A Comparison Study of Physicochemical Properties and Stabilities of H-Shaped Molecule and the Corresponding Polymer

Quan-You Feng; Bin Li; Zong-Yan Zuo; Song-Lin Xie; Meng-Na Yu; Bin Liu; Ying Wei; Ling-Hai Xie; Rui-Dong Xia; Wei Huang

doi:10.1007/s10118-018-2152-5

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A Comparison Study of Physicochemical Properties and Stabilities of H-Shaped Molecule and the Corresponding Polymer

ARTICLE | Updated：2021-02-18

- A Comparison Study of Physicochemical Properties and Stabilities of H-Shaped Molecule and the Corresponding Polymer
- Chinese Journal of Polymer Science Vol. 37, Issue 1, Pages: 11-17(2019)
- Affiliations：
  
  a.Center for Molecular Systems and Organic Devices (CMSOD), Key Laboratory for Organic Electronics and Information Displays & Jiangsu Key Laboratory for Biosensors, Institute of Advanced Materials (IAM), Jiangsu National Synergetic Innovation Center for Advanced Materials (SICAM), Nanjing University of Posts & Telecommunications, Nanjing 210023, China
  b.Shaanxi Institute of Flexible Electronics (SIFE), Northwestern Polytechnical University (NPU), Xi’an 710072, China
- Author bio：
  
  iamlhxie@njupt.edu.cn
- Funds：
- DOI：10.1007/s10118-018-2152-5
  CLC：
- Received：26 March 2018，
  
  Revised：2018-5-4，
  
  Accepted：05 May 2018，
  
  Online First：01 June 2018，
  
  Published：2019-01
- Accepted：
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Citation: Feng, Q. Y.; Li, B.; Zuo, Z. Y.; Xie, S. L.; Yu, M. N.; Liu, B.; Wei, Y.; Xie, L. H.; Xia, R. D.; Huang, W. A comparison study of physicochemical properties and stabilities of H-shaped molecule and the corresponding polymer. Chinese J. Polym. Sci. 2019, 37, 11–17

Quan-You Feng, Bin Li, Zong-Yan Zuo, et al. A Comparison Study of Physicochemical Properties and Stabilities of H-Shaped Molecule and the Corresponding Polymer[J]. Chinese Journal of Polymer Science, 2019, 37(1): 11-17.
Citation: Feng, Q. Y.; Li, B.; Zuo, Z. Y.; Xie, S. L.; Yu, M. N.; Liu, B.; Wei, Y.; Xie, L. H.; Xia, R. D.; Huang, W. A comparison study of physicochemical properties and stabilities of H-shaped molecule and the corresponding polymer. Chinese J. Polym. Sci. 2019, 37, 11–17 DOI： 10.1007/s10118-018-2152-5.

Quan-You Feng, Bin Li, Zong-Yan Zuo, et al. A Comparison Study of Physicochemical Properties and Stabilities of H-Shaped Molecule and the Corresponding Polymer[J]. Chinese Journal of Polymer Science, 2019, 37(1): 11-17. DOI： 10.1007/s10118-018-2152-5.

摘要

Abstract

Rare attention has been paid to the comparison between a monomer and its corresponding polymer in terms of the optoelectronic characteristics. In this article

a model H-shaped molecule and its corresponding polymer

both of which exhibited similar properties including blue emission and solution processing

were designed and synthesized. Optoelectronic properties and various kinds of stability features

including the thermostabilities

spectral stabilities and amplified spontaneous emission characteristic of the monomer and polymer were investigated. In general

the corresponding polymer

exhibited similar optoelectronic properties but deteriorated stabilities compared with its H-shaped monomer

H-1

probably owing to the similar chemical structure but the wider molecular weight distribution and metal catalyst residue. Importantly

monomer

H-1

displayed a comparable ASE threshold value with its polymer

suggesting that H-shaped fluorene-based small molecules may be more promising optical gain media in solid state amplifers and lasers.

关键词

Keywords

references

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