Prominently Promoting the Formation of Poly(butylene adipate) <italic style="font-style: italic">α</italic>-Form Crystals by Coalescing from Inclusion Complex

Hai-Mu Ye; Xiao-Tong Chen; Ping Liu; Na Yan

doi:10.1007/s10118-018-2095-x

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Prominently Promoting the Formation of Poly(butylene adipate) α-Form Crystals by Coalescing from Inclusion Complex

ARTICLE | Updated：2021-02-18

- Prominently Promoting the Formation of Poly(butylene adipate) α-Form Crystals by Coalescing from Inclusion Complex
- Chinese Journal of Polymer Science Vol. 36, Issue 7, Pages: 866-870(2018)
- Affiliations：
  
  Department of Materials Science and Engineering, China University of Petroleum, Beijing 102249, China
- Author bio：
  
  yehaimu@cup.edu.cn
- Funds：
- DOI：10.1007/s10118-018-2095-x
  CLC：
- Received：12 October 2017，
  
  Accepted：23 November 2017，
  
  Online First：11 February 2018，
  
  Published：2018-07
- Accepted：
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Hai-Mu Ye, Xiao-Tong Chen, Ping Liu, et al. Prominently Promoting the Formation of Poly(butylene adipate) α-Form Crystals by Coalescing from Inclusion Complex[J]. Chinese Journal of Polymer Science, 2018, 36(7): 866-870. DOI: 10.1007/s10118-018-2095-x.
DOI：

Hai-Mu Ye, Xiao-Tong Chen, Ping Liu, et al. Prominently Promoting the Formation of Poly(butylene adipate) α-Form Crystals by Coalescing from Inclusion Complex[J]. Chinese Journal of Polymer Science, 2018, 36(7): 866-870. DOI: 10.1007/s10118-018-2095-x. DOI：

摘要

Abstract

We successfully use a co-precipitation method to prepare inclusion complex between poly(butylene adipate) (PBA) chains (guest component) and urea molecules (host component). The PBA/urea inclusion complex is confirmed to adopt a hexagonal crystal modification with lattice parameters of

= 8.14 Å and

= 10.92 Å

and the interaction between PBA chains and urea is van der Waals force. The singly isolated PBA chains are suggested to take some

gauche

conformation

which is different from the all-

trans

conformation in

-form PBA. Furthermore

we employ the isolated PBA chains which are uniformly pre-established in a specific conformation in urea channels to regulate the crystal form of PBA for the first time. After removing the host urea molecules

the coalesced PBA chains are found to solely crystallize into

-form crystals at different coalescing temperatures. By comparing the FTIR spectra

it is found that PBA chains in inclusion complex plausibly contain some similar conformers as those in

-form crystal

which is suggested to be the intrinsic reason for the sole formation of

-form crystals. This research proves that inclusion complex can be used as a very effective method to regulate polymorphism of semi-crystalline polymers.

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Keywords

references

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Prominently Promoting the Formation of Poly(butylene adipate) α-Form Crystals by Coalescing from Inclusion Complex

DOI：10.1007/s10118-018-2095-x

摘要

Abstract

关键词

Keywords

references