Massive Preparation of Coumarone-indene Resin-based Hyper-crosslinked Polymers for Gas Adsorption

Ke Tian; Ting-Ting Zhu; Ping Lan; Zheng-Chen Wu; Wei Hu; Fei-Fei Xie; Lei Li

doi:10.1007/s10118-018-2127-6

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Massive Preparation of Coumarone-indene Resin-based Hyper-crosslinked Polymers for Gas Adsorption

ARTICLE | Updated：2021-02-18

- Massive Preparation of Coumarone-indene Resin-based Hyper-crosslinked Polymers for Gas Adsorption
- Chinese Journal of Polymer Science Vol. 36, Issue 10, Pages: 1168-1174(2018)
- Affiliations：
  
  a.College of Materials and Fujian Provincial Key Laboratory of Materials Genome, Xiamen University, Xiamen 361005, China
  b.Material and Textile College, Jiaxing University, Jiaxing 314000, China
- Author bio：
  
  lanping007@126.com (P.L.)
  lilei@xmu.edu.cn (L.L.)
- Funds：
- DOI：10.1007/s10118-018-2127-6
  CLC：
- Received：04 January 2018，
  
  Revised：2018-1-4，
  
  Accepted：13 February 2018，
  
  Online First：28 March 2018，
  
  Published：2018-10
- Accepted：
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Citation: Tian, K.; Zhu, T. T.; Lan, P.; Wu, Z. C.; Hu, W.; Xie, F. F.; Li, L. Massive Preparation of Coumarone-indene Resin-based Hyper-crosslinked Polymers for Gas Adsorption. Chinese J. Polym. Sci. 2018, 36(10), 1168–1174.

Ke Tian, Ting-Ting Zhu, Ping Lan, et al. Massive Preparation of Coumarone-indene Resin-based Hyper-crosslinked Polymers for Gas Adsorption[J]. Chinese Journal of Polymer Science, 2018, 36(10): 1168-1174.
Citation: Tian, K.; Zhu, T. T.; Lan, P.; Wu, Z. C.; Hu, W.; Xie, F. F.; Li, L. Massive Preparation of Coumarone-indene Resin-based Hyper-crosslinked Polymers for Gas Adsorption. Chinese J. Polym. Sci. 2018, 36(10), 1168–1174. DOI： 10.1007/s10118-018-2127-6.

Ke Tian, Ting-Ting Zhu, Ping Lan, et al. Massive Preparation of Coumarone-indene Resin-based Hyper-crosslinked Polymers for Gas Adsorption[J]. Chinese Journal of Polymer Science, 2018, 36(10): 1168-1174. DOI： 10.1007/s10118-018-2127-6.

摘要

Abstract

Hyper-crosslinked polymers (HCPs) are promising materials for gas capture and storage because of their low cost and easy preparation. In this work

we report the massive preparation of coumarone-indene resin-based hyper-crosslinked polymers

via

one-step Friedel-Crafts alkylation. Low-cost coumarone-indene resin serves as the new building block and chloroform is employed as both solvent and external crosslinker. A maximum surface area of 966 m

·g

−1

is achieved

which is comparable with that of previously-reported coal tar-based porous organic polymers. Most importantly

a large number of heteroatoms including inherent oxygen atoms and introduced chlorine atoms in obtianed HCPs further enhance the interaction between specific sorbate molecule and adsorbent. Therefore

optimal structural and chemical property endow the new coumarone-indene resin-based HCPs with decent gas storage capacity (14.60 wt% at 273 K and 0.1 MPa for CO

; 1.18 wt% at 77.3 K and 0.1 MPa for H

). These results demonstrate that new HCPs are potential candidates for applications in CO

and H

capture.

关键词

Keywords

references

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