Improving Damping Properties and Thermal Stability of Epoxy/Polyurethane Grafted Copolymer by Adding Glycidyl POSS

Ge-Liang Zhu; Di Han; Ye Yuan; Feng Chen; Qiang Fu

doi:10.1007/s10118-018-2145-4

Your Location：

Home >

Browse articles >

Improving Damping Properties and Thermal Stability of Epoxy/Polyurethane Grafted Copolymer by Adding Glycidyl POSS

ARTICLE | Updated：2021-02-18

- Improving Damping Properties and Thermal Stability of Epoxy/Polyurethane Grafted Copolymer by Adding Glycidyl POSS
- Chinese Journal of Polymer Science Vol. 36, Issue 11, Pages: 1297-1302(2018)
- Affiliations：
  
  College of Polymer Science and Engineering, State Key Laboratory of Polymer Materials Engineering, Sichuan University, Chengdu 610065, China
- Author bio：
  
  fengchen@scu.edu.cn (F.C.)
  qiangfu@scu.edu.cn (Q.F.)
- Funds：
- DOI：10.1007/s10118-018-2145-4
  CLC：
- Received：07 March 2018，
  
  Accepted：28 April 2018，
  
  Online First：01 June 2018，
  
  Published：2018-11
- Accepted：
Scan QR Code
Citation: Zhu, G. L.; Han, D.; Yuan, Y.; Chen, F.; Fu, Q. Improving Damping Properties and Thermal Stability of Epoxy/Polyurethane Grafted Copolymer by Adding Glycidyl POSS. Chinese J. Polym. Sci. 2018, 36(11), 1297–1302.

Ge-Liang Zhu, Di Han, Ye Yuan, et al. Improving Damping Properties and Thermal Stability of Epoxy/Polyurethane Grafted Copolymer by Adding Glycidyl POSS[J]. Chinese Journal of Polymer Science, 2018, 36(11): 1297-1302.
Citation: Zhu, G. L.; Han, D.; Yuan, Y.; Chen, F.; Fu, Q. Improving Damping Properties and Thermal Stability of Epoxy/Polyurethane Grafted Copolymer by Adding Glycidyl POSS. Chinese J. Polym. Sci. 2018, 36(11), 1297–1302. DOI： 10.1007/s10118-018-2145-4.

Ge-Liang Zhu, Di Han, Ye Yuan, et al. Improving Damping Properties and Thermal Stability of Epoxy/Polyurethane Grafted Copolymer by Adding Glycidyl POSS[J]. Chinese Journal of Polymer Science, 2018, 36(11): 1297-1302. DOI： 10.1007/s10118-018-2145-4.

摘要

Abstract

Modified castor oil-based epoxy resin (EP)/polyurethane (PU) grafted copolymer by glycidyl polyhedral oligomeric silsesquioxane (glycidyl POSS) was synthesized. The damping properties

thermal stability

mechanical properties and morphology of the grafted copolymer modified by glycidyl POSS were studied systematically. The results revealed that the incorporation of glycidyl POSS improved the damping performance evidently and broadened damping temperature range

especially when the glycidyl POSS content was 0.2%–1%. At the same time

there was a slight increase in thermal stability with the increase of POSS content. The tensile properties changed with the change of the copolymer’s

decreased at low POSS contents and increased at high POSS contents. This modified copolymer has the potential to be used as film damping material or constrained damping layer.

关键词

Keywords

references

Moreira, R.; Rodrigues, J. D . Constrained damping layer treatments: Finite element modeling . Modal. Anal. , 2004 . 10 ( 4 ): 575 - 595 . DOI: 10.1177/1077546304039060 http://doi.org/10.1177/1077546304039060 .

Johnson, C. D.; Kienholzm, D. A . Finite element prediction of damping in structures with constrained viscoelastic layers . AIAA. J. , 1982 . 20 ( 9 ): 1284 - 1290 . DOI: 10.2514/3.51190 http://doi.org/10.2514/3.51190 .

Remillat. C . Damping mechanism of polymers filled with elastic particles . Mech. Mater. , 2007 . 39 ( 6 ): 525 - 537 . DOI: 10.1016/j.mechmat.2006.08.001 http://doi.org/10.1016/j.mechmat.2006.08.001 .

Sperling L. H.; Hu. R. in "Interpenetrating polymer networks, polymer blends handbook". Springer. Netherlands, 2014, 677-724.

Merlin. D. L.; Sivasankar. B . Synthesis and characterization of semi-interpenetrating polymer networks using biocompatible polyurethane and acrylamide monomer . Eur. Polym. J. , 2009 . 45 ( 1 ): 165 - 170 . DOI: 10.1016/j.eurpolymj.2008.10.012 http://doi.org/10.1016/j.eurpolymj.2008.10.012 .

Cristea, M.; Bruma, M.; Ibanescu, S.; Cascaval, C. N.; Rosu, D . Dynamic mechanical analysis of polyurethane-epoxy interpenetrating polymer networks . High Perform. Polym. , 2009 . 21 ( 5 ): 608 - 623 . DOI: 10.1177/0954008309339940 http://doi.org/10.1177/0954008309339940 .

Chen, S.; Wang, Q.; Pei, X.; Wang, T . Dynamic mechanical properties of castor oil-based polyurethane/epoxy graft interpenetrating polymer network composites . J. Appl. Polym. Sci. , 2010 . 118 ( 2 ): 1144 - 1151 . .

Suhr, J.; Koratkar, N.; Keblinski, P.; Ajayan, P . Viscoelasticity in carbon nanotube composites . Nat. Mater. , 2005 . 4 ( 2 ): 134 - 137 . DOI: 10.1038/nmat1293 http://doi.org/10.1038/nmat1293 .

Chen, S.; Wang, Q.; Wang, T . Damping, thermal, and mechanical properties of carbon nanotubes modified castor oil-based polyurethane/epoxy interpenetrating polymer network composites . Mater. Design , 2012 . 38 47 - 52 . DOI: 10.1016/j.matdes.2012.02.003 http://doi.org/10.1016/j.matdes.2012.02.003 .

Chen, S.; Wang, Q.; Wang, T . Damping, thermal, and mechanical properties of montmorillonite modified castor oil-based polyurethane/epoxy graft IPN composites . Mater. Chem. Phys. , 2011 . 130 ( 1-2 ): 680 - 684 . DOI: 10.1016/j.matchemphys.2011.07.044 http://doi.org/10.1016/j.matchemphys.2011.07.044 .

Chen, S.; Wang, Q.; Wang, T.; Pei, X . Preparation, damping and thermal properties of potassium titanate whiskers filled castor oil-based polyurethane/epoxy interpenetrating polymer network composites . Mater. Design , 2011 . 32 ( 2 ): 803 - 807 . DOI: 10.1016/j.matdes.2010.07.021 http://doi.org/10.1016/j.matdes.2010.07.021 .

Raftopoulos, K. N.; Pielichowski, K . Segmental dynamics in hybrid polymer/POSS nanomaterials . Prog. Polym. Sci. , 2016 . 52 136 - 187 . DOI: 10.1016/j.progpolymsci.2015.01.003 http://doi.org/10.1016/j.progpolymsci.2015.01.003 .

Vannier, A.; Duquesne, S.; Bourbigot, S.; Castrovinci, A.; Camino, G.; Delobel, R . The use of POSS as synergist in intumescent recycled poly(ethylene terephthalate) . Polym. Degrad. Stab. , 2008 . 93 ( 4 ): 818 - 826 . DOI: 10.1016/j.polymdegradstab.2008.01.016 http://doi.org/10.1016/j.polymdegradstab.2008.01.016 .

Huang, X.; Zhi, C.; Jiang, P.; Golberg, D.; Bando, Y.; Tanaka, T . Polyhedral oligosilsesquioxane-modified boron nitride nanotube based epoxy nanocomposites: an ideal dielectric material with high thermal conductivity . Adv. Funct. Mater. , 2013 . 23 ( 14 ): 1824 - 1831 . DOI: 10.1002/adfm.v23.14 http://doi.org/10.1002/adfm.v23.14 .

Huang, H.; Chen, B.; Wang, Z.; Hung, T. F.; Susha, A. S.; Zhong, H.; Rogach, A. L . Water resistant CsPbX 3 nanocrystals coated with polyhedral oligomeric silsesquioxane and their use as solid state luminophores in all-perovskite white light-emitting devices . Chem. Sci. , 2016 . 7 ( 9 ): 5699 - 5703 . DOI: 10.1039/C6SC01758D http://doi.org/10.1039/C6SC01758D .

Gu, J.; Liang, C.; Dang, J.; Dong, W.; Zhang, Q . Ideal dielectric thermally conductive bismaleimide nanocomposites filled with polyhedral oligomeric silsesquioxane functionalized nanosized boron nitride . RSC Adv. , 2016 . 6 ( 42 ): 35809 - 35814 . DOI: 10.1039/C6RA04513H http://doi.org/10.1039/C6RA04513H .

Bu, Y.; Sun, G.; Zhang, L . POSS-modified PEG adhesives for wound closure . Chinese J. Polym. Sci. , 2017 . 35 ( 10 ): 1231 - 1242 . DOI: 10.1007/s10118-017-1958-x http://doi.org/10.1007/s10118-017-1958-x .

Schwab, J. J.; Lichtenhan, J. D . Polyhedral oligomeric silsesquioxane (POSS)-based polymers . Appl. Organomet. Chem. , 1998 . 12 ( 10-11 ): 707 - 713 . DOI: 10.1002/(ISSN)1099-0739 http://doi.org/10.1002/(ISSN)1099-0739 .

Matějka, L.; Strachota, A.; Pleštil, J . Epoxy networks reinforced with polyhedral oligomeric silsesquioxanes (POSS) . Structure and morphology. Macromolecules , 2004 . 37 ( 25 ): 9449 - 9456 . .

Zhang, W.; Camino, G.; Yang, R . Polymer/polyhedral oligomeric silsesquioxane (POSS) nanocomposites: An overview of fire retardance . Prog. Polym. Sci. , 2017 . 67 77 - 125 . DOI: 10.1016/j.progpolymsci.2016.09.011 http://doi.org/10.1016/j.progpolymsci.2016.09.011 .

Song, J.; Chen, G.; Wu, G.; Cai, C.; Liu, P.; Li, Q . Thermal and dynamic mechanical properties of epoxy resin/poly(urethane-imide)/polyhedral oligomeric silsesquioxane nanocomposites . Polym. Adv. Technol. , 2011 . 22 ( 12 ): 2069 - 2074 . DOI: 10.1002/pat.v22.12 http://doi.org/10.1002/pat.v22.12 .

Views

117

Downloads

CSCD

Alert me when the article has been cited

Submit

Tools

Publicity Resources

Two-way Shape Memory Effect of Polycaprolactone-based Polyurethane via Synergistic Role of Hydrogen Bonding and Crystallization Tuned by Malic Acid

Soft-segment-engineered Self-healing Polyurethane for High-performance Electrorheological Elastomers and Capacitive Sensors

Modulating Molecular Weight of Polyethylenes from Oligomer to Polymer Using Highly Thermal Stable Cationic α-Diimine Palladium Complexes

Phase Equilibrium Analysis of Ternary Systems Based on an Epoxy Oligomer, Polysulfone, and Tetraethoxysilane

Circularly Polarized Luminescence Based on Helical Polymers: Structure-Property Relationships and Regulation Mechanisms

Related Author

Xue-Qing Li

Shuai Lu

Jun-Jie Tan

Bo Lv

Hong-Ye Yan

Yan Tang

Yu Zhou

Yang Zhou

Related Institution

School of Chemistry and Chemical Engineering, Wuhan University of Science and Technology

School of Textile Science and Engineering, State Key Laboratory of New Textile Materials and Advanced Processing Technology, Wuhan Textile University

Hubei Key Laboratory of Pollutant Analysis & Reuse Technology, Hubei Normal University

Center for Advanced Structural Materials, State Key Lab of Metastable Materials Science and Technology, and College of Materials Science and Engineering, Yanshan University

Department of Polymer Science and Engineering, Inha University

⁰