Rheology of Poly(vinyl butyral) Solution Containing Fumed Silica in Correlation with Electrospinning

Petra Peer; Martina Polaskova; Pavol Suly

doi:10.1007/s10118-018-2077-z

Your Location：

Home >

Browse articles >

Rheology of Poly(vinyl butyral) Solution Containing Fumed Silica in Correlation with Electrospinning

Articles | Updated：2021-02-18

- Rheology of Poly(vinyl butyral) Solution Containing Fumed Silica in Correlation with Electrospinning
- Chinese Journal of Polymer Science Vol. 36, Issue 6, Pages: 742-748(2018)
- Affiliations：
  
  a.Institute of Hydrodynamics of the Czech Academy of Sciences, Pod Patankou 5, 166 12 Prague 6, Czech Republic
  b.Centre of Polymer Systems, Tomas Bata University in Zlín, trida Tomase Bati 5678, 760 01 Zlín, Czech Republic
  c.Department of Polymer Engineering, Faculty of Technology, Tomas Bata University in Zlín, Vavreckova 275, 760 01 Zlín, Czech Republic
- Author bio：
  
  Petra Peer, E-mail peer@ih.cas.cz
- Funds：
- DOI：10.1007/s10118-018-2077-z
  CLC：
- Received：28 August 2017，
  
  Accepted：24 October 2017，
  
  Online First：06 February 2018，
  
  Published：2018-06
- Accepted：
Scan QR Code
Petra Peer, Martina Polaskova, Pavol Suly. Rheology of Poly(vinyl butyral) Solution Containing Fumed Silica in Correlation with Electrospinning[J]. Chinese Journal of Polymer Science, 2018, 36(6): 742-748.
DOI：

Petra Peer, Martina Polaskova, Pavol Suly. Rheology of Poly(vinyl butyral) Solution Containing Fumed Silica in Correlation with Electrospinning[J]. Chinese Journal of Polymer Science, 2018, 36(6): 742-748. DOI： 10.1007/s10118-018-2077-z.

摘要

Abstract

The rheological properties in question are influenced by many factors

ranging from the characteristics of the given polymer or solvent to the flowing conditions. The primary focus of this study is to analyse the rheological behaviour of poly(vinyl butyral)-Mowital B 60H-(PVB) solutions dissolved in methanol and a blend of these with fumed silica nanoparticles. The preparation of the nanofibrous web and the quality of nanofibres were correlated with the rheology of the polymer solution. It was discerned that drastically intensifying shear viscosity and the elasticity of the solution exerted a negligible effect on the formation of fibres

a finding which has rarely been discussed in the literature. The morphologies and structures of the PVB/silica nanofibrous membranes were investigated by scanning electron microscopy

thermogravimetric analysis and Fourier transform infrared spectroscopy.

关键词

Keywords

references

A. Vanangamudi , S. Hamzah , G. Singh . Synthesis of hybrid hydrophobic composite air filtration membranes for antibacterial activity and chemical detoxification with high particulate filtration efficiency (PFE) . Chem. Eng. J. , 2015 . 260 801 - 808 . DOI: 10.1016/j.cej.2014.08.062 http://doi.org/10.1016/j.cej.2014.08.062 .

R. Khajavi , M. Abbasipour , A. Bahador . Electrospun biodegradable nanofibers scaffolds for bone tissue engineering . J. Appl. Polym. Sci. , 2016 . 133 ( 3 ): 42883 http://doi.wiley.com/10.1002/app.42883 http://doi.wiley.com/10.1002/app.42883 , .

A. K. Capulli , L. A. MacQueen , S. P. Sheehy , K. K. Parker . Fibrous scaffolds for building hearts and heart parts . Adv. Drug Deliv. Rev. , 2016 . 96 83 - 102 . DOI: 10.1016/j.addr.2015.11.020 http://doi.org/10.1016/j.addr.2015.11.020 .

I. Sas , R. E. Gorga , J. A. Joines , K. A. Thoney . Literature review on superhydrophobic self-cleaning surfaces produced by electrospinning . J. Polym. Sci., Part B:Polym. Phys. , 2012 . 50 ( 12 ): 824 - 845 . DOI: 10.1002/polb.v50.12 http://doi.org/10.1002/polb.v50.12 .

S. Ramakrishna , K. Fujihara , W. E. Teo , T. C. Lim , Z. Ma . "An introduction to electrospinning and nanofibers", World Scientific Publishing Co . Pte. Ltd., Singapore, , 2005 . p. 90 http://doi.wiley.com/10.1002/app.42883 http://doi.wiley.com/10.1002/app.42883 , .

J. Deitzel , J. Kleinmeyer , D. Harris , N. C. B. Tan . The effect of processing variables on the morphology of electrospun nanofibers and textiles . Polymer , 2001 . 42 ( 1 ): 261 - 272 . DOI: 10.1016/S0032-3861(00)00250-0 http://doi.org/10.1016/S0032-3861(00)00250-0 .

W. K. Son , J. H. Youk , T. S. Lee , W. H. Park . The effects of solution properties and polyelectrolyte on electrospinning of ultrafine poly(ethylene oxide) fibers . Polymer , 2004 . 45 ( 9 ): 2959 - 2966 . DOI: 10.1016/j.polymer.2004.03.006 http://doi.org/10.1016/j.polymer.2004.03.006 .

W. Han , D. Nurwaha , C. Li , X. Wang . Free surface electrospun fibers:the combined effect of processing parameters . Polym. Eng. Sci. , 2014 . 54 ( 1 ): 189 - 197 . DOI: 10.1002/pen.v54.1 http://doi.org/10.1002/pen.v54.1 .

S. Basu , N. Gogoi , S. Sharma , M. Jassal , A. K. Agrawal . Role of elasticity in control of diameter of electrospun PAN nanofibers . Fib. Polym. , 2013 . 14 ( 6 ): 950 - 956 . DOI: 10.1007/s12221-013-0950-5 http://doi.org/10.1007/s12221-013-0950-5 .

D. Gupta , M. Jassal , A. K. Agrawal . Electrospinning of poly(vinyl alcohol)-based boger fluids to understand the role of elasticity on morphology of nanofibers . Ind. Eng. Chem. Res. , 2015 . 54 ( 5 ): 1547 - 1554 . DOI: 10.1021/ie504141c http://doi.org/10.1021/ie504141c .

M. K. Dufficy , M. T. Geiger , C. A. Bonino , S. A. Khan . Electrospun ultrafine fiber composites containing fumed silica:from solution rheology to materials with tunable wetting . Langmuir , 2015 . 31 ( 45 ): 12455 - 12463 . DOI: 10.1021/acs.langmuir.5b03545 http://doi.org/10.1021/acs.langmuir.5b03545 .

G. D. Yadav , A. R. Yadav . Atom economical Michael addition of indole with methyl vinyl ketone over novel solid acid catalyst sulfated zirconia on silica tubes . Microporous and Mesoporous Mater. , 2014 . 195 180 - 190 . DOI: 10.1016/j.micromeso.2014.03.025 http://doi.org/10.1016/j.micromeso.2014.03.025 .

H. Xu , H. Li , J. Chang . Controlled drug release from a polymer matrix by patterned electrospun nanofibers with controllable hydrophobicity . J. Mater. Chem. B , 2013 . 1 ( 33 ): 4182 - 4188 . DOI: 10.1039/c3tb20404a http://doi.org/10.1039/c3tb20404a .

L. J. Chen , J. D. Liao , S. J. Lin , Y. J. Chuang , Y. S. Fu . Synthesis and characterization of PVB/silica nanofibers by electrospinning process . Polymer , 2009 . 50 ( 15 ): 3516 - 3521 . DOI: 10.1016/j.polymer.2009.05.063 http://doi.org/10.1016/j.polymer.2009.05.063 .

H. Fong , I. Chun , D. H. Reneker . Beaded nanofibers formed during electrospinning . Polymer , 1999 . 40 ( 16 ): 4585 - 4592 . DOI: 10.1016/S0032-3861(99)00068-3 http://doi.org/10.1016/S0032-3861(99)00068-3 .

F. Yalcinkaya . Experimental study on electrospun polyvinyl butyral nanofibers using a non-solvent system . Fib. Polym. , 2015 . 16 ( 12 ): 2544 - 2551 . DOI: 10.1007/s12221-015-5525-1 http://doi.org/10.1007/s12221-015-5525-1 .

P. Cassagnau . Melt rheology of organoclay and fumed silica nanocomposites . Polymer , 2008 . 49 ( 9 ): 2183 - 2196 . DOI: 10.1016/j.polymer.2007.12.035 http://doi.org/10.1016/j.polymer.2007.12.035 .

S. L. Shenoy , W. D. Bates , H. L Frisch , G. E. Wnek . Role of chain entanglements on fiber formation during electrospinning of polymer solutions:good solvent, non-specific polymer-polymer interaction limit . Polymer , 2005 . 46 ( 10 ): 3372 - 3384 . DOI: 10.1016/j.polymer.2005.03.011 http://doi.org/10.1016/j.polymer.2005.03.011 .

J. H. Yu , S. V. Fridrikh , G. C. Rutledge . The role of elasticity in the formation of electrospun fibers . Polymer , 2006 . 47 ( 13 ): 4789 - 4797 . DOI: 10.1016/j.polymer.2006.04.050 http://doi.org/10.1016/j.polymer.2006.04.050 .

O. Regev , S. Vandebril , E. Zussman , C. Clasen . The role of interfacial viscoelasticity in the stabilization of an electrospun jet . Polymer , 2010 . 51 ( 12 ): 2611 - 2620 . DOI: 10.1016/j.polymer.2010.03.061 http://doi.org/10.1016/j.polymer.2010.03.061 .

G. W. Ehrenstein , G. Riedel , P. Trawiel . "Thermal analysis of plastic:theory and practice" , : Munich Hanser Publisher , 2004 . p. 368 .

Views

Downloads

CSCD

Alert me when the article has been cited

Submit

Tools

Publicity Resources

UiO-66-functionalized Sandwich Composite Separators for Improved Performance and Safety of Lithium-ion Batteries

Boehmite/Polyacrylonitrile Composite Nanofiber Separator with Enhanced Ionic Conductivity and Thermal Stability for Lithium-Ion Batteries

Swelling, Interfacial Behavior, and Rheology of Soft Core-Shell Microgels Introducing Acid Isomer for pH-Temperature Dual-responsiveness

Droplet Bridging Effect in Polymer/Polymer/Filler Ternary Composites

Fabrication of Modified Fibrous Filters by Electrospinning and Investigating Their Application as Improved Face Masks

Related Author

Wen-Fei Ding

Yu-Xing Liu

Lan Xu

Zhi-Jun Tu

Sheng-Bin Cao

Xiao-Song Liu

Xiao-Peng Li

Wei Luo

Related Institution

National Engineering Laboratory for Modern Silk, College of Textile and Engineering, Soochow University

Jiangsu Engineering Research Center of Textile Dyeing and Printing for Energy Conservation, Discharge Reduction and Cleaner Production (ERC), Soochow University

Jiangsu Advanced Textile Engineering Technology Center

School of Materials, Shanghai Dianji University

Oxford Suzhou Centre for Advanced Research

⁰