Dewetting Behavior of Hydrogen Bonded Polymer Complex Film under Hydrothermal Condition

Chao Su; Song-Mei Ma; Geng-Xin Liu; Shu-Guang Yang

doi:10.1007/s10118-018-2109-8

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Dewetting Behavior of Hydrogen Bonded Polymer Complex Film under Hydrothermal Condition

ARTICLE | Updated：2021-02-18

- Dewetting Behavior of Hydrogen Bonded Polymer Complex Film under Hydrothermal Condition
- Chinese Journal of Polymer Science Vol. 36, Issue 9, Pages: 1036-1042(2018)
- Affiliations：
  
  a.State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, Center for Advanced Low-dimension Materials, College of Material Science and Engineering, Donghua University, Shanghai 201620, China
  b.Department of Polymer Science, The University of Akron, OH 44325, USA
- Author bio：
  
  shgyang@dhu.edu.cn
- Funds：
- DOI：10.1007/s10118-018-2109-8
  CLC：
- Received：13 December 2017，
  
  Revised：2018-1-4，
  
  Accepted：10 January 2018，
  
  Online First：15 March 2018，
  
  Published：2018-09
- Accepted：
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Chao Su, Song-Mei Ma, Geng-Xin Liu, et al. Dewetting Behavior of Hydrogen Bonded Polymer Complex Film under Hydrothermal Condition[J]. Chinese Journal of Polymer Science, 2018, 36(9): 1036-1042.
DOI：

Chao Su, Song-Mei Ma, Geng-Xin Liu, et al. Dewetting Behavior of Hydrogen Bonded Polymer Complex Film under Hydrothermal Condition[J]. Chinese Journal of Polymer Science, 2018, 36(9): 1036-1042. DOI： 10.1007/s10118-018-2109-8.

摘要

Abstract

Hydrogen-bonded polymer complex films with the thickness ranging from 50 nm to 2400 nm were prepared by layer-by-layer (LbL) assembly of poly(2-ethyl-2-oxazoline) (PEOX) and poly(acrylic acid) (PAA). The dewetting behavior of PEOX/PAA films under hydrothermal condition was investigated. It was found that the dewetting occurred at solid-liquid interface

and the typical morphologies such as holes

irregular cellular structure

and droplets were observed. Atomic force microscopy (AFM) revealed the initial rupture of the film. Microscopic Raman and infrared (IR) imaging demonstrated that the PEOX and PAA chains remained association during the dewetting process.

关键词

Keywords

references

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