The Silk Textile Embedded in Silk Fibroin Composite: Preparation and Properties

Yu Duan; Xin Chen; Zheng-Zhong Shao

doi:10.1007/s10118-018-2117-8

Your Location：

Home >

Browse articles >

The Silk Textile Embedded in Silk Fibroin Composite: Preparation and Properties

ARTICLE | Updated：2021-02-18

- The Silk Textile Embedded in Silk Fibroin Composite: Preparation and Properties
- Chinese Journal of Polymer Science Vol. 36, Issue 9, Pages: 1043-1046(2018)
- Affiliations：
  
  State Key Laboratory of Molecular Engineering of Polymers, Department of Macromolecular Science, Laboratory of Advanced Materials, Fudan University, Shanghai 200433, China
- Author bio：
  
  zzshao@fudan.edu.cn
- Funds：
- DOI：10.1007/s10118-018-2117-8
  CLC：
- Received：03 January 2018，
  
  Revised：2018-1-30，
  
  Accepted：30 January 2018，
  
  Online First：27 March 2018，
  
  Published：2018-09
- Accepted：
Scan QR Code
Yu Duan, Xin Chen, Zheng-Zhong Shao. The Silk Textile Embedded in Silk Fibroin Composite: Preparation and Properties[J]. Chinese Journal of Polymer Science, 2018, 36(9): 1043-1046.
DOI：

Yu Duan, Xin Chen, Zheng-Zhong Shao. The Silk Textile Embedded in Silk Fibroin Composite: Preparation and Properties[J]. Chinese Journal of Polymer Science, 2018, 36(9): 1043-1046. DOI： 10.1007/s10118-018-2117-8.

摘要

Abstract

Silk reinforced silk-fibroin-based composites were prepared by embedding of silk textile into regenerated silk fibroin (RSF) matrix. The breaking stress and breaking strain of the composites were found 37.7 MPa and 71.1% respectively at (95 ± 5)% RH. Morphological analysis was carried out to observe fracture behavior of the samples. The

in vitro

biodegradation test showed that the composite degraded slowly and lost 70% weight at the end of 168 h. Moreover

compared with RSF pure film

the composite kept strength and toughness much longer time. In conclusion

this composite has the potential for more accurate cytology research and biomedical tests in the future.

关键词

Keywords

references

Altman, G. H.; Diaz, F.; Jakuba, C.; Calabro, T.; Horan, R. L.; Chen, J.; Lu, H.; Richmond, J.; Kaplan, D. L . Silk-based biomaterials . Biomaterials , 2003 . 24 ( 3 ): 401 - 416 . DOI: 10.1016/S0142-9612(02)00353-8 http://doi.org/10.1016/S0142-9612(02)00353-8 .

Rockwood, D. N.; Preda, R. C.; Yücel, T.; Wang, X.; Lovett, M. L.; Kaplan, D. L . Materials fabrication from Bombyx mori silk fibroin . Nat. Protoc. , 2011 . 6 ( 10 ): 1612 - 1631 . DOI: 10.1038/nprot.2011.379 http://doi.org/10.1038/nprot.2011.379 .

Sun, H. X.; Wang, S.; Zhu, H. S . Surface modification of blend films composed of silk fibroin and poly(ethylene glycol) macromer and their in vitro antithrombogenicity . Chinese J. Polym. Sci. , 2004 . 22 ( 4 ): 399 - 403 . .

Melke, J.; Midha, S.; Ghosh, S.; Ito, K.; Hofmann, S . Silk fibroin as biomaterial for bone tissue engineering . Acta Biomater. , 2016 . 31 1 - 16 . DOI: 10.1016/j.actbio.2015.09.005 http://doi.org/10.1016/j.actbio.2015.09.005 .

Wang, Q.; Yang, Y. H.; Chen, X.; Shao, Z. Z . Investigation of rheological properties and conformation of silk fibroin in the solution of AmimCl . Biomacromolecules , 2012 . 13 ( 6 ): 1875 - 1881 . DOI: 10.1021/bm300387z http://doi.org/10.1021/bm300387z .

Hu, X.; Kaplan, D. L.; Cebe, P . Effect of water on the thermal properties of silk fibroin . Thermochim. Acta , 2007 . 461 137 - 144 . DOI: 10.1016/j.tca.2006.12.011 http://doi.org/10.1016/j.tca.2006.12.011 .

Motta, A.; Fambri, L.; Migliaresi, C . Regenerated silk fibroin films: thermal and dynamic mechanical analysis . Macromol. Chem. Phys. , 2002 . 203 1658 - 1665 . DOI: 10.1002/1521-3935(200207)203:10/11<1658::AID-MACP1658>3.0.CO;2-3 http://doi.org/10.1002/1521-3935(200207)203:10/11<1658::AID-MACP1658>3.0.CO;2-3 .

Faruk, O . Biocomposites reinforced with natural fibers: 2000–2010 . Prog. Polym. Sci. , 2012 . 37 1552 - 1596 . DOI: 10.1016/j.progpolymsci.2012.04.003 http://doi.org/10.1016/j.progpolymsci.2012.04.003 .

Yao, H.; Niu, J. L.; Zhang, J.; Ning, N. Y.; Yang, X. Q.; Tian, M.; Sun, X. L.; Zhang, L. Q.; Yan, S. L . Morphologies and mechanical properties of cis -1,4-butadiene rubber/polyethylene blends . Chinese J. Polym. Sci. , 2016 . 34 ( 7 ): 820 - 829 . DOI: 10.1007/s10118-016-1794-4 http://doi.org/10.1007/s10118-016-1794-4 .

Azwa, Z.; Yousif, B.; Manalo, A.; Karunasena, W . A review on the degradability of polymeric composites based on natural fibres . Mater. Design , 2013 . 47 ( 9 ): 424 - 442 . DOI: 10.1016/j.matdes.2012.11.025 http://doi.org/10.1016/j.matdes.2012.11.025 .

Han, S. O.; Lee, S. M.; Park, W. H.; Cho, D . Mechanical and thermal properties of waste silk fiber-reinforced poly(butylene succinate) biocomposites . J. Appl. Polym. Sci. , 2006 . 100 4972 - 4980 . DOI: 10.1002/(ISSN)1097-4628 http://doi.org/10.1002/(ISSN)1097-4628 .

Yuan, Q. Q.; Yao, J. R.; Chen, X.; Huang, L.; Shao, Z. Z . The preparation of high performance silk fiber/fibroin composite . Polymer , 2010 . 51 4843 - 4849 . DOI: 10.1016/j.polymer.2010.08.042 http://doi.org/10.1016/j.polymer.2010.08.042 .

Luo, K. Y.; Yang, Y. H.; Shao, Z. Z . Physically crosslinked biocompatible silk-fibroin-based hydrogels with high mechanical performance . Adv. Funct. Mater. , 2016 . 26 872 - 880 . DOI: 10.1002/adfm.v26.6 http://doi.org/10.1002/adfm.v26.6 .

Zhou, H.; Shao, Z. Z.; Chen, X . Wet-spinning of regenerated silk fiber from aqueous silk fibroin solutions: influence of calcium ion addition in spinning dope on the performance of regenerated silk fiber . Chinese J. Polym. Sci. , 2014 . 32 ( 1 ): 29 - 34 . DOI: 10.1007/s10118-014-1368-2 http://doi.org/10.1007/s10118-014-1368-2 .

Numata, K.; Cebe, P.; Kaplan, D. L . Mechanism of enzymatic degradation of beta-sheet crystals . Biomaterials , 2010 . 31 2926 - 2933 . DOI: 10.1016/j.biomaterials.2009.12.026 http://doi.org/10.1016/j.biomaterials.2009.12.026 .

Porter, D.; Vollrath, F.; Tian, K.; Chen, X.; Shao, Z. Z . A kinetic model for thermal degradation in polymers with specific application to proteins . Polymer , 2009 . 50 ( 7 ): 1814 - 1818 . DOI: 10.1016/j.polymer.2009.01.064 http://doi.org/10.1016/j.polymer.2009.01.064 .

Views

206

Downloads

CSCD

Alert me when the article has been cited

Submit

Tools

Publicity Resources

Improvements of Hydrophobicity and Toughness of Epoxy Coatings Modified with Hydroxyl-terminated Fluororubber

Effects of Different Nucleating Agents, Annealing and Pre-stretching Process on the Crystallinity and Mechanical Properties of Poly(butylene carbonate)

Advancing the Thin-film Mechanics of Conjugated Polymers: Characterization, Modulation, and Innovation

Enhanced Mechanical Properties and Prolonged Recovery Onset Period of Timed Shape Memory Hydrogels via Hydrophobic Interaction

A Phosphorus/Nitrogen-containing Phosphaphenanthrene Derivative as Flame Retardant for Poly(lactic acid)

Related Author

Yu-Tong Zhou

You-Fan Wu

Qian-Qian Yang

Hai-Bao Zhang

Ting Zhang

Hao-Yan Guo

Zhen-Jun Wang

Gang Li

Related Institution

School of Materials Science and Engineering, Chang’an University

Shaanxi Union Research Center of University and Enterprise for Advanced Transportation Infrastructure Materials

College of Water Conservancy & Architectural Engineering, Shihezi University

Chengdu Institute of Organic Chemistry, Chinese Academy of Sciences

University of Chinese Academy of Sciences

⁰