Geminal Cross Coupling (GCC) Reaction for AIE Materials

Qi Yu; Ya-Long Wang; Ze-Qiang Chen; Peng-Ju Zhao; Cheng Fan; Chong Li; Ming-Qiang Zhu

doi:10.1007/s10118-019-2207-2

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Geminal Cross Coupling (GCC) Reaction for AIE Materials

REVIEW | Updated：2021-02-18

- Geminal Cross Coupling (GCC) Reaction for AIE Materials
- Chinese Journal of Polymer Science Vol. 37, Issue 4, Pages: 327-339(2019)
- Affiliations：
  
  Wuhan National Laboratory for Optoelectronics, School of Optical and Electronic Information, Huazhong University of Science and Technology, Wuhan 430074, China
- Author bio：
  
  chongli@hust.edu.cn (C.L.)
  mqzhu@hust.edu.cn (M.Q.Z.)
- Funds：
- DOI：10.1007/s10118-019-2207-2
  CLC：
- Received：30 October 2018，
  
  Revised：2018-12-6，
  
  Accepted：09 December 2018，
  
  Online First：11 January 2019，
  
  Published：2019-04
- Accepted：
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Citation: Yu, Q.; Wang, Y. L.; Chen, Z. Q.; Zhao, P. J.; Fan, C.; Li, C.; Zhu, M. Q. Geminal cross coupling (GCC) reaction for AIE materials. Chinese J. Polym. Sci. 2019, 37, 327–339

Qi Yu, Ya-Long Wang, Ze-Qiang Chen, et al. Geminal Cross Coupling (GCC) Reaction for AIE Materials[J]. Chinese Journal of Polymer Science, 2019, 37(4): 327-339.
Citation: Yu, Q.; Wang, Y. L.; Chen, Z. Q.; Zhao, P. J.; Fan, C.; Li, C.; Zhu, M. Q. Geminal cross coupling (GCC) reaction for AIE materials. Chinese J. Polym. Sci. 2019, 37, 327–339 DOI： 10.1007/s10118-019-2207-2.

Qi Yu, Ya-Long Wang, Ze-Qiang Chen, et al. Geminal Cross Coupling (GCC) Reaction for AIE Materials[J]. Chinese Journal of Polymer Science, 2019, 37(4): 327-339. DOI： 10.1007/s10118-019-2207-2.

摘要

Abstract

Tetraphenylethylene (TPE) derivatives are typical aggregation-induced emission (AIE) molecules

which have been widely investigated and applicated. The Rathore’s procedures and McMurry reaction are the two frequently used methods for synthesizing the TPE derivatives. The complex processes and low tolerance of active function groups make the TPE with limited structures and properties in some degree. Very recently

a novel strategy

named geminal cross coupling (GCC) reaction

is developed for designing and synthesizing various topological small molecules and polymers with rich optical properties beyond simple TPE compounds

and becomes a powerful synthesis method to AIE materials. This review overviews the current progresses of AIE molecules and polymers prepared by GCC as well as their applications. We believe that GCC reaction will have a bright future in the development of the next generation of tetraarylethylene (TAE)-kind AIE materials.

关键词

Keywords

references

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