Fully Biodegradable Poly(lactic acid)/Poly(propylene carbonate) Shape Memory Materials with Low Recovery Temperature Based on <italic style="font-style: italic">in situ</italic> Compatibilization by Dicumyl Peroxide

Sheng-Xue Qin; Cui-Xiang Yu; Xue-Yang Chen; Hai-Ping Zhou; Li-Fen Zhao

doi:10.1007/s10118-018-2065-3

Your Location：

Home >

Browse articles >

Fully Biodegradable Poly(lactic acid)/Poly(propylene carbonate) Shape Memory Materials with Low Recovery Temperature Based on in situ Compatibilization by Dicumyl Peroxide

Articles | Updated：2021-02-18

- Fully Biodegradable Poly(lactic acid)/Poly(propylene carbonate) Shape Memory Materials with Low Recovery Temperature Based on in situ Compatibilization by Dicumyl Peroxide
- Chinese Journal of Polymer Science Vol. 36, Issue 6, Pages: 783-790(2018)
- Affiliations：
  
  a.College of Mechanical and Electric Engineering, College of Materials Science and Engineering, Shandong University of Science and Technology, Qingdao 266590, China
  b.Qingdao Reinforced Thermoplastic Pipes Engineering Technology Center, Qingdao 266590, China
- Author bio：
  
  Hai-Ping Zhou, E-mail zhouhp325@163.com (H.P.Z)
  Li-Fen Zhao, E-mail lfzhao2009@126.com (L.F.Z)
- Funds：
- DOI：10.1007/s10118-018-2065-3
  CLC：
- Received：05 September 2017，
  
  Accepted：17 October 2017，
  
  Online First：30 January 2018，
  
  Published：2018-06
- Accepted：
Scan QR Code
Sheng-Xue Qin, Cui-Xiang Yu, Xue-Yang Chen, et al. Fully Biodegradable Poly(lactic acid)/Poly(propylene carbonate) Shape Memory Materials with Low Recovery Temperature Based on in situ Compatibilization by Dicumyl Peroxide[J]. Chinese Journal of Polymer Science, 2018, 36(6): 783-790. DOI: 10.1007/s10118-018-2065-3.
DOI：

Sheng-Xue Qin, Cui-Xiang Yu, Xue-Yang Chen, et al. Fully Biodegradable Poly(lactic acid)/Poly(propylene carbonate) Shape Memory Materials with Low Recovery Temperature Based on in situ Compatibilization by Dicumyl Peroxide[J]. Chinese Journal of Polymer Science, 2018, 36(6): 783-790. DOI: 10.1007/s10118-018-2065-3. DOI：

摘要

Abstract

Fully biodegradable blends with low shape memory recovery temperature were obtained based on poly(lactic acid) (PLA) and poly(propylene carbonate) (PPC). By virtue of their similar chemical structures

in situ

cross-linking reaction initiated by dicumyl peroxide (DCP) between PLA and PPC chains was realized in PLA/PPC blends. Therefore

the compatibility between PLA and PPC was increased

which obviously changed the phase structures and increased the elongation at break of the blends. The compatibilized blends had a recovery performance at 45℃. Combining the changes of phase structures

the mechanism of the shape memory was discussed. It was demonstrated that

in situ

compatibilization by dicumyl peroxide was effective to obtain eco-friendly PLA/PPC blends with good mechanical and shape memory properties.

关键词

Keywords

references

K. J. Cha , E. Lih , J. Choi , Y. K. Joung , D. J. Ahn , D. K. Han . Shape-memory effect by specific biodegradable polymer blending for biomedical applications . Macromol. Biosci. , 2014 . 14 ( 5 ): 667 - 678 . DOI: 10.1002/mabi.201300481 http://doi.org/10.1002/mabi.201300481 .

Y. S. Wong , Z. H. Stachurski , S. S. Venkatraman . Modeling shape memory effect in uncrosslinked amorphous biodegradable polymer . Polymer , 2011 . 52 ( 3 ): 874 - 880 . DOI: 10.1016/j.polymer.2010.12.004 http://doi.org/10.1016/j.polymer.2010.12.004 .

V. K. Kotharangannagari , K. Krishnan . Biodegradable hybrid nanocomposites of starch/lysine and zno nanoparticles with shape memory properties . Mater. Design , 2016 . 109 590 - 595 . DOI: 10.1016/j.matdes.2016.07.046 http://doi.org/10.1016/j.matdes.2016.07.046 .

I. Navarro-Baena , V. Sessini , F. Dominici , L. Torre , J. M. Kenny , L. Peponi . Design of biodegradable blends based on PLA and PCL:from morphological, thermal and mechanical studies to shape memory behavior . Polym. Degrad. Stab. , 2016 . 132 97 - 108 . DOI: 10.1016/j.polymdegradstab.2016.03.037 http://doi.org/10.1016/j.polymdegradstab.2016.03.037 .

S. Gu , X. Gao , S. Jin , Y. Liu . Biodegradable shape memory polyurethanes with controllable trigger temperature . Chinese J. Polym. Sci. , 2016 . 34 ( 6 ): 720 - 729 . DOI: 10.1007/s10118-016-1795-3 http://doi.org/10.1007/s10118-016-1795-3 .

E. Zini , M. Scandola , P. Dobrzynski , J. Kasperczyk , M. Bero . Shape memory behavior of novel (L-lactide-glycolidetrimethylene carbonate) terpolymers . Biomacromolecules , 2009 . 8 ( 11 ): 3661 - 3667 . http://cat.inist.fr/?aModele=afficheN&cpsidt=19873237 http://cat.inist.fr/?aModele=afficheN&cpsidt=19873237 , .

Q. Xing , R. Li , X. Dong , X. Zhang , L. Zhang , D. Wang . Phase morphology, crystallization behavior and mechanical properties of poly(L-lactide) toughened with biodegradable polyurethane:effect of composition and hard segment ratio . Chinese J. Polym. Sci , 2015 . 33 ( 9 ): 1294 - 1304 . DOI: 10.1007/s10118-015-1679-y http://doi.org/10.1007/s10118-015-1679-y .

T. Talbamrung , C. Kasemsook , W. Sangtean , S. Wachirahuttapong , C. Thongpin . Effect of peroxide and organoclay on thermal and mechanical properties of PLA in PLA/NBR melted blend . Energy. Proced. , 2016 . 89 274 - 281 . DOI: 10.1016/j.egypro.2016.05.035 http://doi.org/10.1016/j.egypro.2016.05.035 .

X. Jing , H. Mi , X. Peng , L. Turng . The morphology, properties, and shape memory behavior of polylactic acid/thermoplastic polyurethane blends . Polym. Eng. Sci , 2015 . 55 ( 1 ): 70 - 80 . DOI: 10.1002/pen.v55.1 http://doi.org/10.1002/pen.v55.1 .

Z. Wei , C. Long , Z. Yu . Surprising shape-memory effect of polylactide resulted from toughening by polyamide elastomer . Polymer , 2009 . 50 ( 5 ): 1311 - 1315 . DOI: 10.1016/j.polymer.2009.01.032 http://doi.org/10.1016/j.polymer.2009.01.032 .

D. Yuan , Z. Chen , C. Xu , K. Chen , Y. Chen . Fully biobased shape memory material based on novel cocontinuous structure in poly(lactic acid)/natural rubber TVPs fabricated via peroxide-induced dynamic vulcanization and in situ interfacial compatibilization . ACS Sustain. Chem. Eng. , 2015 . 3 ( 11 ): 2856 - 2865 . DOI: 10.1021/acssuschemeng.5b00788 http://doi.org/10.1021/acssuschemeng.5b00788 .

C. Barreto , A. Altskär , S. Fredriksen , E. Hansen , R. W. Rychwalski . Multiwall carbon nanotube/ppc composites:preparation, structural analysis and thermal stability . Eur. Polym. J. , 2013 . 49 ( 8 ): 2149 - 2161 . DOI: 10.1016/j.eurpolymj.2013.05.009 http://doi.org/10.1016/j.eurpolymj.2013.05.009 .

X. Y. Wang , Y. X. Weng , W. Wang , Z. G. Huang , Y. Z. Wang . Modification of poly(propylene carbonate) with chain extender ADR-4368 to improve its thermal, barrier, and mechanical properties . Polym. Test , 2016 . 54 301 - 307 . DOI: 10.1016/j.polymertesting.2016.07.024 http://doi.org/10.1016/j.polymertesting.2016.07.024 .

C. Xing , H. Wang , Q. Hu , F. Xu , X. Cao , J. You . Mechanical and thermal properties of eco-friendly poly(propylene carbonate)/cellulose acetate butyrate blends . Carbohyd. Polym. , 2013 . 92 ( 2 ): 1921 - 1927 . DOI: 10.1016/j.carbpol.2012.11.058 http://doi.org/10.1016/j.carbpol.2012.11.058 .

X. Hu , C. Xu , J. Gao , G. Yang , C. Geng , F. Chen . Toward environment-friendly composites of poly(propylene carbonate) reinforced with cellulose nanocrystals . Compos. Sci. Technol. , 2013 . 78 ( 2 ): 63 - 68 . https://www.deepdyve.com/lp/elsevier/toward-environment-friendly-composites-of-poly-propylene-carbonate-LVJsj9dp2w https://www.deepdyve.com/lp/elsevier/toward-environment-friendly-composites-of-poly-propylene-carbonate-LVJsj9dp2w , .

S. Cui , L. Li , Q. Wang . Enhancing glass transition temperature and mechanical properties of poly(propylene carbonate) by intermacromolecular complexation with poly(vinyl alcohol) . Compos. Sci. Technol. , 2016 . 127 177 - 184 . DOI: 10.1016/j.compscitech.2016.03.007 http://doi.org/10.1016/j.compscitech.2016.03.007 .

J. Seo , G. Jeon , E. S. Jang , S. B. Khan , H. Han . Preparation and properties of poly(propylene carbonate) and nanosized zno composite films for packaging applications . J. Appl. Polym. Sci. , 2011 . 122 ( 2 ): 1101 - 1108 . DOI: 10.1002/app.v122.2 http://doi.org/10.1002/app.v122.2 .

P. Song , M. Xiao , F. Du , S. Wang , L. Gan , G. Liu . Synthesis and properties of aliphatic polycarbonates derived from carbon dioxide, propylene oxide and maleic anhydride . J. Appl. Polym. Sci. , 2008 . 109 ( 6 ): 4121 - 4129 . DOI: 10.1002/app.v109:6 http://doi.org/10.1002/app.v109:6 .

S. Wang , L. Du , X. Zhao , Y. Meng , S. Tjong . Synthesis and characterization of alternating copolymer from carbon dioxide and propylene oxide . J. Appl. Polym. Sci. , 2010 . 85 ( 11 ): 2327 - 2334 . http://cat.inist.fr/?aModele=afficheN&cpsidt=13747888 http://cat.inist.fr/?aModele=afficheN&cpsidt=13747888 , .

Z. Li , W. Li , H. Zhang , L. Dong . Thermal, rheological and mechanical properties of poly(propylene carbonate)/methyl methacrylate-butadiene-styrene blends . Iran. Polym. J , 2015 . 24 ( 10 ): 861 - 870 . DOI: 10.1007/s13726-015-0374-8 http://doi.org/10.1007/s13726-015-0374-8 .

L. Zhou , G. Zhao , W. Jiang . Effects of catalytic transesterification and composition on the toughness of poly(lactic acid)/poly(propylene carbonate) blends . Ind. Eng. Chem. Res. , 2016 . 55 ( 19 ): 5565 - 5573 . DOI: 10.1021/acs.iecr.6b00315 http://doi.org/10.1021/acs.iecr.6b00315 .

Y. Chen , Y. Peng , W. Liu , G. Zeng , X. Li , X. Yan . Study on the mechenical properties of PPC/PLA blends modified by poss . Adv. Mater. Res. , 2013 . 741 28 - 32 . DOI: 10.4028/www.scientific.net/AMR.741 http://doi.org/10.4028/www.scientific.net/AMR.741 .

J. Gao , Q. Fu , H. Bai , Q. Zhang . Effect of homopolymer poly(vinyl acetate) on compatibility and mechanical properties of poly(propylene carbonate)/poly(lactic acid) blends . Express Polym. Lett. , 2012 . 6 ( 11 ): 860 - 870 . DOI: 10.3144/expresspolymlett.2012.92 http://doi.org/10.3144/expresspolymlett.2012.92 .

M. Yao , H. Deng , F. Mai , K. Wang . Modification of poly(lactic acid)/poly(propylene carbonate) blends through melt compounding with maleic anhydride . Express Polym. Lett. , 2011 . 5 ( 11 ): 937 - 949 . DOI: 10.3144/expresspolymlett.2011.92 http://doi.org/10.3144/expresspolymlett.2011.92 .

S. W. Hwang , D. H. Park , D. H. Kang , S. B. Lee , J. K. Shim . Reactive compatibilization of poly(L-lactic acid)/poly(propylene carbonate) blends:thermal, thermomechanical, and morphological properties . J. Appl. Polym. Sci. , 2016 . 133 ( 18 ): DOI: 10.1002/APP.43388 http://doi.org/10.1002/APP.43388 .

D. Yuan , C. Xu , Z. Chen , Y. Chen . Crosslinked bicontinuous biobased polylactide/natural rubber materials:super toughness, "net-like"-structure of NR phase and excellent interfacial adhesion . Polym. Test , 2014 . 38 73 - 80 . DOI: 10.1016/j.polymertesting.2014.07.004 http://doi.org/10.1016/j.polymertesting.2014.07.004 .

P. Xu , P. Ma , X. Cai , S. Song , Y. Zhang , W. Dong . Selectively cross-linked poly (lactide)/ethylene-glycidyl methacrylate-vinyl acetate thermoplastic elastomers with partial dual-continuous network-like structures and shape memory performances . Eur. Polym. J. , 2016 . 84 1 - 12 . http://dx.doi.org/10.1016/j.eurpolymj.2016.09.004 http://dx.doi.org/10.1016/j.eurpolymj.2016.09.004 , .

T. Raidt , R. Hoeher , F. Katzenberg , J. C. Tiller . Chemical cross-linking of polypropylenes towards new shape memory polymers . Macromol. Rapid Commun. , 2015 . 36 ( 8 ): 744 - 749 . DOI: 10.1002/marc.v36.8 http://doi.org/10.1002/marc.v36.8 .

Y. Wang , G. Zhu , Y. Tang , J. Xie , T. Liu , Z. Liu . Mechanical and shape memory behavior of chemically cross-linked SBS/LDPE blends . J. Polym. Res. , 2014 . 21 ( 4 ): 1 - 10 . http://link.springer.com/10.1007/s10965-014-0405-8 http://link.springer.com/10.1007/s10965-014-0405-8 , .

P. Ma , X. Cai , Y. Zhang , S. Wang , W. Dong , M. Chen , P. J. Lemstra . In situ compatibilization of poly(lactic acid) and poly(butylene adipate- co -terephthalate) blends by using dicumyl peroxide as a free-radical initiator . Polym. Degrad. Stab. , 2014 . 102 ( 2 ): 145 - 151 . http://dx.doi.org/10.1016/j.polymdegradstab.2014.01.025 http://dx.doi.org/10.1016/j.polymdegradstab.2014.01.025 , .

N. I. Akos , M. U. Wahit , R. Mohamed , A. A. Yussuf . Preparation, characterization, and mechanical properties of poly( ε -caprolactone)/polylactic acid blend composites . Polym. Compos , 2013 . 34 ( 5 ): 763 - 768 . DOI: 10.1002/pc.v34.5 http://doi.org/10.1002/pc.v34.5 .

P. Rytlewski , M. Żenkiewicz , R. Malinowski . Influence of dicumyl peroxide content on thermal and mechanical properties of polylactide . Int. Polym. Proc. , 2013 . 26 ( 5 ): 580 - 586 . http://www.hanser-elibrary.com/doi/abs/10.3139/217.2521 http://www.hanser-elibrary.com/doi/abs/10.3139/217.2521 , .

S. W. Lim , M. C. Choi , J. H. Jeong , E. Y. Park , C. S. Ha . Toughening poly(lactic acid) (PLA) through reactive blending with liquid polybutadiene rubber (LPB) . Compos. Interface. , 2016 . 23 ( 8 ): 807 - 818 . DOI: 10.1080/09276440.2016.1175168 http://doi.org/10.1080/09276440.2016.1175168 .

M. Agarwal , K. W. Koelling , J. J. Chalmers . Characterization of the degradation of polylactic acid polymer in a solid substrate environment . Biotechnol. Prog. , 1998 . 14 ( 3 ): 517 - 526 . DOI: 10.1021/bp980015p http://doi.org/10.1021/bp980015p .

B. Fei , C. Chen , S. Peng , X. Zhao , X. Wang , L. Dong . FTIR study of poly(propylene carbonate)/bisphenol A blends . Polym. Int. , 2010 . 53 ( 12 ): 2092 - 2098 . http://cat.inist.fr/?aModele=afficheN&cpsidt=16262942 http://cat.inist.fr/?aModele=afficheN&cpsidt=16262942 , .

Views

Downloads

CSCD

Alert me when the article has been cited

Submit

Tools

Publicity Resources

Design of Tough, yet Strong, Heat-resistant PLA/PBAT Blends with Reconfigurable Shape Memory Behavior by Engineering Exchangeable Covalent Crosslinks

Preparation and Characteristics of Poly(butylene adipate-co-terephthalate)/Polylactide Blend Films via Synergistic Efficiency of Plasticization and Compatibilization

Water Swelling-induced Stiffness Enhancement of Polymer Hydrogels

Optimization of 4D Printing Performance of Poly(lactic acid)/Thermoplastic Polyurethane Composites via Orthogonal Design and the Synergistic Effect of Crosslinking Agent-coupling Agent

Sequence-encoded Conformation Pathways in Viscoelastic Microphase Separation of Multiblock Copolymers

Related Author

Xiao-Wen Zhou

Jing Huang

Xu-Hui Zhang

Ting Li

Yang Wang

Shi-Bo Wang

Bi-Hua Xia

Wei-Fu Dong

Related Institution

The Key Laboratory of Synthetic and Biological Colloids, Ministry of Education, School of Chemical and Material Engineering, Jiangnan University

Department of Materials Science and Technology, Faculty of Science, Prince of Songkla University, Hatyai

Bioplastic Research Unit, Department of Materials Science and Technology, Faculty of Science, Prince of Songkla University, Hatyai

Department of Chemistry, Faculty of Science, Prince of Songkla University, Hatyai

Department of Materials Science, Faculty of Science, Chulalongkorn University

⁰

Fully Biodegradable Poly(lactic acid)/Poly(propylene carbonate) Shape Memory Materials with Low Recovery Temperature Based on in situ Compatibilization by Dicumyl Peroxide

DOI：10.1007/s10118-018-2065-3

摘要

Abstract

关键词

Keywords

references