Perylene Bisimide In-chain Polyethylene with Unique Self-assembly Nanostructure through Acyclic Diene Metathesis (ADMET) Polymerization

Wei Song; Yang You; Tian-Jing Li; Juan Li; Liang Ding

doi:10.1007/s10118-018-2067-1

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Perylene Bisimide In-chain Polyethylene with Unique Self-assembly Nanostructure through Acyclic Diene Metathesis (ADMET) Polymerization

Articles | Updated：2021-02-18

- Perylene Bisimide In-chain Polyethylene with Unique Self-assembly Nanostructure through Acyclic Diene Metathesis (ADMET) Polymerization
- Chinese Journal of Polymer Science Vol. 36, Issue 6, Pages: 703-711(2018)
- Affiliations：
  
  a.Department of Polymer and Composite Material, School of Materials Engineering, Yancheng Institute of Technology, Yancheng 224051, China
  b.Roy & Diana Vagelos Laboratories, Department of Chemistry, University of Pennsylvania, Philadelphia 19104-6323, PA, USA
  c.School of Automotive Engineering, Yancheng Vocational Institute of Industry Technology, Yancheng 224005, China
- Author bio：
  
  E-mail sw121092@ycit.cn (W.S.)
  E-mail dl1984911@ycit.edu.cn (L.D.)
- Funds：
- DOI：10.1007/s10118-018-2067-1
  CLC：
- Received：16 September 2017，
  
  Accepted：17 October 2017，
  
  Online First：13 February 2018，
  
  Published：2018-06
- Accepted：
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Wei Song, Yang You, Tian-Jing Li, et al. Perylene Bisimide In-chain Polyethylene with Unique Self-assembly Nanostructure through Acyclic Diene Metathesis (ADMET) Polymerization[J]. Chinese Journal of Polymer Science, 2018, 36(6): 703-711.
DOI：

Wei Song, Yang You, Tian-Jing Li, et al. Perylene Bisimide In-chain Polyethylene with Unique Self-assembly Nanostructure through Acyclic Diene Metathesis (ADMET) Polymerization[J]. Chinese Journal of Polymer Science, 2018, 36(6): 703-711. DOI： 10.1007/s10118-018-2067-1.

摘要

Abstract

A novel perylene tetracarboxylic acid bisimide (PTCBI) in-chain polyethylene (PE) was first prepared

via

acyclic diene metathesis (ADMET) polymerization of PTCBI-functionalized

-diene monomer. The polymers could spontaneously self-assemble into hollow cylindrical structures in which the

interaction between adjacent PTCBI moieties was enhanced and the electron mobility was possibly promoted. The hydrogenation of as-obtained polymer was readily accomplished

affording the desired precision PTCBI in-chain PE with a saturated backbone

which showed high glass transition temperature (

=63℃)

relatively wide range of light absorption (

=200-575 nm)

and higher LUMO level (-3.62 eV). It can therefore serve as a superior model for facile construction of functional polyolefin and soluble PTCBI polymer with ordered architecture.

关键词

Keywords

references

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