 . DOI: 10.1021/jacs.6b12536 http://doi.org/10.1021/jacs.6b12536 .

Lu, C.; Zhang, M.; Tang, D.; Yan, X.; Zhang, Z.; Zhou, Z.; Song, B.; Wang, H.; Li, X.; Yin, S.; Sepehrpour, H.; Stang, P. J . Fluorescent metallacage-core supramolecular polymer gel formed by orthogonal metal coordination and host-guest interactions . J. Am. Chem. Soc. , 2018 . 140 ( 24 ): 7674 - 7680 . DOI: 10.1021/jacs.8b03781 http://doi.org/10.1021/jacs.8b03781 .

Sun, Y.; Yao, Y.; Wang, H.; Fu, W.; Chen, C.; Saha, M. L.; Zhang, M.; Datta, S.; Zhou, Z.; Yu, H.; Li, X.; Stang, P. J . Self-assembly of metallacages into multidimensional suprastructures with tunable emissions . J. Am. Chem. Soc. , 2018 . 140 ( 40 ): 12819 - 12828 . DOI: 10.1021/jacs.8b05809 http://doi.org/10.1021/jacs.8b05809 .

Yu, G.; Cook, T. R.; Li, Y.; Yan, X.; Wu, D.; Shao, L.; Shen, J.; Tang, G.; Huang, F.; Chen, X.; Stang, P. J . Tetraphenylethene-based highly emissive metallacage as a component of theranostic supramolecular nanoparticles . Proc. Natl. Acad. Sci. , 2016 . 113 ( 48 ): 13720 - 13725 . DOI: 10.1073/pnas.1616836113 http://doi.org/10.1073/pnas.1616836113 .

Shustova, N. B.; McCarthy, B. D.; Dincǎ, M . Turn-on in tetraphenylethylene-based metal-organic frameworks: An alternative to aggregation-induced emission . J. Am. Chem. Soc. , 2011 . 133 ( 50 ): 20126 - 20129 . DOI: 10.1021/ja209327q http://doi.org/10.1021/ja209327q .

Shustova, N. B.; Cozzoline, A. F.; Reineke, S.; Baldo, M.; Dincǎ, M . Selective turn-on ammonia sensing enabled by high-temperature fluorescence in metal-organic frameworks with open metal sites . J. Am. Chem. Soc. , 2013 . 135 ( 36 ): 13326 - 13329 . DOI: 10.1021/ja407778a http://doi.org/10.1021/ja407778a .

Shustova, N.; Cozzolino, A. F.; Dincǎ, M . Conformational locking by design: Relating strain energy with luminescence and stability in rigid metal-organic frameworks . J. Am. Chem. Soc. , 2012 . 134 ( 48 ): 19596 - 19599 . DOI: 10.1021/ja3103154 http://doi.org/10.1021/ja3103154 .

Shustova, N. B.; Ong, T.; Cozzolino, A. F.; Michaelis, V. K.; Griffin, R. G.; Dincǎ, M . Phenyl ring dynamics in a tetraphenylethylene-bridged metal-organic framework: Implications for the mechanism of aggregation induced emission . J. Am. Chem. Soc. , 2012 . 134 ( 36 ): 15061 - 15070 . DOI: 10.1021/ja306042w http://doi.org/10.1021/ja306042w .

Zhang, Q.; Su, J.; Feng, D.; Wei, Z.; Zou, X.; Zhou, H. C . Piezofluorochromic metal-organic framework: A microscissor lift . J. Am. Chem. Soc. , 2015 . 137 ( 32 ): 10064 - 10067 . DOI: 10.1021/jacs.5b04695 http://doi.org/10.1021/jacs.5b04695 .

Wei, Z.; Gu, Z. Y.; Arvapallu, R. K.; Chen, Y. P.; McDougald, Jr. R. N.; Ivy, J. F.; Yakovenko, A. A.; Feng, D.; Omary, M. A.; Zhou, H. C . Rigidifying fluorescent linkers by metal-organic framework formation for fluorescence blue shift and quantum yield enhancement . J. Am. Chem. Soc. , 2014 . 136 ( 23 ): 8269 - 8276 . DOI: 10.1021/ja5006866 http://doi.org/10.1021/ja5006866 .

Zhang, M.; Feng, G.; Song, Z.; Zhou, Y. P.; Chao, H. Y.; Yuan, D.; Tan, T. T. Y.; Guo, Z.; Hu, Z.; Tang, B. Z.; Liu, B.; Zhao, D . Two-dimensional metal-organic framework with wide channels and responsive turn-on fluorescence for the chemical sensing of volatile organic compounds . J. Am. Chem. Soc. , 2014 . 136 ( 20 ): 7241 - 7244 . DOI: 10.1021/ja502643p http://doi.org/10.1021/ja502643p .

Hu, Z.; Lustig, W. P.; Zhang, J.; Zheng, C.;Wang, H.; Teat, S. J.; Gong, Q.; Rudd, N. D.; Li, J . Effective detection of mycotoxins by a highly luminescent metal-organic framework . J. Am. Chem. Soc. , 2015 . 137 ( 51 ): 16209 - 16215 . DOI: 10.1021/jacs.5b10308 http://doi.org/10.1021/jacs.5b10308 .

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