Synthesis of Novel Scolopendra-type Polydodecyloxybenzoyl[1, 5]-diazocine as New Material for Optical Sensor

Ya-Nan Liu; Jian-Zhong Li; Xiao-Bo Wan

doi:10.1007/s10118-018-2062-6

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Synthesis of Novel Scolopendra-type Polydodecyloxybenzoyl[1, 5]-diazocine as New Material for Optical Sensor

Articles | Updated：2021-02-18

- Synthesis of Novel Scolopendra-type Polydodecyloxybenzoyl[1, 5]-diazocine as New Material for Optical Sensor
- Chinese Journal of Polymer Science Vol. 36, Issue 6, Pages: 736-741(2018)
- Affiliations：
  
  a.College of Chemistry and Pharmaceutical Sciences, Qingdao Agricultural University, Qingdao 266109, China
  b.Qingdao institute of Bioprocess Technology, Chinese Academy of Science, Qingdao 266101, China
- Author bio：
  
  E-mail jzhlee@163.com (J.Z.L.)
  E-mail wanxb@qibebt.ac.cn (X.B.W.)
- Funds：
- DOI：10.1007/s10118-018-2062-6
  CLC：
- Received：01 September 2017，
  
  Accepted：11 October 2017，
  
  Online First：08 February 2018，
  
  Published：2018-06
- Accepted：
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Ya-Nan Liu, Jian-Zhong Li, Xiao-Bo Wan. Synthesis of Novel Scolopendra-type Polydodecyloxybenzoyl[1, 5]-diazocine as New Material for Optical Sensor[J]. Chinese Journal of Polymer Science, 2018, 36(6): 736-741.
DOI：

Ya-Nan Liu, Jian-Zhong Li, Xiao-Bo Wan. Synthesis of Novel Scolopendra-type Polydodecyloxybenzoyl[1, 5]-diazocine as New Material for Optical Sensor[J]. Chinese Journal of Polymer Science, 2018, 36(6): 736-741. DOI： 10.1007/s10118-018-2062-6.

摘要

Abstract

A new scolopendra-type polymer of polydodecyloxybenzoyl[1

5]-diazocine (

PDBD

) was designed and prepared using 2

5-bis(4-(dodecyloxy)-benzoyl)terephthaloyl azide with trifluoroacetic acid (TFA)

via

one-pot reaction in good yields. The structure of polymer was characterized using

H-NMR

C-NMR and MALDI-TOF spectra. The polymer

PDBD

exhibits good thermal stability as measured by TGA and DSC

and can be dissolved well in common organic solvents such as chloroform and tetrahydrofuran. In addition

UV-Vis spectral studies indicate that the polymer

PDBD

shows unique optical property changes (protonation/deprotonation) in the different trifluoroacetic acid environments. The new polymer is expected to be utilized as an optical functional material for fabricating optical sensors in environmental and biological fields.

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references

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