Enolic Schiff Base Zinc Amide Complexes: Highly Active Catalysts for Ring-Opening Polymerization of Lactide and <italic style="font-style: italic">ε</italic>-Caprolactone

Chen-Yang Hu; Ran-Long Duan; Jing-Wei Yang; Shu-Jun Dong; Zhi-Qiang Sun; Xuan Pang; Xian-Hong Wang; Xue-Si Chen

doi:10.1007/s10118-018-2129-4

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Enolic Schiff Base Zinc Amide Complexes: Highly Active Catalysts for Ring-Opening Polymerization of Lactide and ε-Caprolactone

ARTICLE | Updated：2021-02-18

- Enolic Schiff Base Zinc Amide Complexes: Highly Active Catalysts for Ring-Opening Polymerization of Lactide and ε-Caprolactone
- Chinese Journal of Polymer Science Vol. 36, Issue 10, Pages: 1123-1128(2018)
- Affiliations：
  
  a.Key Laboratory of Polymer Ecomaterials, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China
  b.University of Chinese Academy of Sciences, Beijing 100049, China
  c.Department of Materials Science and Engineering, Jilin University, Changchun 130025, China
  d.VIP Department, Stomatological Hospital of Jilin University, Changchun 130021, China
- Author bio：
  
  xpang@ciac.ac.cn (X.P.)
  xschen@ciac.ac.cn (X.S.C.)
- Funds：
- DOI：10.1007/s10118-018-2129-4
  CLC：
- Received：23 January 2018，
  
  Accepted：13 February 2018，
  
  Online First：16 April 2018，
  
  Published：2018-10
- Accepted：
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Citation: Hu, C. Y.; Duan, R. L.; Yang, J. W.; Dong, S. J.; Sun, Z. Q.; Pang, X.; Wang, X. H.; Chen, X. S. Enolic Schiff Base Zinc Amide Complexes: Highly Active Catalysts for Ring-Opening Polymerization of Lactide and ε-Caprolactone. Chinese J. Polym. Sci. 2018, 36(10), 1123–1128.

Chen-Yang Hu, Ran-Long Duan, Jing-Wei Yang, et al. Enolic Schiff Base Zinc Amide Complexes: Highly Active Catalysts for Ring-Opening Polymerization of Lactide and ε-Caprolactone[J]. Chinese Journal of Polymer Science, 2018, 36(10): 1123-1128. DOI: 10.1007/s10118-018-2129-4.
Citation: Hu, C. Y.; Duan, R. L.; Yang, J. W.; Dong, S. J.; Sun, Z. Q.; Pang, X.; Wang, X. H.; Chen, X. S. Enolic Schiff Base Zinc Amide Complexes: Highly Active Catalysts for Ring-Opening Polymerization of Lactide and ε-Caprolactone. Chinese J. Polym. Sci. 2018, 36(10), 1123–1128. DOI： 10.1007/s10118-018-2129-4.

Chen-Yang Hu, Ran-Long Duan, Jing-Wei Yang, et al. Enolic Schiff Base Zinc Amide Complexes: Highly Active Catalysts for Ring-Opening Polymerization of Lactide and ε-Caprolactone[J]. Chinese Journal of Polymer Science, 2018, 36(10): 1123-1128. DOI: 10.1007/s10118-018-2129-4. DOI：

摘要

Abstract

A series of zinc silylamido complexes based upon

NNO

tridentate enolic Schiff base framework have been synthesized and characterized. These complexes were tested for the ring opening polymerization of lactide and

-caprolactone

exhibiting notably high activity at ambient temperature. The influence of imine bridge length and substituents of diketone over the course of polymerization was investigated in details. Remarkably

was confirmed to be a rare example of exceedingly active and robust zinc catalysts

achieving major transformation of lactide under extremely low loading (0.025 mol%) within 18 min. The influence of various monomers as well as the polymerization mechanism have also been discussed.

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references

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Enolic Schiff Base Zinc Amide Complexes: Highly Active Catalysts for Ring-Opening Polymerization of Lactide and ε-Caprolactone

DOI：10.1007/s10118-018-2129-4

摘要

Abstract

关键词

Keywords

references