Enhanced Crystallization Kinetics of PLLA by Ethoxycarbonyl Ionic Liquid Modified Graphene

Pei Xu; Zhao-Pei Cui; Gang Ruan; Yun-Sheng Ding

doi:10.1007/s10118-019-2192-5

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Enhanced Crystallization Kinetics of PLLA by Ethoxycarbonyl Ionic Liquid Modified Graphene

ARTICLE | Updated：2021-02-18

- Enhanced Crystallization Kinetics of PLLA by Ethoxycarbonyl Ionic Liquid Modified Graphene
- Chinese Journal of Polymer Science Vol. 37, Issue 3, Pages: 243-252(2019)
- Affiliations：
  
  Department of Polymer Science and Engineering, School of Chemistry and Chemical Engineering, and Anhui Key Laboratory of Advanced Functional Materials and Devices, Hefei University of Technology, Hefei 230009, China
- Author bio：
  
  chxuper@hfut.edu.cn (P.X.)
  dingys@hfut.edu.cn (Y.S.D.)
- Funds：
- DOI：10.1007/s10118-019-2192-5
  CLC：
- Received：04 July 2018，
  
  Revised：2018-9-23，
  
  Accepted：25 September 2018，
  
  Online First：02 November 2018，
  
  Published：2019-03
- Accepted：
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Citation: Xu, P.; Cui, Z. P.; Ruan, G.; Ding, Y. S. Enhanced crystallization kinetics of PLLA by ethoxycarbonyl ionic liquid modified graphene. Chinese J. Polym. Sci. 2019, 37, 243–252

Pei Xu, Zhao-Pei Cui, Gang Ruan, et al. Enhanced Crystallization Kinetics of PLLA by Ethoxycarbonyl Ionic Liquid Modified Graphene[J]. Chinese Journal of Polymer Science, 2019, 37(3): 243-252.
Citation: Xu, P.; Cui, Z. P.; Ruan, G.; Ding, Y. S. Enhanced crystallization kinetics of PLLA by ethoxycarbonyl ionic liquid modified graphene. Chinese J. Polym. Sci. 2019, 37, 243–252 DOI： 10.1007/s10118-019-2192-5.

Pei Xu, Zhao-Pei Cui, Gang Ruan, et al. Enhanced Crystallization Kinetics of PLLA by Ethoxycarbonyl Ionic Liquid Modified Graphene[J]. Chinese Journal of Polymer Science, 2019, 37(3): 243-252. DOI： 10.1007/s10118-019-2192-5.

摘要

Abstract

To investigate the performance of graphene (Gra) modified with ethoxycarbonyl ionic liquid (IL)

chain mobility and crystallization kinetics of poly(L-lactic acid) (PLLA)

a series of PLLA nanocomposites have been prepared using solution-cast method. IL can improve the dispersion of Gra in PLLA matrix and the samples containing IL have higher growth rate of PLLA spherulite than neat PLLA does. PLLA/IL/Gra and PLLA/2Gra exhibit the same relaxation strength and time of

relaxation that corresponds to the longest normal mode motion at 110−140 °C. PLLA/IL/Gra shows a faster crystallization rate than PLLA/2Gra does

which might be attributed to the Gra-imidazolium cation interaction in IL modified Gra

the significant dispersion effect of IL at Gra surface

and the increase of nuclei density of PLLA/IL/Gra.

关键词

Keywords

references

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