Nanomagnetic Organogel Based on Dodecyl Methacrylate for Absorption and Removal of Organic Solvents

Hossein Ghasemzadeh; Maryam Dargahi; Ghazaleh Eyvazi; Bahman Vasheghani Farahani

doi:10.1007/s10118-019-2213-4

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Nanomagnetic Organogel Based on Dodecyl Methacrylate for Absorption and Removal of Organic Solvents

ARTICLE | Updated：2021-02-18

- Nanomagnetic Organogel Based on Dodecyl Methacrylate for Absorption and Removal of Organic Solvents
- Chinese Journal of Polymer Science Vol. 37, Issue 5, Pages: 444-450(2019)
- Affiliations：
  
  Department of Chemistry, Faculty of Science, Imam Khomeini International University, P.O. Box 288, Qazvin, Iran
- Author bio：
  
  hoghasemzadeh@gmail.com
  dargahi@sci.ikiu.ac.ir (M.D.)
  ghazaleyvazi@yahoo.com (G.E.)
  bvasheghanif@yahoo.com (V.B.F.)
- Funds：
- DOI：10.1007/s10118-019-2213-4
  CLC：
- Received：22 September 2018，
  
  Revised：2018-12-8，
  
  Accepted：21 December 2018，
  
  Online First：29 January 2019，
  
  Published：2019-05
- Accepted：
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Citation: Ghasemzadeh, H.; Dargahi, M.; Eyvazi, G.; Farahani, B. V. Nanomagnetic organogel based on dodecyl methacrylate for absorption and removal of organic solvents. Chinese J. Polym. Sci. 2019, 37, 444–450

Hossein Ghasemzadeh, Maryam Dargahi, Ghazaleh Eyvazi, et al. Nanomagnetic Organogel Based on Dodecyl Methacrylate for Absorption and Removal of Organic Solvents[J]. Chinese Journal of Polymer Science, 2019, 37(5): 444-450.
Citation: Ghasemzadeh, H.; Dargahi, M.; Eyvazi, G.; Farahani, B. V. Nanomagnetic organogel based on dodecyl methacrylate for absorption and removal of organic solvents. Chinese J. Polym. Sci. 2019, 37, 444–450 DOI： 10.1007/s10118-019-2213-4.

Hossein Ghasemzadeh, Maryam Dargahi, Ghazaleh Eyvazi, et al. Nanomagnetic Organogel Based on Dodecyl Methacrylate for Absorption and Removal of Organic Solvents[J]. Chinese Journal of Polymer Science, 2019, 37(5): 444-450. DOI： 10.1007/s10118-019-2213-4.

摘要

Abstract

A novel nanomagnetic organogel was synthesized by

in situ

emulsion polymerization-crosslinking method using dodecyl methacrylate (DDMA) and styrene (St) as monomers

divinylbenzene (DVB) as a crosslinking agent

azobisisobutyronitrile (AIBN) as an initiator

and Fe

as a nanomagnetic particle. Modification of the network was carried out by inclusion of the multi-walled carbon nanotubes (MWCNT) into the organogel matrix. The structure of the nanocomposite was characterized using FTIR spectroscopy

SEM

TEM

TGA/DTG

VSM

and BET analysis. The effects of various parameters such as the amount of crosslinker

initiator

and reaction time as well as monomer ratio on the oil absorption of the organogel were studied. The synthesized organogel can absorb about 35.5

22.1

29.86

14.58

17.6

15.3

and 13.7 g·g

−1

of CHCl

toluene

hexane

crude oil

gasoline

and diesel oil

under the optimized polymerization conditions

respectively. The nanocomposite organogels can be easily separated by a magnetic field after absorption of organic solvents.

关键词

Keywords

references

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