Synthesis and Characterization of Easily Colored Meta-aramid Copolymer Containing Ether Bonds

Na Li; Xing-Ke Zhang; Jun-Rong Yu; Yan Wang; Jing Zhu; Zu-Ming Hu

doi:10.1007/s10118-019-2200-9

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Synthesis and Characterization of Easily Colored Meta-aramid Copolymer Containing Ether Bonds

ARTICLE | Updated：2021-02-18

- Synthesis and Characterization of Easily Colored Meta-aramid Copolymer Containing Ether Bonds
- Chinese Journal of Polymer Science Vol. 37, Issue 3, Pages: 227-234(2019)
- Affiliations：
  
  State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, College of Materials Science and Engineering, Donghua University, Shanghai 201620, China
- Author bio：
  
  yjr@dhu.edu.cn
- Funds：
- DOI：10.1007/s10118-019-2200-9
  CLC：
- Received：03 September 2018，
  
  Revised：2018-10-18，
  
  Accepted：03 November 2018，
  
  Online First：14 December 2018，
  
  Published：2019-03
- Accepted：
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Citation: Li, N.; Zhang, X. K.; Yu, J. R.; Wang, Y.; Zhu, J.; Hu, Z. M. Synthesis and characterization of easily colored meta-aramid copolymer containing ether bonds. Chinese J. Polym. Sci. 2019, 37, 227–234

Na Li, Xing-Ke Zhang, Jun-Rong Yu, et al. Synthesis and Characterization of Easily Colored Meta-aramid Copolymer Containing Ether Bonds[J]. Chinese Journal of Polymer Science, 2019, 37(3): 227-234.
Citation: Li, N.; Zhang, X. K.; Yu, J. R.; Wang, Y.; Zhu, J.; Hu, Z. M. Synthesis and characterization of easily colored meta-aramid copolymer containing ether bonds. Chinese J. Polym. Sci. 2019, 37, 227–234 DOI： 10.1007/s10118-019-2200-9.

Na Li, Xing-Ke Zhang, Jun-Rong Yu, et al. Synthesis and Characterization of Easily Colored Meta-aramid Copolymer Containing Ether Bonds[J]. Chinese Journal of Polymer Science, 2019, 37(3): 227-234. DOI： 10.1007/s10118-019-2200-9.

摘要

Abstract

This work described the preparation of easily colored meta-aramid (PMIA) copolymers from

-phenylenediamine (MPD)

isophthaloyl dichloride (IPC)

and 3

4′-oxydianiline (3

4′-ODA)

via

solution polycondensation in

-dimethylacetamide (DMAc). The novel co-PMIAs were obtained in relatively high inherent viscosities ranging from 1.32 dL/g to 2.53 dL/g

which could be easily cast into flexible films with high transparence or spun into fibers. All the newly synthesized copolymers possessed excellent thermal stabilities even better than that of commercial PMIA

with 5% weight loss temperatures higher than 430 °C in nitrogen measured by TGA and glass transition temperature of 267–277 °C measured by DSC. The cast films exhibited good mechanical properties with a tensile strength up to 107 MPa and a tensile modulus up to 2.2 GPa. The resultant PMIAs also showed good solubility and better dye ability for cationic dyes.

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references

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