<italic style="font-style: italic">β</italic>-Phase Crystallization of Poly(vinylidene fluoride) in Poly(vinylidene fluoride)/Poly(ethyl methacrylate) Blends

Zi-Jie Huang; Jing Jiang; Gi Xue; Dong-Shan Zhou

doi:10.1007/s10118-019-2177-4

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β-Phase Crystallization of Poly(vinylidene fluoride) in Poly(vinylidene fluoride)/Poly(ethyl methacrylate) Blends

ARTICLE | Updated：2021-02-18

- β-Phase Crystallization of Poly(vinylidene fluoride) in Poly(vinylidene fluoride)/Poly(ethyl methacrylate) Blends
- Chinese Journal of Polymer Science Vol. 37, Issue 1, Pages: 94-100(2019)
- Affiliations：
  
  a.Department of Polymer Science and Engineering, School of Chemistry and Chemical Engineering, Key Laboratory of High Performance Polymer Materials and Technology, and The State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093, China
  b.School of Physical Science and Technology, Xinjiang Key Laboratory and Phase Transitions and Microstructures in Condensed Matters, Yili Normal University, Yining 835000, China
- Author bio：
  
  dzhou@nju.edu.cn
- Funds：
- DOI：10.1007/s10118-019-2177-4
  CLC：
- Received：31 May 2018，
  
  Revised：2018-7-27，
  
  Accepted：31 July 2018，
  
  Online First：30 August 2018，
  
  Published：2019-01
- Accepted：
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Citation: Huang, Z. J.; Jiang, J.; Xue, G.; Zhou, D. S. , β,-Phase crystallization of poly(vinylidene fluoride) in poly(vinylidene fluoride)/poly(ethyl methacrylate) blends. Chinese J. Polym. Sci. 2019, 37, 94–100

Zi-Jie Huang, Jing Jiang, Gi Xue, et al. β-Phase Crystallization of Poly(vinylidene fluoride) in Poly(vinylidene fluoride)/Poly(ethyl methacrylate) Blends[J]. Chinese Journal of Polymer Science, 2019, 37(1): 94-100. DOI: 10.1007/s10118-019-2177-4.
Citation: Huang, Z. J.; Jiang, J.; Xue, G.; Zhou, D. S. , β,-Phase crystallization of poly(vinylidene fluoride) in poly(vinylidene fluoride)/poly(ethyl methacrylate) blends. Chinese J. Polym. Sci. 2019, 37, 94–100 DOI： 10.1007/s10118-019-2177-4.

Zi-Jie Huang, Jing Jiang, Gi Xue, et al. β-Phase Crystallization of Poly(vinylidene fluoride) in Poly(vinylidene fluoride)/Poly(ethyl methacrylate) Blends[J]. Chinese Journal of Polymer Science, 2019, 37(1): 94-100. DOI: 10.1007/s10118-019-2177-4. DOI：

摘要

Abstract

The nature of the crystalline phase of poly(vinylidene fluoride) (PVDF) in compatible blends with poly(ethyl methacrylate) (PEMA) was investigated by using X-ray diffraction (XRD)

infrared microscopy (IR) and differential scanning calorimetry (DSC). The

phase of PVDF was observed after quenching from the melt and further annealing above the glass transition temperature over a composition range. The PVDF/PEMA blend with weight ratio of 3:2 has formed higher content of PVDF

crystals than others. By taking advantage of fast cooling rate of ultrafast differential scanning calorimeter (UFDSC)

the quenching process of blends was modeled and tested simultaneously

and the melting behavior of

crystals in all blends was investigated. Three types of crystallization behavior of

phase PVDF in blends were found after quenching-annealing at different temperatures.

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Abraham, K. M.; Alamgir, M . Li + -conductive solid polymer electrolytes with liquid-like conductivity . J. Electrochem. Soc. , 1990 . 137 1657 - 1658 . DOI: 10.1149/1.2086749 http://doi.org/10.1149/1.2086749 .

Passerini, S.; Rosolen, J. M.; Scrosati, B . Plasticized carbon electrodes of interest for lithium rocking chair batteries . J. Power Sources , 1993 . 45 333 - 341 . DOI: 10.1016/0378-7753(93)80022-H http://doi.org/10.1016/0378-7753(93)80022-H .

Choe, H. S.; Giaccai, J.; Alamgir, M.; Abraham, K. M . Preparation and characterization of poly(vinyl sulfone)- and poly(vinylidene fluoride)-based electrolytes . Electrochim. Acta , 1995 . 40 2289 - 2293 . DOI: 10.1016/0013-4686(95)00180-M http://doi.org/10.1016/0013-4686(95)00180-M .

Lovinger, A. J . Crystallization of the β phase of poly(vinylidene fluoride) from the melt . Polymer , 1981 . 22 412 - 413 . DOI: 10.1016/0032-3861(81)90058-6 http://doi.org/10.1016/0032-3861(81)90058-6 .

Kim, J. C.; Yong, J. C.; Kim, Y. H . Factors determining the formation of the β crystalline phase of poly(vinylidene fluoride) in poly(vinylidene fluoride)-poly(methyl methacrylate) blends . Vib. Spectrosc. , 1995 . 9 147 - 159 . DOI: 10.1016/0924-2031(94)00092-U http://doi.org/10.1016/0924-2031(94)00092-U .

Salimi, A.; Yousefi, A. A . Analysis method: FTIR studies of β -phase crystal formation in stretched PVDF films . Polym. Test. , 2003 . 22 699 - 704 . DOI: 10.1016/S0142-9418(03)00003-5 http://doi.org/10.1016/S0142-9418(03)00003-5 .

Benz, M.; Euler, W. B.; Gregory, O. J . The role of solution phase water on the deposition of thin films of poly(vinylidene fluoride) . Macromolecules , 2002 . 35 2682 - 2688 . DOI: 10.1021/ma011744f http://doi.org/10.1021/ma011744f .

Yang, J.; Wang, J.; Zhang, Q.; Chen, F.; Deng, H.; Wang, K.; Fu, Q . Cooperative effect of shear and nanoclay on the formation of polar phase in poly(vinylidene fluoride) and the resultant properties . Polymer , 2011 . 52 4970 - 4978 . DOI: 10.1016/j.polymer.2011.08.051 http://doi.org/10.1016/j.polymer.2011.08.051 .

Li, M.; Stingelin, N.; Michels, J. J.; Spijkman, M. J.; Asadi, K.; Feldman, K.; Blom, P. W. M.; de Leeuw, D. M . Ferroelectric phase diagram of PVDF:PMMA . Macromolecules , 2012 . 45 7477 - 7485 . DOI: 10.1021/ma301460h http://doi.org/10.1021/ma301460h .

Sajkiewicz, P.; Wasiak, A.; Gocłowski, Z . Phase transitions during stretching of poly(vinylidene fluoride) . Eur. Polym. J. , 1999 . 35 423 - 429 . DOI: 10.1016/S0014-3057(98)00136-0 http://doi.org/10.1016/S0014-3057(98)00136-0 .

Ferreira, A.; Costa, P.; Carvalho, H.; Nobrega, J. M.; Sencadas, V.; Lanceros-Mendez, S . Extrusion of poly(vinylidene fluoride) filaments: Effect of the processing conditions and conductive inner core on the electroactive phase content and mechanical properties . J. Polym. Res. , 2011 . 18 1653 - 1658 . DOI: 10.1007/s10965-011-9570-1 http://doi.org/10.1007/s10965-011-9570-1 .

Gonçalves, R.; Martins, P. M.; Caparrós, C.; Martins, P.; Benelmekki, M.; Botelho, G.; Lanceros-Mendez, S.; Lasheras, A.; Gutiérrez, J.; Barandiarán, J. M . Nucleation of the electroactive β -phase, dielectric and magnetic response of poly(vinylidene fluoride) composites with Fe 2 O 3 nanoparticles . J. Non-Cryst. Solids , 2013 . 361 93 - 99 . DOI: 10.1016/j.jnoncrysol.2012.11.003 http://doi.org/10.1016/j.jnoncrysol.2012.11.003 .

Voet, V. S. D.; Hermida-Merino, D.; ten Brinke, G.; Loos, K . Block copolymer route towards poly(vinylidene fluoride)/poly(methacrylic acid)/nickel nanocomposites . RSC Adv. , 2013 . 3 7938 - 7946 . DOI: 10.1039/c3ra40365c http://doi.org/10.1039/c3ra40365c .

Wu, Y.; Hsu, S. L.; Honeker, C.; Bravet, D. J.; Williams, D. S . The role of surface charge of nucleation agents on the crystallization behavior of poly(vinylidene fluoride) . J. Phys. Chem. B , 2012 . 116 7379 - 7388 . DOI: 10.1021/jp3043494 http://doi.org/10.1021/jp3043494 .

Jia, N.; Xing, Q.; Xia, G.; Sun, J.; Song, R.; Huang, W . Enhanced β -crystalline phase in poly(vinylidene fluoride) films by polydopamine-coated BaTiO 3 nanoparticles . Mater. Lett. , 2015 . 139 212 - 215 . DOI: 10.1016/j.matlet.2014.10.069 http://doi.org/10.1016/j.matlet.2014.10.069 .

Yu, J. H.; Jiang, P. K.; Wu, C.; Wang, L. C.; Wu, X. F . Graphene nanocomposites based on poly(vinylidene fluoride): Structure and properties . Polym. Compos. , 2011 . 32 1483 - 1491 . DOI: 10.1002/pc.v32.10 http://doi.org/10.1002/pc.v32.10 .

Leonard, C.; Halary, J. L.; Monnerie, L . Crystallization of poly(vinylidene fluoride) poly(methyl methacrylate) blends: Analysis of the molecular parameters controlling the nature of the poly(vinylinene fluoride) crystalline phase . Macromolecules , 1988 . 21 2988 - 2994 . DOI: 10.1021/ma00188a016 http://doi.org/10.1021/ma00188a016 .

Guo, H. F.; Li, Z. S.; Dong, S. W.; Chen, W. J.; Deng, L.; Wang, Y. F.; Ying, D. J . Piezoelectric PU/PVDF electrospun scaffolds for wound healing applications . Colloid. Surface B , 2012 . 96 29 - 36 . DOI: 10.1016/j.colsurfb.2012.03.014 http://doi.org/10.1016/j.colsurfb.2012.03.014 .

Chaudhari, S.; Sharma, Y.; Archana, P. S.; Jose, R.; Ramakrishna, S.; Mhaisalkar, S.; Srinivasan, M . Electrospun polyaniline nanofibers web electrodes for supercapacitors . J. Appl. Polym. Sci. , 2013 . 129 1660 - 1668 . DOI: 10.1002/app.v129.4 http://doi.org/10.1002/app.v129.4 .

Leonard, C.; Halary, J. L.; Monnerie, L.; Broussoux, D.; Servet, B.; Micheron, F . FTIR evidence of beta-crystal phase formation in PVDF PMMA blends . Polym. Commun. , 1983 . 24 110 - 114 . .

Naber, R. C. G.; Tanase, C.; Blom, P. W. M.; Gelinck, G. H.; Marsman, A. W.; Touwslager, F. J.; Setayesh, S.; De Leeuw, D. M . High-performance solution-processed polymer ferroelectric field-effect transistors . Nat. Mater. , 2005 . 4 243 - 248 . DOI: 10.1038/nmat1329 http://doi.org/10.1038/nmat1329 .

Naber, R. C. G.; Asadi, K.; Blom, P. W. M.; De Leeuw, D. M.; De Boer, B . Organic nonvolatile memory devices based on ferroelectricity . Adv. Mater. , 2010 . 22 933 - 945 . DOI: 10.1002/adma.200900759 http://doi.org/10.1002/adma.200900759 .

Khan, M. A.; Bhansali, U. S.; Alshareef, H. N . High-performance non-volatile organic ferroelectric memory on banknotes . Adv. Mater. , 2012 . 24 2165 - 2170 . DOI: 10.1002/adma.201200626 http://doi.org/10.1002/adma.201200626 .

Asadi, K.; De Leeuw, D. M.; De Boer, B.; Blom, P. W. M . Organic non-volatile memories from ferroelectric phase-separated blends . Nat. Mater. , 2008 . 7 547 - 550 . DOI: 10.1038/nmat2207 http://doi.org/10.1038/nmat2207 .

Asadi, K.; Li, M.; Stingelin, N.; Blom, P. W. M.; De Leeuw, D. M . Crossbar memory array of organic bistable rectifying diodes for nonvolatile data storage . Appl. Phys. Lett. , 2010 . 97 193308 DOI: 10.1063/1.3508948 http://doi.org/10.1063/1.3508948 .

Asadi, K.; Li, M.; Blom, P. W. M.; Kemerink, M.; De Leeuw, D. M . Organic ferroelectric opto-electronic memories . Mater. Today , 2011 . 14 592 - 599 . DOI: 10.1016/S1369-7021(11)70300-5 http://doi.org/10.1016/S1369-7021(11)70300-5 .

Feuillade, G.; Perche, P . Ion-conductive macromolecular gels and membranes for solid lithium cells . J. Appl. Electrochem. , 1975 . 5 63 - 69 . DOI: 10.1007/BF00625960 http://doi.org/10.1007/BF00625960 .

Han, H. S.; Kang, H. R.; Kim, S. W.; Kim, H. T . Phase-separated polymer electrolyte based on poly(vinyl chloride)/poly(ethyl methacrylate) blend . J. Power Sources , 2002 . 112 461 - 468 . DOI: 10.1016/S0378-7753(02)00436-6 http://doi.org/10.1016/S0378-7753(02)00436-6 .

Alsaigh, Z. Y.; Chen, P . Characterization of semicrystalline polymers by inverse gas-chromatography. 2. A blend of poly(vinylidene fluoride) and poly(ethylmethacrylate) . Macromolecules , 1991 . 24 3788 - 3795 . DOI: 10.1021/ma00013a008 http://doi.org/10.1021/ma00013a008 .

Jiang, J.; Zhuravlev, E.; Huang, Z.; Wei, L.; Xu, Q.; Shan, M.; Xue, G.; Zhou, D.; Schick, C.; Jiang, W . A transient polymorph transition of 4-cyano-4′-octyloxybiphenyl (8OCB) revealed by ultrafast differential scanning calorimetry (UFDSC) . Soft Matter , 2013 . 9 1488 - 1491 . DOI: 10.1039/C2SM27012A http://doi.org/10.1039/C2SM27012A .

Jiang, J.; Zhuravlev, E.; Hu, W. B.; Schick, C.; Zhou, D. S . The effect of self-nucleation on isothermal crystallization kinetics of poly(butylene succinate) (PBS) investigated by differential fast scanning calorimetry . Chinese J. Polym. Sci. , 2017 . 35 1009 - 1019 . DOI: 10.1007/s10118-017-1942-5 http://doi.org/10.1007/s10118-017-1942-5 .

Gregorio, R . Determination of the alpha, beta, and gamma crystalline phases of poly(vinylidene fluoride) films prepared at different conditions . J. Appl. Polym. Sci. , 2006 . 100 3272 - 3279 . DOI: 10.1002/(ISSN)1097-4628 http://doi.org/10.1002/(ISSN)1097-4628 .

Zhuravlev, E.; Schick, C . Fast scanning power compensated differential scanning nano-calorimeter: 1 The device . Thermochim. Acta , 2010 . 505 1 - 13 . DOI: 10.1016/j.tca.2010.03.019 http://doi.org/10.1016/j.tca.2010.03.019 .

Zhuravlev, E.; Schick, C . Fast scanning power compensated differential scanning nano-calorimeter: 2 Heat capacity analysis . Thermochim. Acta , 2010 . 505 14 - 21 . .

Gradys, A.; Sajkiewicz, P.; Zhuravlev, E.; Schick, C . Kinetics of isothermal and non-isothermal crystallization of poly(vinylidene fluoride) by fast scanning calorimetry . Polymer , 2016 . 82 40 - 48 . DOI: 10.1016/j.polymer.2015.11.020 http://doi.org/10.1016/j.polymer.2015.11.020 .

Wei, L.; Jiang, J.; Shan, M.; Chen, W.; Deng, Y.; Xue, G.; Zhou, D . Integration of ultrafast scanning calorimetry with micro-Raman spectroscopy for investigation of metastable materials . Rev. Sci. Instrum. , 2014 . 85 074901 DOI: 10.1063/1.4889882 http://doi.org/10.1063/1.4889882 .

Zhuravlev, E.; Schmelzer, J. W. P.; Wunderlich, B.; Schick, C . Kinetics of nucleation and crystallization in poly(epsilon caprolactone) (PCL) . Polymer , 2011 . 52 1983 - 1997 . DOI: 10.1016/j.polymer.2011.03.013 http://doi.org/10.1016/j.polymer.2011.03.013 .

Wunderlich, B. in Crystal structure, Morphology, Defects . Vol. 1. Academic Press, New York, 1973 , 1-552.

Hoffman, J. D.; Weeks, J. J . Melting process and the equilibrium melting temperature of polychlorotrifluoroethylene . J. Res. Nat. Bur. Stand. A , 1962 . 66A 13 - 28 . DOI: 10.6028/jres.066A.003 http://doi.org/10.6028/jres.066A.003 .

Hellmuth, E.; Wunderlich, B . Superheating of linear high-polymer polyethylene crystals . J. Appl. Phys. , 1965 . 36 3039 - 3044 . DOI: 10.1063/1.1702924 http://doi.org/10.1063/1.1702924 .

Minakov, A.; Wurm, A.; Schick, C . Superheating in linear polymers studied by ultrafast nanocalorimetry . Eur. Polym. J. E , 2007 . 23 43 - 53 . .

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β-Phase Crystallization of Poly(vinylidene fluoride) in Poly(vinylidene fluoride)/Poly(ethyl methacrylate) Blends

DOI：10.1007/s10118-019-2177-4

摘要

Abstract

关键词

Keywords

references