Salen-iron Complexes: Synthesis, Characterization and Their Reactivity with Lactide

Yuan Liang; Ran-Long Duan; Chen-Yang Hu; Li-Li Li; Xuan Pang; Wan-Xi Zhang; Xue-Si Chen

doi:10.1007/s10118-018-2068-0

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Salen-iron Complexes: Synthesis, Characterization and Their Reactivity with Lactide

Articles | Updated：2021-02-18

- Salen-iron Complexes: Synthesis, Characterization and Their Reactivity with Lactide
- Chinese Journal of Polymer Science Vol. 36, Issue 2, Pages: 185-189(2018)
- Affiliations：
  
  a.Department of Materials Science and Engineering, Jilin University, Changchun 130025, China
  b.Key Laboratory of Polymer Ecomaterials, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China
- Author bio：
  
  E-mail lilyllee@jlu.edu.cn (L.L.L.)
  E-mail xpang@ciac.jl.cn (X.P.)
- Funds：
- DOI：10.1007/s10118-018-2068-0
  CLC：
- Received：31 August 2017，
  
  Accepted：17 October 2017，
  
  Online First：29 November 2017，
  
  Published：05 February 2018
- Accepted：
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Yuan Liang, Ran-Long Duan, Chen-Yang Hu, et al. Salen-iron Complexes: Synthesis, Characterization and Their Reactivity with Lactide[J]. Chinese Journal of Polymer Science, 2018, 36(2): 185-189.
DOI：

Yuan Liang, Ran-Long Duan, Chen-Yang Hu, et al. Salen-iron Complexes: Synthesis, Characterization and Their Reactivity with Lactide[J]. Chinese Journal of Polymer Science, 2018, 36(2): 185-189. DOI： 10.1007/s10118-018-2068-0.

摘要

Abstract

Schiff-base metal complexes as efficient catalysts are widely used in ring-opening polymerization of cycle esters. The salen Fe complexes were formed with their excellent biocompatibility and less toxicity. A series of salen Fe complexes were designed in this work in order to study the activity and control of polymerization of lactide. The salen Fe complexes' activities changed with the ligands configuration and substituent groups.

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references

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