Formation of Poly(<italic style="font-style: italic">ε</italic>-caprolactone) Networks <italic style="font-style: italic">via</italic> Supramolecular Hydrogen Bonding Interactions

Sen Xu; Pengfei Chang; Bingjie Zhao; Muhammad Adeel; Sixun Zheng

doi:10.1007/s10118-019-2199-y

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Formation of Poly(ε-caprolactone) Networks via Supramolecular Hydrogen Bonding Interactions

ARTICLE | Updated：2021-02-18

- Formation of Poly(ε-caprolactone) Networks via Supramolecular Hydrogen Bonding Interactions
- Chinese Journal of Polymer Science Vol. 37, Issue 3, Pages: 197-207(2019)
- Affiliations：
  
  Department of Polymer Science and Engineering and the State Key Laboratory of Metal Matrix Composites, Shanghai Jiao Tong University, Shanghai 200240, China
- Author bio：
  
  szheng@sjtu.edu.cn
- Funds：
- DOI：10.1007/s10118-019-2199-y
  CLC：
- Received：02 November 2018，
  
  Revised：2018-11-16，
  
  Accepted：19 November 2018，
  
  Online First：13 December 2018，
  
  Published：2019-03
- Accepted：
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Citation: Xu, S.; Chang, P.; Zhao, B.; Adeel, M.; Zheng, S. Formation of poly( ε-caprolactone) networks via supramolecular hydrogen bonding interactions. Chinese J. Polym. Sci. 2019, 37, 197–207

Sen Xu, Pengfei Chang, Bingjie Zhao, et al. Formation of Poly(ε-caprolactone) Networks via Supramolecular Hydrogen Bonding Interactions[J]. Chinese Journal of Polymer Science, 2019, 37(3): 197-207. DOI: 10.1007/s10118-019-2199-y.
Citation: Xu, S.; Chang, P.; Zhao, B.; Adeel, M.; Zheng, S. Formation of poly( ε-caprolactone) networks via supramolecular hydrogen bonding interactions. Chinese J. Polym. Sci. 2019, 37, 197–207 DOI： 10.1007/s10118-019-2199-y.

Sen Xu, Pengfei Chang, Bingjie Zhao, et al. Formation of Poly(ε-caprolactone) Networks via Supramolecular Hydrogen Bonding Interactions[J]. Chinese Journal of Polymer Science, 2019, 37(3): 197-207. DOI: 10.1007/s10118-019-2199-y. DOI：

摘要

Abstract

In this contribution

we reported a novel approach to crosslink poly(

-caprolactone) (PCL)

via

supramolecular hydrogen bonding interactions. First

a series of octa-armed poly(

-caprolactone) stars with polyhedral oligomeric silsesquioxane (POSS) cores were synthesized

via

the ring-opening polymerizations. Thereafter

the arm ends of organic-inorganic star-shaped PCLs were reacted with 2-(6-isocyanatohexylaminocarbonylamino)-6-methyl-4[1

]-pyrimidinone to obtain 2-ureido-4[1

]-pyrimidone (UPy)-terminated PCL stars. Notably

the UPy-terminated PCL stars were physically crosslinked

which was evidenced by means of dynamic mechanical thermal analysis (DMTA) and rheological analysis. Owing to the formation of the physically-crosslinked networks

the organic-inorganic PCL stars displayed significant shape memory properties with about 100% of shape recovery

which was in marked contrast to the PCL stars without UPy termini.

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Keywords

references

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Formation of Poly(ε-caprolactone) Networks via Supramolecular Hydrogen Bonding Interactions

DOI：10.1007/s10118-019-2199-y

摘要

Abstract

关键词

Keywords

references