

FOLLOWUS
a.Department of Materials Science and Technology, Faculty of Science, Prince of Songkla University, Hat-Yai, Songkhla 90110, Thailand
b.Institut Européen des Membranes, IEM–UMR5635, ENSCM, CNRS, Univ Montpellier, Montpellier, France
watchanida.c@psu.ac.th
Received:02 January 2018,
Revised:2018-4-1,
Accepted:18 April 2018,
Online First:29 May 2018,
Published:2018-10
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Citation: Phomdum, P.; Gassara, S.; Deratani, A.; Chinpa, W. Enhancement of Resistance to Protein Fouling of Poly(ether imide) Membrane by Surface Grafting with PEG under Organic Solvent-free Condition. Chinese J. Polym. Sci. 2018, 36, 1157–1167.
Pattama Phomdum, Sana Gassara, André Deratani, et al. Enhancement of Resistance to Protein Fouling of Poly(ether imide) Membrane by Surface Grafting with PEG under Organic Solvent-free Condition[J]. Chinese Journal of Polymer Science, 2018, 36(10): 1157-1167.
Citation: Phomdum, P.; Gassara, S.; Deratani, A.; Chinpa, W. Enhancement of Resistance to Protein Fouling of Poly(ether imide) Membrane by Surface Grafting with PEG under Organic Solvent-free Condition. Chinese J. Polym. Sci. 2018, 36, 1157–1167. DOI: 10.1007/s10118-018-2144-5.
Pattama Phomdum, Sana Gassara, André Deratani, et al. Enhancement of Resistance to Protein Fouling of Poly(ether imide) Membrane by Surface Grafting with PEG under Organic Solvent-free Condition[J]. Chinese Journal of Polymer Science, 2018, 36(10): 1157-1167. DOI: 10.1007/s10118-018-2144-5.
Poly(ether imide) (PEI) membrane with enhanced antifouling property was successfully prepared in a mild and simple procedure. The virgin membrane was firstly functionalized with an aqueous solution of diamino-terminated poly(ethylene oxide) block copolymer (PEG-diamine). Glutaraldehyde was used in a second step as a linker to chemically attach additional PEG-diamine to the primary amine groups grafted on PEI membrane surface. Immobilization of PEG segments was confirmed using Fourier transform infrared spectroscopy
X-ray photoelectron spectroscopy
scanning electron microscopy and atomic force microscopy. Ultrafiltration experiments revealed that the enhancement of a PEG coverage on the membrane surface provided superior anti-protein-fouling property. Cycles of protein filtration also demonstrated that the antifouling surface was stable over time and excellent ultrafiltration performance could be maintained without the need of harsh cleansing operation.
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