Supramolecular Polymer Emulsifiers for One-step Complex Emulsions

Zhen Wang; Shenglong Liao; Yapei Wang

doi:10.1007/s10118-018-2084-0

Your Location：

Home >

Browse articles >

Supramolecular Polymer Emulsifiers for One-step Complex Emulsions

FEATURE ARTICLES | Updated：2021-02-18

- Supramolecular Polymer Emulsifiers for One-step Complex Emulsions
- Chinese Journal of Polymer Science Vol. 36, Issue 3, Pages: 288-296(2018)
- Affiliations：
  
  Department of Chemistry, Renmin University of China, Beijing 100872, China
- Author bio：
  
  Yapei Wang, E-mail yapeiwang@ruc.edu.cn
- Funds：
- DOI：10.1007/s10118-018-2084-0
  CLC：
- Received：27 September 2017，
  
  Accepted：12 November 2017，
  
  Online First：04 December 2017，
  
  Published：05 March 2018
- Accepted：
Scan QR Code
Zhen Wang, Shenglong Liao, Yapei Wang. Supramolecular Polymer Emulsifiers for One-step Complex Emulsions[J]. Chinese Journal of Polymer Science, 2018, 36(3): 288-296.
DOI：

Zhen Wang, Shenglong Liao, Yapei Wang. Supramolecular Polymer Emulsifiers for One-step Complex Emulsions[J]. Chinese Journal of Polymer Science, 2018, 36(3): 288-296. DOI： 10.1007/s10118-018-2084-0.

摘要

Abstract

Complex emulsions

such as double emulsions and high-internal-phase emulsions

have shown great applications in the fields of drug delivery

sensing

catalysis

oil-water separation and self-healing materials. Their controllable preparation is at the forefront of interface and material science. Surfactants and polymers have been widely used as emulsifiers for building complex emulsions. Yet some inherent disadvantages exist including multi-step emulsifications and low production efficiency. Alternatively

supramolecular polymer emulsifier for complex emulsions

via

one-step emulsification is rising as a new strategy due to the ease of preparation. In this feature article

we review our recent progresses in using supramolecular polymer emulsifiers for the preparation of complex emulsions. Double emulsions and high-internal-phase emulsions are successfully prepared

via

one-step emulsification with the help of different supramolecular interactions including electrostatic

hydrogen bond

coordination interaction and dynamic covalent bond

which will be particularly emphasized in detail. In the end

a comprehensive prospect is given for the future development of this field. This article is expected to provide new inspirations for preparing complex emulsions

via

supramolecular routes.

关键词

Keywords

references

J. Tang , P. J. Quinlan , K. C. Tam . Stimuli-responsive pickering emulsions:recent advances and potential applications . Soft Matter , 2015 . 11 ( 18 ): 3512 - 3529 . DOI: 10.1039/C5SM00247H http://doi.org/10.1039/C5SM00247H .

A. Gupta , H. B. Eral , T. A. Hatton , P. S. Doyle . Nanoemulsions:formation, properties and applications . Soft Matter , 2016 . 12 ( 11 ): 2826 - 2841 . DOI: 10.1039/C5SM02958A http://doi.org/10.1039/C5SM02958A .

A. Y. Khan , S. Talegaonkar , Z. Iqbal , F. J. Ahmed , R. K. Khar . Multiple emulsions:an overview . Curr. Drug Deliv. , 2006 . 3 ( 4 ): 429 - 43 . DOI: 10.2174/156720106778559056 http://doi.org/10.2174/156720106778559056 .

E. Dickinson . Stabilising emulsion-based colloidal structures with mixed food ingredients . J. Sci. Food Agr. , 2013 . 93 ( 4 ): 710 - 721 . DOI: 10.1002/jsfa.2013.93.issue-4 http://doi.org/10.1002/jsfa.2013.93.issue-4 .

D. J. McClements . Edible nanoemulsions:fabrication, properties, and functional performance . Soft Matter , 2011 . 7 ( 6 ): 2297 - 2316 . DOI: 10.1039/C0SM00549E http://doi.org/10.1039/C0SM00549E .

Y. Shi , Q. Yu , C. Sun , F. Dong , G. Yang , J. Feng . Progress in research work field with respect to physical stability of emulsion oil in water for pesticides . China Surfactant Detergent and Cosmetics , 2016 . 46 ( 3 ): 173 - 177 . http://agris.fao.org/agris-search/export!exportTopEndNoteXML.action?agrovocString=phenomena&onlyFullText=false http://agris.fao.org/agris-search/export!exportTopEndNoteXML.action?agrovocString=phenomena&onlyFullText=false , .

J. Feng , S. Xiang , K. Qian , F. Zhu , Q. Yu , X. Wu . Characterization methods for emulsion stability and their applications in the research and development for pesticide emulsions oil in water . J. Pestic. Sci. , 2015 . 17 ( 1 ): 15 - 26 . .

L. He , F. Lin , X. Li , H. Sui , Z. Xu . Interfacial sciences in unconventional petroleum production:from fundamentals to applications . Chem. Soc. Rev. , 2015 . 44 ( 15 ): 5446 - 5494 . DOI: 10.1039/C5CS00102A http://doi.org/10.1039/C5CS00102A .

H. Yang , L. Fu , L. Wei , J. Liang , B. P. Binks . Compartmentalization of incompatible reagents within Pickering emulsion droplets for one-pot cascade reactions . J. Am. Chem. Soc. , 2015 . 137 ( 3 ): 1362 - 1371 . DOI: 10.1021/ja512337z http://doi.org/10.1021/ja512337z .

H. Yang , T. Zhou , W. Zhang . A strategy for separating and recycling solid catalysts based on the pH-triggered Pickering-emulsion inversion . Angew. Chem. Int. Ed. , 2013 . 52 ( 29 ): 7455 - 7459 . DOI: 10.1002/anie.201300534 http://doi.org/10.1002/anie.201300534 .

F. X. Liang , Z. Z. Yang . Progress in Janus composites toward interfacial engineering . Acta Polymerica Sinica (in Chinese) , 2017 . ( 6 ): 883 - 892 . http://www.en.cnki.com.cn/Article_en/CJFDTotal-GFXB201706001.htm http://www.en.cnki.com.cn/Article_en/CJFDTotal-GFXB201706001.htm , .

Z. Q. Cao , G. J. Wang , Y. Chen , F. X. Lang , Z. Z. Yang . Light-triggered responsive Janus composite nanosheets . Macromolecules , 2015 . 48 ( 19 ): 7256 - 7261 . DOI: 10.1021/acs.macromol.5b01257 http://doi.org/10.1021/acs.macromol.5b01257 .

Z. G. Zhao , F. X. Liang , G. L. Zhang , X. Y. Ji , Q. Wang , X. Z. Qu , X. M. Song , Z. Z. Yang . Dually responsive Janus composite nanosheets . Macromolecules , 2015 . 48 ( 11 ): 3598 - 3603 . DOI: 10.1021/acs.macromol.5b00365 http://doi.org/10.1021/acs.macromol.5b00365 .

J. P. Xu , J. Li , Y. Yang , K. Wang , N. Xu , J. Y. Li , R. J. Liang , L. Shen , X. L. Xie , J. Tao , J. T. Zhu . Block copolymer capsules with structure-dependent release behavior . Angew. Chem. Int. Ed. , 2016 . 55 ( 47 ): 14633 - 14637 . DOI: 10.1002/anie.201607982 http://doi.org/10.1002/anie.201607982 .

M. Hussain , J. Xie , Z. Y. Hou , K. Shezad , J. P. Xu , K. Wang , Y. J. Gao , L. Shen , J. T. Zhu . Regulation of drug release by tuning surface textures of biodegradable polymer microparticles . ACS Appl. Mater. Interfaces , 2017 . 9 ( 16 ): 14391 - 14400 . DOI: 10.1021/acsami.7b02002 http://doi.org/10.1021/acsami.7b02002 .

Z. Wang , Y. Y. Cao , X. Y. Zhang , D. G. Wang , M. Liu , Z. G. Xie , Y. P. Wang . Rapid self-assembly of block copolymers for flower-like particles with high throughput . Langmuir , 2016 . 32 ( 50 ): 13517 - 13524 . DOI: 10.1021/acs.langmuir.6b03940 http://doi.org/10.1021/acs.langmuir.6b03940 .

J. H. Xia , S. B. Ji , H. P. Xu . Diselenide covalent chemistry at the interface:stabilizing an asymmetric diselenide-containing polymer via micelle formation . Polym. Chem. , 2016 . 7 ( 44 ): 6708 - 6713 . DOI: 10.1039/C6PY01610C http://doi.org/10.1039/C6PY01610C .

W. C. Wang , Y. X. Pan , K. Shi , C. Peng , X. L. Jia . Hierarchical porous polymer beads prepared by polymerizationinduced phase separation and emulsion-template in a microfluidic device . Chinese J. Polym. Sci. , 2014 . 32 ( 12 ): 1646 - 1654 . DOI: 10.1007/s10118-014-1547-1 http://doi.org/10.1007/s10118-014-1547-1 .

J. Liang , G. Zhang , G. Wang , B. Li , L. Wu . Construction of ordered porous polymer film and functionality of pore structure via microemulsion template method . Chinese Sci. Bull. , 2017 . 62 ( 6 ): 563 - 575 . DOI: 10.1360/N972016-00218 http://doi.org/10.1360/N972016-00218 .

X. Y. Yang , L. H. Chen , Y. Li , J. C. Rooke , C. Sanchez , B. L. Su . Hierarchically porous materials:synthesis strategies and structure design . Chem. Soc. Rev. , 2017 . 46 ( 2 ): 481 - 558 . DOI: 10.1039/C6CS00829A http://doi.org/10.1039/C6CS00829A .

L. Liu , L. Jiang , X. Xie , S. Yang . Amphiphilic carbonaceous microsphere-stabilized oil-in-water Pickering emulsions and their applications in enzyme catalysis . ChemPlusChem , 2016 . 81 ( 7 ): 629 - 636 . DOI: 10.1002/cplu.201600127 http://doi.org/10.1002/cplu.201600127 .

Z. Chen , C. Zhao , E. Ju , H. Ji , J. Ren , B. P. Binks , X. Qu . Design of surface-active artificial enzyme particles to stabilize Pickering emulsions for high-performance biphasic biocatalysis . Adv. Mater. , 2016 . 28 ( 8 ): 1682 - 1688 . DOI: 10.1002/adma.201504557 http://doi.org/10.1002/adma.201504557 .

H. Gao , J. Pan , D. Han , Y. Zhang , W. Shi , J. Zeng , Y. Peng , Y. Yan . Facile synthesis of microcellular foam catalysts with adjustable hierarchical porous structure, acid-base strength and wettability for biomass energy conversion . J. Mater. Chem. A , 2015 . 3 ( 25 ): 13507 - 13518 . DOI: 10.1039/C5TA02239H http://doi.org/10.1039/C5TA02239H .

X. Gu , Y. Ning , Y. Yang , C. Wang . One-step synthesis of porous graphene-based hydrogels containing oil droplets for drug delivery . RSC Adv. , 2014 . 4 ( 7 ): 3211 - 3218 . DOI: 10.1039/C3RA44993A http://doi.org/10.1039/C3RA44993A .

I. Pulko , P. Krajnc . High internal phase emulsion templating-a path to hierarchically porous functional polymers . Macromol. Rapid. Comm. , 2012 . 33 ( 20 ): 1731 - 1746 . DOI: 10.1002/marc.v33.20 http://doi.org/10.1002/marc.v33.20 .

N. Brun , S. Ungureanu , H. Deleuze , R. Backov . Hybrid foams, colloids and beyond:from design to applications . Chem. Soc. Rev. , 2011 . 40 ( 2 ): 771 - 788 . DOI: 10.1039/B920518G http://doi.org/10.1039/B920518G .

I. Pulko , J. Wall , P. Krajnc , N. R. Cameron . Ultra-high surface area functional porous polymers by emulsion templating and hypercrosslinking:efficient nucleophilic catalyst supports . Chem. Eur. J. , 2010 . 16 ( 8 ): 2350 - 2354 . DOI: 10.1002/chem.v16:8 http://doi.org/10.1002/chem.v16:8 .

N. Zhang , S. Zhong , T. Chen , Y. Zhou , W. Jiang . Emulsion-derived hierarchically porous polystyrene solid foam for oil removal from aqueous environment . RSC Adv. , 2017 . 7 ( 37 ): 22946 - 22953 . DOI: 10.1039/C7RA02953E http://doi.org/10.1039/C7RA02953E .

X. M. Na , F. Gao , L. Y. Zhang , Z. G. Su , G. H. Ma . Biodegradable microcapsules prepared by self-healing of porous microspheres . ACS Macro Lett. , 2012 . 1 ( 6 ): 697 - 700 . DOI: 10.1021/mz200222d http://doi.org/10.1021/mz200222d .

D. G. Wang , L. F. Xiao , X. Y. Zhang , K. Zhang , Y. P. Wang . Emulsion templating cyclic polymers as microscopic particles with tunable porous morphology . Langmuir , 2016 . 32 ( 6 ): 1460 - 1467 . DOI: 10.1021/acs.langmuir.5b04159 http://doi.org/10.1021/acs.langmuir.5b04159 .

S. B. Feng , D. H. Fu , L. Nie , P. Zou , J. P. Suo . A detailed view of PLGA-mPEG microsphere formation by double emulsion solvent evaporation method . Chinese J. Polym. Sci. , 2015 . 33 ( 7 ): 955 - 963 . DOI: 10.1007/s10118-015-1660-9 http://doi.org/10.1007/s10118-015-1660-9 .

Q. G. Wang , F. X. Liang , Q. Wang , X. Z. Qu , Z. Z. Yang . Responsive composite Janus cages . Chinese J. Polym. Sci. , 2015 . 33 ( 10 ): 1462 - 1469 . DOI: 10.1007/s10118-015-1691-2 http://doi.org/10.1007/s10118-015-1691-2 .

T. Zhang , Z. Xu , H. Gui , Q. Guo . Emulsion-templated, macroporous hydrogels for enhancing water efficiency in fighting fires . J. Mater. Chem. A , 2017 . 5 ( 21 ): 10161 - 10164 . DOI: 10.1039/C7TA02319G http://doi.org/10.1039/C7TA02319G .

P. Brown , C. P. Butts , J. Eastoe . Stimuli-responsive surfactants . Soft Matter , 2013 . 9 ( 8 ): 2365 - 2374 . DOI: 10.1039/c3sm27716j http://doi.org/10.1039/c3sm27716j .

Y. Liu , P. G. Jessop , M. Cunningham , C. A. Eckert , C. L. Liotta . Switchable surfactants . Science , 2006 . 313 ( 5789 ): 958 - 960 . DOI: 10.1126/science.1128142 http://doi.org/10.1126/science.1128142 .

X. P. Huang , Q. P. Qian , Y. P. Wang . Anisotropic particles from a one-pot double emulsion induced by partial wetting and their triggered release . Small , 2014 . 10 ( 7 ): 1412 - 1420 . DOI: 10.1002/smll.v10.7 http://doi.org/10.1002/smll.v10.7 .

A. L. B. Macon , S. U. Rehman , R. V. Bell , J. V. M. Weaver . Reversible assembly of pH responsive branched copolymer-stabilised emulsion via electrostatic forces . Chem. Commun. , 2016 . 52 ( 1 ): 136 - 139 . DOI: 10.1039/C5CC06636K http://doi.org/10.1039/C5CC06636K .

J. A. Hanson , C. B. Chang , S. M. Graves , Z. Li , T. G. Mason , T. J. Deming . Nanoscale double emulsions stabilized by single-component block copolypeptides . Nature , 2008 . 455 ( 7209 ): 85 - 88 . DOI: 10.1038/nature07197 http://doi.org/10.1038/nature07197 .

L. Hong , G. Sun , J. Cai , T. Ngai . One-step formation of W/O/W multiple emulsions stabilized by single amphiphilic block copolymers . Langmuir , 2012 . 28 ( 5 ): 2332 - 2336 . DOI: 10.1021/la205108w http://doi.org/10.1021/la205108w .

Q. Chen , T. Shi , F. Han , Z. Li , C. Lin , P. Zhao . Porous polystyrene monoliths and microparticles prepared from core cross-linked star (CCS) polymers-stabilized emulsions . Sci. Rep. , 2017 . 7 8493 DOI: 10.1038/s41598-017-09216-y http://doi.org/10.1038/s41598-017-09216-y .

G. Brusotti , E. Calleri , C. Milanese , L. Catenacci , G. Marrubini , M. Sorrenti , A. Girella , G. Massolini , G. Tripodo . Rational design of functionalized polyacrylate-based high internal phase emulsion materials for analytical and biomedical uses . Polym. Chem. , 2016 . 7 ( 48 ): 7436 - 7445 . DOI: 10.1039/C6PY01992G http://doi.org/10.1039/C6PY01992G .

R. T. Woodward , R. A. Slater , S. Higgins , S. P. Rannard , A. I. Cooper , B. J. L. Royles , P. H. Findlay , J. V. M. Weaver . Controlling responsive emulsion properties via polymer design . Chem. Commun. , 2009 . ( 24 ): 3554 - 3556 . DOI: 10.1039/b904320a http://doi.org/10.1039/b904320a .

B. Verdonck , E. J. Goethals , F. E. Du Prez . Block copolymers of methyl vinyl ether and isobutyl vinyl ether with thermo-adjustable amphiphilic properties . Macromol. Chem. Phys. , 2003 . 204 ( 17 ): 2090 - 2098 . DOI: 10.1002/(ISSN)1521-3935 http://doi.org/10.1002/(ISSN)1521-3935 .

G. Q. Sun , M. Liu , X. Zhou , L. Z. Hong , T. Ngai . Influence of asymmetric ratio of amphiphilic diblock copolymers on one-step formation and stability of multiple emulsions . Colloid. Surface. A , 2014 . 454 16 - 22 . DOI: 10.1016/j.colsurfa.2014.04.015 http://doi.org/10.1016/j.colsurfa.2014.04.015 .

N. H. Raduan , T. S. Horozov , T. K. Georgiou . "Comb-like" non-ionic polymeric macrosurfactants . Soft Matter , 2010 . 6 ( 10 ): 2321 - 2329 . DOI: 10.1039/b926822g http://doi.org/10.1039/b926822g .

P. Perrin , N. Monfreux , F. Lafuma . Highly hydrophobically modified polyelectrolytes stabilizing macroemulsions:relationship between copolymer structure and emulsion type . Colloid. Polym. Sci. , 1999 . 277 ( 1 ): 89 - 94 . DOI: 10.1007/s003960050372 http://doi.org/10.1007/s003960050372 .

H. K. Cho , K. S. Cho , J. H. Cho , S. W. Choi , J. H. Kim , I. W. Cheong . Synthesis and characterization of PEO-PCL-PEO triblock copolymers:effects of the PCL chain length on the physical property of W-1/O/W-2 multiple emulsions . Colloid. Surface B , 2008 . 65 ( 1 ): 61 - 68 . DOI: 10.1016/j.colsurfb.2008.02.017 http://doi.org/10.1016/j.colsurfb.2008.02.017 .

N. Garti , C. Bisperink . Double emulsions:progress and applications . Curr. Opin. Colloid In. , 1998 . 3 ( 6 ): 657 - 667 . DOI: 10.1016/S1359-0294(98)80096-4 http://doi.org/10.1016/S1359-0294(98)80096-4 .

F. Liang , K. Shen , X. Qu , C. Zhang , Q. Wang , J. Li , J. Liu , Z. Yang . Inorganic Janus nanosheets . Angew. Chem. Int. Ed. , 2011 . 50 ( 10 ): 2379 - 2382 . DOI: 10.1002/anie.201007519 http://doi.org/10.1002/anie.201007519 .

S. S. Datta , A. Abbaspourrad , E. Amstad , J. Fan , S. H. Kim , M. Romanowsky , H. C. Shum , B. Sun , A. S. Utada , M. Windbergs , S. Zhou , D. A. Weitz . 25th anniversary article:double emulsion templated solid microcapsules:mechanics and controlled release . Adv. Mater. , 2014 . 26 ( 14 ): 2205 - 18 . DOI: 10.1002/adma.v26.14 http://doi.org/10.1002/adma.v26.14 .

B. F. B. Silva , C. Rodríguez-Abreu , N. Vilanova . Recent advances in multiple emulsions and their application as templates . Curr. Opin. Colloid. Interface. Sci. , 2016 . 25 98 - 108 . DOI: 10.1016/j.cocis.2016.07.006 http://doi.org/10.1016/j.cocis.2016.07.006 .

S. Y. Wang , X. D. Shi , Z. H. Gan , F. Wang . Preparation of PLGA microspheres with different porous morphologies . Chinese J. Polym. Sci. , 2015 . 33 ( 1 ): 128 - 136 . DOI: 10.1007/s10118-014-1507-9 http://doi.org/10.1007/s10118-014-1507-9 .

W. C. Wang , C. Peng , K. Shi , Y. X. Pan , H. S. Zhang , X. L. Ji . Double emulsion droplets as microreactors for synthesis of magnetic macroporous polymer beads . Chinese J. Polym. Sci. , 2014 . 32 ( 12 ): 1639 - 1645 . DOI: 10.1007/s10118-014-1543-5 http://doi.org/10.1007/s10118-014-1543-5 .

W. C. Wang , K. Shi , Y. X. Pan , C. Peng , Z. L. Zhao , W. Liu , Y. G. Liu , X. L. Ji . Fabrication of polymersomes with controllable morphologies through dewetting W/O/W double emulsion droplets . Chinese J. Polym. Sci. , 2016 . 34 ( 4 ): 475 - 482 . DOI: 10.1007/s10118-016-1769-5 http://doi.org/10.1007/s10118-016-1769-5 .

S. Mashaghi , A. Abbaspourrad , D. A. Weitz , A. M. van Oijen . Droplet microfluidics:a tool for biology, chemistry and nanotechnology . Trac-trend. Anal. Chem. , 2016 . 82 118 - 125 . DOI: 10.1016/j.trac.2016.05.019 http://doi.org/10.1016/j.trac.2016.05.019 .

M. L. Eggersdorfer , W. Zheng , S. Nawar , C. Mercandetti , A. Ofner , I. Leibacher , S. Koehler , D. A. Weitz . Tandem emulsification for high-throughput production of double emulsions . Lab Chip , 2017 . 17 ( 5 ): 936 - 942 . DOI: 10.1039/C6LC01553K http://doi.org/10.1039/C6LC01553K .

W. Wang , M. J. Zhang , L. Y. Chu . Functional polymeric microparticles engineered from controllable microfluidic emulsions . Acc. Chem. Res. , 2014 . 47 ( 2 ): 373 - 384 . DOI: 10.1021/ar4001263 http://doi.org/10.1021/ar4001263 .

G. H. Ma , H. Sone , S. Omi . Preparation of uniform-sized polystyrene-polyacrylamide composite microspheres from a W/O/W emulsion by membrane emulsification technique and subsequent suspension polymerization . Macromolecules , 2004 . 37 ( 8 ): 2954 - 2964 . DOI: 10.1021/ma035316g http://doi.org/10.1021/ma035316g .

P. S. Clegg , J. W. Tavacoli , P. J. Wilde . One-step production of multiple emulsions:microfluidic, polymer-stabilized and particle-stabilized approaches . Soft Matter , 2016 . 12 ( 4 ): 998 - 1008 . DOI: 10.1039/C5SM01663K http://doi.org/10.1039/C5SM01663K .

M. F. Ficheux , L. Bonakdar , F. Leal-Calderon , J. Bibette . Some stability criteria for double emulsions . Langmuir , 1998 . 14 ( 10 ): 2702 - 2706 . DOI: 10.1021/la971271z http://doi.org/10.1021/la971271z .

J. M. Morais , O. D. H. Santos , S. E. Friberg . Some fundamentals of the one-step formation of double emulsions . J. Disper. Sci. Technol. , 2010 . 31 ( 8 ): 1019 - 1026 . DOI: 10.1080/01932690903224656 http://doi.org/10.1080/01932690903224656 .

J. M. Morais , O. D. H. Santos , J. R. L. Nunes , C. F. Zanatta , P. A. Rocha-Filho . W/O/W multiple emulsions obtained by one-step emulsification method and evaluation of the involved variables . J. Disper. Sci. Technol. , 2008 . 29 ( 1 ): 63 - 69 . DOI: 10.1080/01932690701688391 http://doi.org/10.1080/01932690701688391 .

J. M. Morais , P. A. Rocha-Filho , D. J. Burgess . Influence of phase inversion on the formation and stability of one-step multiple emulsions . Langmuir , 2009 . 25 ( 14 ): 7954 - 7961 . DOI: 10.1021/la9007125 http://doi.org/10.1021/la9007125 .

B. P. Binks , R. Murakami , S. P. Armes , S. Fujii . Temperature-induced inversion of nanoparticle-stabilized emulsions . Angew. Chem. Int. Ed. , 2005 . 44 ( 30 ): 4795 - 4798 . DOI: 10.1002/(ISSN)1521-3773 http://doi.org/10.1002/(ISSN)1521-3773 .

L. Besnard , F. Marchal , J. F. Paredes , J. Daillant , N. Pantoustier , P. Perrin , P. Guenoun . Multiple emulsions controlled by stimuli-responsive polymers . Adv. Mater. , 2013 . 25 ( 20 ): 2844 - 2848 . DOI: 10.1002/adma.201204496 http://doi.org/10.1002/adma.201204496 .

M. Protat , N. Bodin , F. Gobeaux , F. Malloggi , J. Daillant , N. Pantoustier , P. Guenoun , P. Perrin . Biocompatible stimuli-responsive W/O/W multiple emulsions prepared by one-step mixing with a single diblock copolymer emulsifier . Langmuir , 2016 . 32 ( 42 ): 10912 - 10919 . DOI: 10.1021/acs.langmuir.6b02590 http://doi.org/10.1021/acs.langmuir.6b02590 .

A. Manova , J. Viktorova , J. Köhler , S. Theiler , H. Keul , A. A. Piryazev , D. A. Ivanov , L. Tsarkova , M. Möller . Multilamellar thermoresponsive emulsions stabilized with biocompatible semicrystalline block copolymers . ACS Macro Lett. , 2016 . 5 ( 2 ): 163 - 167 . DOI: 10.1021/acsmacrolett.5b00743 http://doi.org/10.1021/acsmacrolett.5b00743 .

Q. Chen , Y. Xu , X. Cao , L. Qin , Z. An . Core cross-linked star (CCS) polymers with temperature and salt dual responsiveness:synthesis, formation of high internal phase emulsions (HIPEs) and triggered demulsification . Polym. Chem. , 2014 . 5 ( 1 ): 175 - 185 . DOI: 10.1039/C3PY00942D http://doi.org/10.1039/C3PY00942D .

Q. Chen , M. R. Hill , W. L. A. Brooks , A. Zhu , B. S. Sumerlin , Z. An . Boronic acid linear homopolymers as effective emulsifiers and gelators . ACS Appl. Mater. Interfaces , 2015 . 7 ( 39 ): 21668 - 21672 . DOI: 10.1021/acsami.5b07456 http://doi.org/10.1021/acsami.5b07456 .

F. Liu , S. D. Lin , Z. Q. Zhang , J. W. Hu , G. J. Liu , Y. Y. Tu , Y. Yang , H. L. Zou , Y. M. Mo , L. Miao . pH-Responsive nanoemulsions for controlled drug release . Biomacromolecules , 2014 . 15 ( 3 ): 968 - 977 . DOI: 10.1021/bm4018484 http://doi.org/10.1021/bm4018484 .

D. G. Wang , S. L. Liao , S. M. Zhang , Y. P. Wang . A reversed photosynthesis-like process for light-triggered CO 2 capture, release, and conversion . ChemSusChem , 2017 . 10 ( 12 ): 2573 - 2577 . DOI: 10.1002/cssc.v10.12 http://doi.org/10.1002/cssc.v10.12 .

J. Wang , J. Zhao , Y. B. Li , M. Yang , Y. Q. Chang , J. P. Zhang , Z. W. Sun , Y. P. Wang . Enhanced light absorption in porous particles for ultra-NIR-sensitive biomaterials . ACS Macro Lett. , 2015 . 4 ( 4 ): 392 - 397 . DOI: 10.1021/acsmacrolett.5b00089 http://doi.org/10.1021/acsmacrolett.5b00089 .

Y. Y. Cao , Z. Wang , S. L. Liao , J. Wang , Y. P. Wang . A light-activated microheater for the remote control of enzymatic catalysis . Chem. Eur. J. , 2016 . 22 ( 3 ): 1152 - 1158 . DOI: 10.1002/chem.201503665 http://doi.org/10.1002/chem.201503665 .

Q. P. Qian , X. P. Huang , X. Y. Zhang , Z. G. Xie , Y. P. Wang . One-step preparation of macroporous polymer particles with multiple interconnected chambers:a candidate for trapping biomacromolecules . Angew. Chem. Int. Ed. , 2013 . 52 ( 40 ): 10625 - 10629 . DOI: 10.1002/anie.201305003 http://doi.org/10.1002/anie.201305003 .

X. P. Huang , R. C. Fang , D. G. Wang , J. Wang , H. P. Xu , Y. P. Wang , X. Zhang . Tuning polymeric amphiphilicity via Se-N interactions:towards one-step double emulsion for highly selective enzyme mimics . Small , 2015 . 11 ( 13 ): 1537 - 1541 . DOI: 10.1002/smll.v11.13 http://doi.org/10.1002/smll.v11.13 .

D. G. Wang , X. P. Huang , Y. P. Wang . Managing the phase separation in double emulsion by tuning amphiphilicity via a supramolecular route . Langmuir , 2014 . 30 ( 48 ): 14460 - 14468 . DOI: 10.1021/la5043525 http://doi.org/10.1021/la5043525 .

Z. Wang , J. Song , S. Zhang , X. Q. Xu , Y. P. Wang . Formulating polyethylene glycol as supramolecular emulsifiers for one-step double emulsions . Langmuir , 2017 . 33 ( 36 ): 9160 - 9169 . DOI: 10.1021/acs.langmuir.7b02326 http://doi.org/10.1021/acs.langmuir.7b02326 .

N. R. Cameron , D. C. Sherrington . High internal phase emulsions (HIPEs)-structure, properties and use in polymer preparation . Adv. Polym. Sci. , 1996 . 126 163 - 214 . DOI: 10.1007/3-540-60484-7 http://doi.org/10.1007/3-540-60484-7 .

M. S. Silverstein , N. R. Cameron . PolyHIPEs-porous polymers from high internal phase emulsions. In Encyclopedia of polymer science and technology , John Wiley & Sons, Inc. , 2010 .

M. S. Silverstein . PolyHIPEs:recent advances in emulsiontemplated porous polymers . Prog. Polym. Sci. , 2014 . 39 ( 1 ): 199 - 234 . DOI: 10.1016/j.progpolymsci.2013.07.003 http://doi.org/10.1016/j.progpolymsci.2013.07.003 .

J. M. Williams . High internal phase water-in-oil emulsionsinfluence of surfactants and cosurfactants on emulsion stability and foam quality . Langmuir , 1991 . 7 ( 7 ): 1370 - 1377 . DOI: 10.1021/la00055a014 http://doi.org/10.1021/la00055a014 .

A. Barbetta , N. R. Cameron . Morphology and surface area of emulsion-derived (polyHIPE) solid foams prepared with oil-phase soluble porogenic solvents:span 80 as surfactant . Macromolecules , 2004 . 37 ( 9 ): 3188 - 3201 . DOI: 10.1021/ma0359436 http://doi.org/10.1021/ma0359436 .

K. Haibach , A. Menner , R. Powell , A. Bismarck . Tailoring mechanical properties of highly porous polymer foams:silica particle reinforced polymer foams via emulsion templating . Polymer , 2006 . 47 ( 13 ): 4513 - 4519 . DOI: 10.1016/j.polymer.2006.03.114 http://doi.org/10.1016/j.polymer.2006.03.114 .

S. Kovacic , F. Preishuber-Pfluegl , D. Pahovnik , E. Zagar , C. Slugovc . Covalent incorporation of the surfactant into high internal phase emulsion templated polymeric foams . Chem. Commun. , 2015 . 51 ( 36 ): 7725 - 7728 . DOI: 10.1039/C4CC09199J http://doi.org/10.1039/C4CC09199J .

B. P. Binks , S. O. Lumsdon . Catastrophic phase inversion of water-in-oil emulsions stabilized by hydrophobic silica . Langmuir , 2000 . 16 ( 6 ): 2539 - 2547 . DOI: 10.1021/la991081j http://doi.org/10.1021/la991081j .

P. A. Kralchevsky , I. B. Ivanov , K. P. Ananthapadmanabhan , A. Lips . On the thermodynamics of particle-stabilized emulsions:curvature effects and catastrophic phase inversion . Langmuir , 2005 . 21 ( 1 ): 50 - 63 . DOI: 10.1021/la047793d http://doi.org/10.1021/la047793d .

P. J. Colver , S. A. F. Bon . Cellular polymer monoliths made via Pickering high internal phase emulsions . Chem. Mater. , 2007 . 19 ( 7 ): 1537 - 1539 . DOI: 10.1021/cm0628810 http://doi.org/10.1021/cm0628810 .

V. O. Ikem , A. Menner , A. Bismarck . High internal phase emulsions stabilized solely by functionalized silica particles . Angew. Chem. Int. Ed. , 2008 . 47 ( 43 ): 8277 - 8279 . DOI: 10.1002/anie.v47:43 http://doi.org/10.1002/anie.v47:43 .

Z. Li , T. Ming , J. Wang , T. Ngai . High internal phase emulsions stabilized solely by microgel particles . Angew. Chem. Int. Ed. , 2009 . 48 ( 45 ): 8490 - 8493 . DOI: 10.1002/anie.v48:45 http://doi.org/10.1002/anie.v48:45 .

G. Sun , Z. Li , T. Ngai . Inversion of particle-stabilized emulsions to form high-internal-phase emulsions . Angew. Chem. Int. Ed. , 2010 . 49 ( 12 ): 2163 - 2166 . DOI: 10.1002/anie.v49:12 http://doi.org/10.1002/anie.v49:12 .

V. O. Ikem , A. Menner , T. S. Horozov , A. Bismarck . Highly permeable macroporous polymers synthesized from Pickering medium and high internal phase emulsion templates . Adv. Mater. , 2010 . 22 ( 32 ): 3588 - 3592 . DOI: 10.1002/adma.201000729 http://doi.org/10.1002/adma.201000729 .

W. Yi , H. Wu , H. Wang , Q. Du . Interconnectivity of macroporous hydrogels prepared via graphene oxide-stabilized Pickering high internal phase emulsions . Langmuir , 2016 . 32 ( 4 ): 982 - 990 . DOI: 10.1021/acs.langmuir.5b04477 http://doi.org/10.1021/acs.langmuir.5b04477 .

Y. Ye , M. Jin , D. Wan . One-pot synthesis of porous monolith-supported gold nanoparticles as an effective recyclable catalyst . J. Mater. Chem. A , 2015 . 3 ( 25 ): 13519 - 13525 . DOI: 10.1039/C5TA02925B http://doi.org/10.1039/C5TA02925B .

H. Xu , X. Zheng , Y. Huang , H. Wang , Q. Du . Interconnected porous polymers with tunable pore throat size prepared via Pickering high internal phase emulsions . Langmuir , 2016 . 32 ( 1 ): 38 - 45 . DOI: 10.1021/acs.langmuir.5b03037 http://doi.org/10.1021/acs.langmuir.5b03037 .

E. Perrin , H. Bizot , B. Cathala , I. Capron . Chitin nanocrystals for Pickering high internal phase emulsions . Biomacromolecules , 2014 . 15 ( 10 ): 3766 - 3771 . DOI: 10.1021/bm5010417 http://doi.org/10.1021/bm5010417 .

J. Li , J. Zhang , Y. Zhao , B. Han , G. Yang . High-internal-ionic liquid-phase emulsions . Chem. Commun. , 2012 . 48 ( 7 ): 994 - 996 . DOI: 10.1039/C2CC15922H http://doi.org/10.1039/C2CC15922H .

N. R. Cameron , D. C. Sherrington . Synthesis and characterization of poly(aryl ether sulfone) polyHIPE materials . Macromolecules , 1997 . 30 ( 19 ): 5860 - 5869 . DOI: 10.1021/ma961403f http://doi.org/10.1021/ma961403f .

A. Menner , R. Powell , A. Bismarck . A new route to carbon black filled polyHIPEs . Soft Matter , 2006 . 2 ( 4 ): 337 - 342 . DOI: 10.1039/b517731f http://doi.org/10.1039/b517731f .

P. Viswanathan , S. Chirasatitsin , K. Ngamkham , A. J. Engler , G. Battaglia . Cell instructive microporous scaffolds through interface engineering . J. Am. Chem. Soc. , 2012 . 134 ( 49 ): 20103 - 20109 . DOI: 10.1021/ja308523f http://doi.org/10.1021/ja308523f .

S. Kovacic , N. B. Matsko , K. Jerabek , P. Krajnc , C. Slugovc . On the mechanical properties of hipe templated macroporous poly(dicyclopentadiene) prepared with low surfactant amounts . J. Mater. Chem. A , 2013 . 1 ( 3 ): 487 - 490 . DOI: 10.1039/C2TA00546H http://doi.org/10.1039/C2TA00546H .

P. Viswanathan , D. W. Johnson , C. Hurley , N. R. Cameron , G. Battaglia . 3D surface functionalization of emulsiontemplated polymeric foams . Macromolecules , 2014 . 47 ( 20 ): 7091 - 7098 . DOI: 10.1021/ma500968q http://doi.org/10.1021/ma500968q .

Y. Xing , J. Peng , K. Xu , S. Gao , X. Gui , S. Liang , L. Sun , M. Chen . A soluble star-shaped silsesquioxane-cored polymer-towards novel stabilization of pH-dependent high internal phase emulsions . Phys. Chem. Chem. Phys. , 2017 . 19 ( 34 ): 23024 - 23033 . DOI: 10.1039/C7CP03325G http://doi.org/10.1039/C7CP03325G .

B. H. L. Oh , A. Bismarck , M. B. Chan-Park . High internal phase emulsion templating with self-emulsifying and thermoresponsive chitosan-graft-PNIPAM-graft-oligoproline . Biomacromolecules , 2014 . 15 ( 5 ): 1777 - 1787 . DOI: 10.1021/bm500172u http://doi.org/10.1021/bm500172u .

Q. J. Chen , Z. S. An . Synthesis of star polymeric ionic liquids and use as the stabilizers for high internal phase emulsions . Chinese J. Polym. Sci. , 2017 . 35 ( 1 ): 54 - 65 . DOI: 10.1007/s10118-016-1858-5 http://doi.org/10.1007/s10118-016-1858-5 .

S. Zhang , D. Wang , Q. Pan , Q. Gui , S. Liao , Y. Wang . Light-triggered CO 2 breathing foam via nonsurfactant high internal phase emulsion . ACS Appl. Mater. Interfaces , 2017 . 9 34497 - 34505 . DOI: 10.1021/acsami.7b11315 http://doi.org/10.1021/acsami.7b11315 .

X. P. Huang , Y. D. Yang , J. Z. Shi , H. T. Ngo , C. H. Shen , W. B. Du , Y. P. Wang . High-internal-phase emulsion tailoring polymer amphiphilicity towards an efficient NIR-sensitive bacteria filter . Small , 2015 . 11 ( 37 ): 4876 - 4883 . DOI: 10.1002/smll.v11.37 http://doi.org/10.1002/smll.v11.37 .

Y. W. Chen , Z. Wang , D. G. Wang , N. Ma , C. C. Li , Y. P. Wang . Surfactant-free emulsions with erasable triggered phase inversions . Langmuir , 2016 . 32 ( 42 ): 11039 - 11042 . DOI: 10.1021/acs.langmuir.6b03189 http://doi.org/10.1021/acs.langmuir.6b03189 .

Views

472

Downloads

CSCD

Alert me when the article has been cited

Submit

Tools

Publicity Resources

Polymer Materials Synthesized in Living Cells for Regulating Biological Functions

Surfactant Mediated Microphase Separation in Miscible Block Copolymer of Poly(4-vinyl pyridine-b-hydroxybutylacrylate)

Azobenzene Based Photo-responsive Mechanical Actuator Fabricated by Intermolecular H-bond Interaction

Pyrimidoisoindigo-based Polymers for Ambipolar Charge Transport

Energy Storage Performance of Supercapacitors with Polyelectrolyte Surface Coatings: Effects of Dielectric Contrast

Related Author

Hua-Ping Xu

Wei Tian

Jia-Hui Ma

Yi-Fan Jin

Cheng-Fei Liu

Jin-Tao Zhu

Bi-Jin Xiong

You-Shuang Zhou

Related Institution

Shaanxi Key Laboratory of Macromolecular Science and Technology, Xi’an Key Laboratory of Hybrid Luminescent Materials and Photonic Device, MOE Key Laboratory of Material Physics and Chemistry under Extraordinary Conditions, School of Chemistry and Chemical Engineering, Northwestern Polytechnical University

Key Lab of Organic Optoelectronics & Molecular Engineering and Laboratory of Flexible Electronics Technology, Department of Chemistry, Tsinghua University

Key Laboratory of Materials Chemistry for Energy Conversion and Storage (HUST) of Ministry of Education, School of Chemistry and Chemical Engineering. Huazhong University of Science and Technology (HUST)

Key Laboratory of Optoelectronic Chemical Materials and Devices (Ministry of Education), Jianghan University

Key Laboratory of Green Preparation and Application of Functional Materials (Ministry of Education), Hubei Key Laboratory of Polymer Materials, Faculty of Materials Science and Engineering, Hubei University

⁰