Isothermal Crystallization Kinetics and Crystalline Morphologies of Poly(butylene adipate-<italic style="font-style: italic">co</italic>-butylene 1, 4-cyclohexanedicarboxylate) Copolymers

Fei Liu; De-Quan Chi; Hai-Ning Na; Jin Zhu

doi:10.1007/s10118-018-2051-9

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Isothermal Crystallization Kinetics and Crystalline Morphologies of Poly(butylene adipate-co-butylene 1, 4-cyclohexanedicarboxylate) Copolymers

Articles | Updated：2021-02-18

- Isothermal Crystallization Kinetics and Crystalline Morphologies of Poly(butylene adipate-co-butylene 1, 4-cyclohexanedicarboxylate) Copolymers
- Chinese Journal of Polymer Science Vol. 36, Issue 6, Pages: 756-764(2018)
- Affiliations：
  
  a.Ningbo Key Laboratory of Polymer Materials, Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo 315201, China
  b.College of Materials Science and Engineering, Qingdao University of Science and Technology, Qingdao 266042, China
- Author bio：
  
  Hai-Ning Na, E-mail nahaining@nimte.ac.cn (H.N.N.)
- Funds：
- DOI：10.1007/s10118-018-2051-9
  CLC：
- Received：01 September 2017，
  
  Accepted：25 September 2017，
  
  Online First：08 February 2018，
  
  Published：2018-06
- Accepted：
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Fei Liu, De-Quan Chi, Hai-Ning Na, et al. Isothermal Crystallization Kinetics and Crystalline Morphologies of Poly(butylene adipate-co-butylene 1, 4-cyclohexanedicarboxylate) Copolymers[J]. Chinese Journal of Polymer Science, 2018, 36(6): 756-764. DOI: 10.1007/s10118-018-2051-9.
DOI：

Fei Liu, De-Quan Chi, Hai-Ning Na, et al. Isothermal Crystallization Kinetics and Crystalline Morphologies of Poly(butylene adipate-co-butylene 1, 4-cyclohexanedicarboxylate) Copolymers[J]. Chinese Journal of Polymer Science, 2018, 36(6): 756-764. DOI: 10.1007/s10118-018-2051-9. DOI：

摘要

Abstract

In this study

the isothermal crystallization kinetics and crystalline morphology of poly(butylene adipate-

-butylene 1

4-cyclohexanedicarboxylate) (PBAC)

which refers to a copolyester containing a non-planar ring structure

were investigated by differential scanning calorimetry and polarized optical microscopy

and compared with those of neat poly(butylene 1

4-cyclohexanedicarboxylate) (PBC). The results indicate that the introduction of butylene adipate (BA) unit into PBAC did not change the intrinsical crystallization mechanism. But

the crystallization rate and ability

and equilibrium melting temperature of PBAC copolymers were reduced. All PBC and PBAC copolymers could only form high density of nucleation from melt at given supercooling

while no Maltese cross or ring-banded spherulites could be observed. PBAC copolymers with a high amount of BA unit became amorphous after quenching with liquid nitrogen from melt

while PBC and PBAC copolymers with a low amount of BA unit could still form a large amount of nuclei under the same treatment.

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Isothermal Crystallization Kinetics and Crystalline Morphologies of Poly(butylene adipate-co-butylene 1, 4-cyclohexanedicarboxylate) Copolymers

DOI：10.1007/s10118-018-2051-9

摘要

Abstract

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Keywords

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