Study on Phase Transformation Behavior of Strain-induced PLLA Mesophase by Polarized Infrared Spectroscopy

Jian Hu; Li-Li Han; Tong-Ping Zhang; Yong-Xin Duan; Jian-Ming Zhang

doi:10.1007/s10118-019-2184-5

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Study on Phase Transformation Behavior of Strain-induced PLLA Mesophase by Polarized Infrared Spectroscopy

ARTICLE | Updated：2021-02-18

- Study on Phase Transformation Behavior of Strain-induced PLLA Mesophase by Polarized Infrared Spectroscopy
- Chinese Journal of Polymer Science Vol. 37, Issue 3, Pages: 253-257(2019)
- Affiliations：
  
  Key Laboratory of Rubber-Plastics, Ministry of Education/Shandong Provincial Key Laboratory of Rubber-plastics, Qingdao University of Science & Technology, Qingdao 266042, China
- Author bio：
  
  zjm@qust.edu.cn
- Funds：
- DOI：10.1007/s10118-019-2184-5
  CLC：
- Received：19 July 2018，
  
  Revised：2018-8-22，
  
  Accepted：28 August 2018，
  
  Online First：25 September 2018，
  
  Published：2019-03
- Accepted：
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Citation: Hu, J.; Han, L. L.; Zhang, T. P.; Duan, Y. X.; Zhang, J. M. Study on phase transformation behavior of strain-induced PLLA mesophase by polarized infrared spectroscopy. Chinese J. Polym. Sci. 2019, 37, 253–257

Jian Hu, Li-Li Han, Tong-Ping Zhang, et al. Study on Phase Transformation Behavior of Strain-induced PLLA Mesophase by Polarized Infrared Spectroscopy[J]. Chinese Journal of Polymer Science, 2019, 37(3): 253-257.
Citation: Hu, J.; Han, L. L.; Zhang, T. P.; Duan, Y. X.; Zhang, J. M. Study on phase transformation behavior of strain-induced PLLA mesophase by polarized infrared spectroscopy. Chinese J. Polym. Sci. 2019, 37, 253–257 DOI： 10.1007/s10118-019-2184-5.

Jian Hu, Li-Li Han, Tong-Ping Zhang, et al. Study on Phase Transformation Behavior of Strain-induced PLLA Mesophase by Polarized Infrared Spectroscopy[J]. Chinese Journal of Polymer Science, 2019, 37(3): 253-257. DOI： 10.1007/s10118-019-2184-5.

摘要

Abstract

The structural transformation of mesophase to crystalline phase of strain-induced poly(L-lactic acid) has been investigated by differential scanning calorimetry (DSC) and

in situ

temperature dependent polarized Fourier transform infrared (FTIR) spectroscopy. It is found that

as the drawing temperature increases

melting of strain-induced mesophase in the heating process can remarkably interfere the crystallization behavior subsequently. Coupling with

in situ

polarized FTIR

from 60 °C to 76 °C

the mesophase melts partially rather than completely melting

and changes immediately to three-dimensional ordered structure. Of particular note

through monitoring the subtle spectral change in the critical phase transformation temperature from 60 °C to 64 °C

it is clearly demonstrated that relaxation of oriented amorphous chains initially takes place prior to the melting of mesophase.

关键词

Keywords

references

Allegra, G. in Interphases and Mesophases in Polymer Crystallization III , Springer, 2005.

Cho, B. K.; Jain, A.; Gruner, S. M.; Wiesner, U . Mesophase structure-mechanical and ionic transport correlations in extended amphiphilic dendrons . Science , 2004 . 305 1598 - 1601 . DOI: 10.1126/science.1100872 http://doi.org/10.1126/science.1100872 .

Bates, F. S . Polymer-polymer phase behavior . Science , 1991 . 251 898 - 905 . DOI: 10.1126/science.251.4996.898 http://doi.org/10.1126/science.251.4996.898 .

De Rosa, C.; Auriemma, F. R.; Giusto, G. O.; De Ballesteros, R . Helical mesophase of syndiotactic polypropylene in copolymers with 1-hexene and 1-octene . Macromolecules , 2010 . 43 9802 - 9809 . DOI: 10.1021/ma1021709 http://doi.org/10.1021/ma1021709 .

Androsch, R.; Di Lorenzo, M. L.; Schick, C.; Wunderlich, B . Mesophases in polyethylene, polypropylene, and poly(1-butene) . Polymer , 2010 . 51 4639 - 4662 . DOI: 10.1016/j.polymer.2010.07.033 http://doi.org/10.1016/j.polymer.2010.07.033 .

De Rosa, C.; Auriemma, F.; Di Girolamo, R.; Romano, L. M.; De Luca, R . A new mesophase of isotactic polypropylene in copolymers of propylene with long branched comonomers . Macromolecules , 2010 . 43 8559 - 8569 . DOI: 10.1021/ma101543d http://doi.org/10.1021/ma101543d .

Mileva, D.; Androsch, R.; Zhuravlev, E.; Schick, C . Temperature of melting of the mesophase of isotactic polypropylene . Macromolecules , 2009 . 42 7275 - 7278 . DOI: 10.1021/ma901797b http://doi.org/10.1021/ma901797b .

Androsch, R . In situ atomic force microscopy of the mesomorphic monoclinic phase transition in isotactic polypropylene . Macromolecules , 2008 . 41 533 - 535 . DOI: 10.1021/ma702334q http://doi.org/10.1021/ma702334q .

Welsh, G. E.; Blundell, D. J.; Windle, A. H . Transient mesophase on drawing polymers based on polyethylene terephthalate (PET) and polyethylene naphthoate (PEN) . J. Mater. Sci. , 2000 . 35 5225 - 5240 . DOI: 10.1023/A:1004820824004 http://doi.org/10.1023/A:1004820824004 .

Cocca, M.; Androsch, R.; Righetti, M. C.; Malinconico, M.; Di Lorenzo, M. L . Conformationally disordered crystals and their influence on material properties: The cases of isotactic polypropylene, isotactic poly(1-butene), and poly(L-lactic acid) . J. Mol. Struct. , 2014 . 1078 114 - 132 . DOI: 10.1016/j.molstruc.2014.02.038 http://doi.org/10.1016/j.molstruc.2014.02.038 .

Chen, C. Y.; Yang, C. F.; Jeng, U. S.; Su, A. C . Intrinsic metastability of the α ′ phase and its partial transformation into α crystals during isothermal cold-crystallization of poly(L-lactide) . Macromolecules , 2014 . 47 5144 - 5151 . DOI: 10.1021/ma501167e http://doi.org/10.1021/ma501167e .

Lan, Q.; Li, Y.; Chi, H . Highly enhanced mesophase formation in glassy poly(L-lactide) at low temperatures by low-pressure CO 2 that provides moderately increased molecular mobility . Macromolecules , 2016 . 49 2262 - 2271 . DOI: 10.1021/acs.macromol.6b00044 http://doi.org/10.1021/acs.macromol.6b00044 .

Androsch, R.; Di Lorenzo, M. L . Effect of molar mass on the α ′/ α -transition in poly (L-lactic acid) . Polymer , 2017 . 114 144 - 148 . DOI: 10.1016/j.polymer.2017.02.063 http://doi.org/10.1016/j.polymer.2017.02.063 .

Su, F.; Li, X.; Zhou, W.; Zhu, S.; Ji, Y.; Wang, Z.; Qi, Z.; Li, L . Direct formation of isotactic poly(1-butene) form I crystal from memorized ordered melt . Macromolecules , 2013 . 46 7399 - 7405 . DOI: 10.1021/ma400952r http://doi.org/10.1021/ma400952r .

Zhang, B.; Chen, J.; Cui, J.; Zhang, H.; Ji, F.; Zheng, G.; Heck, B.; Reiter, G.; Shen, C . effect of shear stress on crystallization of isotactic polypropylene from a structured melt . Macromolecules , 2012 . 45 8933 - 8937 . DOI: 10.1021/ma3014756 http://doi.org/10.1021/ma3014756 .

Natta, G.; Peraldo, M.; Corradini, P . Smectic mesomorphic form of isotactic polypropylene . Rend. Accad. Naz. Lincei , 1959 . 26 14 - 17 . .

Natta, G.; Corradini, P . Structure and properties of isotactic polypropylene . Nuovo Cimento Suppl. , 1960 . 15 40 - 51 . DOI: 10.1007/BF02731859 http://doi.org/10.1007/BF02731859 .

Farrow, G . Measurement of the smectic content in undrawn polypropylene filaments . J. Appl. Polym. Sci. , 1965 . 9 1227 - 1232 . DOI: 10.1002/app.1965.070090404 http://doi.org/10.1002/app.1965.070090404 .

Miller, R. L . On the existence of near-range order in isotactic polypropylenes . Polymer , 1960 . 1 135 - 143 . DOI: 10.1016/0032-3861(60)90021-5 http://doi.org/10.1016/0032-3861(60)90021-5 .

Hosemann, R . Paracrystalline fine structure of natural and synthetic proteins Visual method for the determination of the oscillation tensors of the cell edges . Acta Crystallogr. , 1951 . 4 520 - 530 . .

Bodor, G.; Grell, M.; Kallo, A . Determination of the crystallinity of polypropylene . Faserforsch Textiltech. , 1964 . 15 527 - 532 . .

Grebowicz, J.; Lau, S. F.; Wunderlich, B . The thermal properties of polypropylene . J. Polym. Sci., Part C: Polym. Sym. , 1984 . 71 19 - 37 . .

Corradini, P.; Petraccone, V.; De Rosa, C.; Guerra, G . On the structure of the quenched mesomorphic phase of isotactic polypropylene . Macromolecules , 1986 . 19 2699 - 2703 . DOI: 10.1021/ma00165a006 http://doi.org/10.1021/ma00165a006 .

Qiu, J.; Wang, Z.; Yang, L.; Zhao, J.; Niu, Y.; Hsiao, B. S . Deformation-induced highly oriented and stable mesomorphic phase in quenched isotactic polypropylene . Polymer , 2007 . 48 6934 - 6947 . DOI: 10.1016/j.polymer.2007.08.066 http://doi.org/10.1016/j.polymer.2007.08.066 .

Koerner, H.; Luo, Y.; Li, X.; Cohen, C.; Hedden, R. C.; Ober, C. K . Structural studies of extension-induced mesophase formation in poly(diethylsiloxane) elastomers: In situ synchrotron WAXS and SAXS . Macromolecules , 2003 . 36 1975 - 1981 . DOI: 10.1021/ma020856j http://doi.org/10.1021/ma020856j .

Ran, S.; Wang, Z.; Burger, C.; Chu, B.; Hsiao, B. S . Mesophase as the precursor for strain-induced crystallization in amorphous poly(ethylene terephthalate) film . Macromolecules , 2002 . 35 10102 - 10107 . DOI: 10.1021/ma021252i http://doi.org/10.1021/ma021252i .

Carr, P. L.; Nicholson, T. M.; Ward, I. M . Mesophase structures in poly(ethylene terephthalate), poly(ethylene naphthalate) and poly(ethylene naphthalate bibenzoate) . Polym. Adv. Technol. , 1997 . 8 592 - 600 . DOI: 10.1002/(ISSN)1099-1581 http://doi.org/10.1002/(ISSN)1099-1581 .

García Gutiérrez, M. C.; Karger-Kocsis, J.; Riekel, C . Cold drawing-induced mesophase in amorphous poly(ethylene naphthalate) revealed by X-ray microdiffraction . Macromolecules , 2002 . 35 7320 - 7325 . DOI: 10.1021/ma020468h http://doi.org/10.1021/ma020468h .

Dorgan, J . Polylactic acid: Properties and prospects of an environmentally benign plastic from renewable resources . Macromol. Symp. , 2001 . 175 145 - 149 . .

Gross, R. A.; Kalra, B . Biodegradable polymers for the environment . Science , 2002 . 297 803 - 807 . DOI: 10.1126/science.297.5582.803 http://doi.org/10.1126/science.297.5582.803 .

Pan, P.; Inoue, Y . Polymorphism and isomorphism in biodegradable polyesters . Prog. Polym. Sci. , 2009 . 34 605 - 640 . DOI: 10.1016/j.progpolymsci.2009.01.003 http://doi.org/10.1016/j.progpolymsci.2009.01.003 .

De Santis, P.; Kovacs, J . Molecular conformation of poly(S‐lactic acid) . Biopolymers , 1968 . 6 299 - 306 . DOI: 10.1002/(ISSN)1097-0282 http://doi.org/10.1002/(ISSN)1097-0282 .

Hoogsteen, W.; Postema, A. R.; Pennings, A. J.; ten Brinke, G.; Zugenmaier, P . Crystal structure, conformation and morphology of solution-spun poly(L-lactide) fibers . Macromolecules , 1990 . 23 634 - 642 . DOI: 10.1021/ma00204a041 http://doi.org/10.1021/ma00204a041 .

Kalb, B.; Pennings, A. J . General crystallization behaviour of poly(L-lactic acid) . Polymer , 1980 . 21 607 - 612 . DOI: 10.1016/0032-3861(80)90315-8 http://doi.org/10.1016/0032-3861(80)90315-8 .

Puiggali, J.; Ikada, Y.; Tsuji, H.; Cartier, L.; Okihara, T.; Lotz, B . The frustrated structure of poly(L-lactide) . Polymer , 2000 . 41 8921 - 8930 . DOI: 10.1016/S0032-3861(00)00235-4 http://doi.org/10.1016/S0032-3861(00)00235-4 .

Cartier, L.; Okihara, T.; Ikada, Y.; Tsuji, H.; Puiggali, J.; Lotz, B . Epitaxial crystallization and crystalline polymorphism of polylactides . Polymer , 2000 . 41 8909 - 8919 . DOI: 10.1016/S0032-3861(00)00234-2 http://doi.org/10.1016/S0032-3861(00)00234-2 .

Zhang, J.; Duan, Y.; Sato, H.; Tsuji, H.; Noda, I.; Yan, S.; Ozaki, Y . Crystal modifications and thermal behavior of poly (L-lactic acid) revealed by infrared spectroscopy . Macromolecules , 2005 . 38 8012 - 8021 . DOI: 10.1021/ma051232r http://doi.org/10.1021/ma051232r .

Stoclet, G.; Seguela, R.; Lefebvre, J. M.; Elkoun, S.; Vanmansart, C . Strain-induced molecular ordering in polylactide upon uniaxial stretching . Macromolecules , 2010 . 43 1488 - 1498 . DOI: 10.1021/ma9024366 http://doi.org/10.1021/ma9024366 .

Stoclet, G.; Seguela, R.; Lefebvre, J. M.; Rochas, C . New insights on the strain-induced mesophase of poly(D, L-lactide): In situ WAXS and DSC study of the thermo-mechanical stability . Macromolecules , 2010 . 43 7228 - 7237 . DOI: 10.1021/ma101430c http://doi.org/10.1021/ma101430c .

Zhang, J.; Duan, Y.; Domb, A. J.; Ozaki, Y . PLLA mesophase and its phase transition behavior in the PLLA-PEG-PLLA copolymer as revealed by infrared spectroscopy . Macromolecules , 2010 . 43 4240 - 4246 . DOI: 10.1021/ma100301h http://doi.org/10.1021/ma100301h .

Wasanasuk, K.; Tashiro, K . Structural regularization in the crystallization process from the glass or melt of poly(L-lactic acid) viewed from the temperature-dependent and time-resolved measurements of FTIR and wide-angle/small-angle X-ray scatterings . Macromolecules , 2011 . 44 9650 - 9660 . DOI: 10.1021/ma2017666 http://doi.org/10.1021/ma2017666 .

Wasanasuk, K.; Tashiro, K . Theoretical and experimental evaluation of crystallite moduli of various crystalline forms of poly(L-lactic acid) . Macromolecules , 2012 . 45 7019 - 7026 . DOI: 10.1021/ma3010982 http://doi.org/10.1021/ma3010982 .

Lv, R.; Na, B.; Tian, N.; Zou, S.; Li, Z.; Jiang, S . Mesophase formation and its thermal transition in the stretched glassy polylactide revealed by infrared spectroscopy . Polymer , 2011 . 52 4979 - 4984 . DOI: 10.1016/j.polymer.2011.08.023 http://doi.org/10.1016/j.polymer.2011.08.023 .

Hu, J.; Zhang, T.; Gu, M.; Chen, X.; Zhang, J . Spectroscopic analysis on cold drawing-induced PLLA mesophase . Polymer , 2012 . 53 4922 - 4926 . DOI: 10.1016/j.polymer.2012.09.012 http://doi.org/10.1016/j.polymer.2012.09.012 .

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