Near-Infrared-Emissive Self-assembled Polymers <italic style="font-style: italic">via</italic> the Implementation of Molecular Tweezer/Guest Complexation on a Supramolecular Coordination Complex Platform

Zong-Chun Gao; Cheng-Peng Wei; Yi-Fei Han; Ming Yuan; Xu-Zhou Yan; Feng Wang

doi:10.1007/s10118-018-2090-2

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Near-Infrared-Emissive Self-assembled Polymers via the Implementation of Molecular Tweezer/Guest Complexation on a Supramolecular Coordination Complex Platform

ARTICLES | Updated：2021-02-18

- Near-Infrared-Emissive Self-assembled Polymers via the Implementation of Molecular Tweezer/Guest Complexation on a Supramolecular Coordination Complex Platform
- Chinese Journal of Polymer Science Vol. 36, Issue 3, Pages: 399-405(2018)
- Affiliations：
  
  a.Chinese Academy of Sciences Key Laboratory of Soft Matter Chemistry, Department of Polymer Science and Engineering, University of Science and Technology of China, Hefei 230026, China
  b.Department of Chemical Engineering, Stanford University, California 94305, United States
  c.Faculty of Pharmaceutical Engineering, Bengbu Medical College, Anhui Engineering Technology Research Center of Biochemical Pharmaceuticals, Bengbu 233030, China
- Author bio：
  
  Xu-Zhou Yan, E-mail xzyan@stanford.edu
  Feng Wang, E-mail drfwang@ustc.edu.cn
- Funds：
- DOI：10.1007/s10118-018-2090-2
  CLC：
- Received：01 October 2017，
  
  Accepted：10 November 2017，
  
  Online First：15 December 2017，
  
  Published：05 March 2018
- Accepted：
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Zong-Chun Gao, Cheng-Peng Wei, Yi-Fei Han, et al. Near-Infrared-Emissive Self-assembled Polymers via the Implementation of Molecular Tweezer/Guest Complexation on a Supramolecular Coordination Complex Platform[J]. Chinese Journal of Polymer Science, 2018, 36(3): 399-405. DOI: 10.1007/s10118-018-2090-2.
DOI：

Zong-Chun Gao, Cheng-Peng Wei, Yi-Fei Han, et al. Near-Infrared-Emissive Self-assembled Polymers via the Implementation of Molecular Tweezer/Guest Complexation on a Supramolecular Coordination Complex Platform[J]. Chinese Journal of Polymer Science, 2018, 36(3): 399-405. DOI: 10.1007/s10118-018-2090-2. DOI：

摘要

Abstract

Coordination-driven self-assembly strategy has demonstrated the efficiency and versatility to construct well-ordered supramolecular coordination complexes (SCCs) such as discrete metallacycles and metallacages. In recent years

it has aroused tremendous interest to build more complexed self-assembled structures

via

the implementation of additional non-covalent recognition motifs on the SCCs platform. In this work

we have successfully attained this objective

with the elaborate manipulation of non-interfering pyridine-Pt

and molecular tweezer/guest complexation in a hierarchical self-assembly manner. The resulting SCCs-based linear supramolecular polymers exhibit intriguing NIR-emissive behaviors

primarily attributed to the presence of intermolecular Pt(Ⅱ)-Pt(Ⅱ) metal-metal interactions in the non-covalent tweezering structure. Hence

supramolecular engineering of multiple non-covalent interactions offers a feasible avenue toward functional materials with tailored properties.

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references

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Near-Infrared-Emissive Self-assembled Polymers via the Implementation of Molecular Tweezer/Guest Complexation on a Supramolecular Coordination Complex Platform

DOI：10.1007/s10118-018-2090-2

摘要

Abstract

关键词

Keywords

references