Binuclear and Hexanuclear Ti(IV) Complexes Supported by [OOOO]<sup>4–</sup>-type Ligand for Preparing Disentangled UHMWPE

Vladislav A. Tuskaev; Svetlana Ch. Gagieva; Dmitry A. Kurmaev; Viktor G. Vasil'ev; Nikolay A. Kolosov; Sergey V. Zubkevich; Elena S. Mikhaylik; Evgenii K. Golubev; Galina G. Nikiforova; Pavel A. Zhizhko; Olga A. Serenko; Boris M. Bulychev

doi:10.1007/s10118-019-2197-0

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Binuclear and Hexanuclear Ti(IV) Complexes Supported by [OOOO]^4–-type Ligand for Preparing Disentangled UHMWPE

ARTICLE | Updated：2021-02-18

- Binuclear and Hexanuclear Ti(IV) Complexes Supported by [OOOO]^4–-type Ligand for Preparing Disentangled UHMWPE
- Chinese Journal of Polymer Science Vol. 37, Issue 5, Pages: 471-477(2019)
- Affiliations：
  
  a.Department of Chemistry, M. V. Lomonosov Moscow State University, 1 Leninskie Gory, Moscow 119992, Russian Federation
  b.A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, Moscow 119991, Russian Federation
  c.Enikolopov Institute of Synthetic Polymer Materials, Russian Academy of Sciences, Profsoyuznaya Str., 70, Moscow 117393, Russian Federation
- Author bio：
  
  tuskaev@yandex.ru
- Funds：
- DOI：10.1007/s10118-019-2197-0
  CLC：
- Received：08 September 2018，
  
  Revised：2018-11-3，
  
  Accepted：03 November 2018，
  
  Online First：04 December 2018，
  
  Published：2019-05
- Accepted：
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Citation: Tuskaev, V. A.; Gagieva, S. C.; Kurmaev, D. A.; Vasil'ev, V. G.; Kolosov, N. A.; Zubkevich, S. V.; Mikhaylik, E. S.; Golubev, E. K.; Nikiforova, G. G.; Zhizhko, P. A.; Serenko, O. A.; Bulychev, B. M. Binuclear and hexanuclear Ti(IV) complexes supported by [OOOO]^4–-type ligand for preparing disentangled UHMWPE. Chinese J. Polym. Sci. 2019, 37, 471–477 DOI: 10.1007/s10118-019-2197-0.

Vladislav A. Tuskaev, Svetlana Ch. Gagieva, Dmitry A. Kurmaev, et al. Binuclear and Hexanuclear Ti(IV) Complexes Supported by [OOOO]^4–-type Ligand for Preparing Disentangled UHMWPE[J]. Chinese Journal of Polymer Science, 2019, 37(5): 471-477. DOI: 10.1007/s10118-019-2197-0.
Citation: Tuskaev, V. A.; Gagieva, S. C.; Kurmaev, D. A.; Vasil'ev, V. G.; Kolosov, N. A.; Zubkevich, S. V.; Mikhaylik, E. S.; Golubev, E. K.; Nikiforova, G. G.; Zhizhko, P. A.; Serenko, O. A.; Bulychev, B. M. Binuclear and hexanuclear Ti(IV) complexes supported by [OOOO]^4–-type ligand for preparing disentangled UHMWPE. Chinese J. Polym. Sci. 2019, 37, 471–477 DOI: 10.1007/s10118-019-2197-0. DOI：

Vladislav A. Tuskaev, Svetlana Ch. Gagieva, Dmitry A. Kurmaev, et al. Binuclear and Hexanuclear Ti(IV) Complexes Supported by [OOOO]^4–-type Ligand for Preparing Disentangled UHMWPE[J]. Chinese Journal of Polymer Science, 2019, 37(5): 471-477. DOI: 10.1007/s10118-019-2197-0. DOI：

摘要

Abstract

Binuclear and hexanuclear titanium complexes stabilized by tetradentate [OOOO]

4–

-type ligand were active in ethylene polymerization in the presence of Et

AlCl/Bu

Mg binary co-catalyst

giving high molecular weight polyethylene. The binuclear complex showed significantly higher catalytic activity and thermal stability in comparison to mononuclear analogue. Ultra high molecular weight polyethylene (UHMWPE) samples were processed by a solid-state uniaxial deformation into high-strength (up to 2.5 GPa) and high-modulus (over 100 GPa) oriented film tapes

which indirectly indicates a low degree of entanglements between the macromolecular chains.

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references

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Binuclear and Hexanuclear Ti(IV) Complexes Supported by [OOOO]4–-type Ligand for Preparing Disentangled UHMWPE

DOI：10.1007/s10118-019-2197-0

摘要

Abstract

关键词

Keywords

references

Binuclear and Hexanuclear Ti(IV) Complexes Supported by [OOOO]^4–-type Ligand for Preparing Disentangled UHMWPE