Preparation and Characterization of UV-absorbing PVDF Membranes via Pre-irradiation Induced Graft Polymerization

Li Dong; Xiang-Dong Liu; Zheng-Rong Xiong; De-Kun Sheng; Yan Zhou; Yu-Ming Yang

doi:10.1007/s10118-019-2194-3

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Preparation and Characterization of UV-absorbing PVDF Membranes via Pre-irradiation Induced Graft Polymerization

ARTICLE | Updated：2021-02-18

- Preparation and Characterization of UV-absorbing PVDF Membranes via Pre-irradiation Induced Graft Polymerization
- Chinese Journal of Polymer Science Vol. 37, Issue 5, Pages: 493-499(2019)
- Affiliations：
  
  a.Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China
  b.University of Science and Technology of China, Hefei 230026, China
- Author bio：
  
  dksheng@ciac.ac.cn (D.K.S.)
  ymyang@ciac.ac.cn (Y.M.Y.)
- Funds：
- DOI：10.1007/s10118-019-2194-3
  CLC：
- Received：31 August 2018，
  
  Revised：2018-10-6，
  
  Accepted：19 October 2018，
  
  Online First：14 November 2018，
  
  Published：2019-05
- Accepted：
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Citation: Dong, L.; Liu, X. D.; Xiong, Z. R.; Sheng, D. K.; Zhou, Y.; Yang, Y. M. Preparation and characterization of UV-absorbing PVDF membranes , via, pre-irradiation induced graft polymerization. Chinese J. Polym. Sci. 2019, 37, 493–499

Li Dong, Xiang-Dong Liu, Zheng-Rong Xiong, et al. Preparation and Characterization of UV-absorbing PVDF Membranes via Pre-irradiation Induced Graft Polymerization[J]. Chinese Journal of Polymer Science, 2019, 37(5): 493-499.
Citation: Dong, L.; Liu, X. D.; Xiong, Z. R.; Sheng, D. K.; Zhou, Y.; Yang, Y. M. Preparation and characterization of UV-absorbing PVDF membranes , via, pre-irradiation induced graft polymerization. Chinese J. Polym. Sci. 2019, 37, 493–499 DOI： 10.1007/s10118-019-2194-3.

Li Dong, Xiang-Dong Liu, Zheng-Rong Xiong, et al. Preparation and Characterization of UV-absorbing PVDF Membranes via Pre-irradiation Induced Graft Polymerization[J]. Chinese Journal of Polymer Science, 2019, 37(5): 493-499. DOI： 10.1007/s10118-019-2194-3.

摘要

Abstract

Herein

excellent UV-absorbing poly(vinylidene fluoride) (PVDF) membranes were fabricated through the pre-irradiation induced graft polymerization method. The PVDF chains irradiated with

-ray were modified with the polymerizable UV absorber 2-[2-hydroxy-5-[2-(methacryloyloxy)ethyl]phenyl]

-2

-benzotriazole (RUVA-93). The influences of irradiation dose and monomer concentration on the prepared PVDF-

-PRUVA-93 membranes were investigated

and the optimal condition was eventually obtained. The chemical structures of the films were studied by

H-NMR

FTIR

and XRD. UV light transmittance and DSC tests were used to characterize the UV-absorbing performance and thermal property of the PVDF films before and after modification. The results proved that the PRUVA-93 side chains were successfully incorporated into the PVDF main chains and the obtained PVDF-

-PRUVA-93 films possessed remarkable UV-absorbing property. The modified membrane made under the optimized experiment condition could completely block the UV light in the range of 200−387 nm. Additionally

the transmittance of the PVDF-

-PRUVA-93 film could be reduced to 0.04% in 280−320 nm

where the light irradiation could damage polymer materials most seriously.

关键词

Keywords

references

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