HCAⅡ-inspired Catalysts for Making Carbon Dioxide-based Copolymers: The Role of Metal-hydroxide Bond

Yang Li; Ying-Ying Zhang; Bin Liu; Xing-Hong Zhang

doi:10.1007/s10118-018-2047-5

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HCAⅡ-inspired Catalysts for Making Carbon Dioxide-based Copolymers: The Role of Metal-hydroxide Bond

Reviews | Updated：2021-02-18

- HCAⅡ-inspired Catalysts for Making Carbon Dioxide-based Copolymers: The Role of Metal-hydroxide Bond
- Chinese Journal of Polymer Science Vol. 36, Issue 2, Pages: 139-148(2018)
- Affiliations：
  
  Ministry of Education Key Laboratory of Macromolecular Synthesis and Functionalization, Department of Polymer Science
- Author bio：
  
  Xing-Hong Zhang, E-mail xhzhang@zju.edu.cn
- Funds：
- DOI：10.1007/s10118-018-2047-5
  CLC：
- Received：30 August 2017，
  
  Accepted：21 September 2017，
  
  Online First：21 November 2017，
  
  Published：05 February 2018
- Accepted：
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Yang Li, Ying-Ying Zhang, Bin Liu, et al. HCAⅡ-inspired Catalysts for Making Carbon Dioxide-based Copolymers: The Role of Metal-hydroxide Bond[J]. Chinese Journal of Polymer Science, 2018, 36(2): 139-148.
DOI：

Yang Li, Ying-Ying Zhang, Bin Liu, et al. HCAⅡ-inspired Catalysts for Making Carbon Dioxide-based Copolymers: The Role of Metal-hydroxide Bond[J]. Chinese Journal of Polymer Science, 2018, 36(2): 139-148. DOI： 10.1007/s10118-018-2047-5.

摘要

Abstract

The general characteristics of the active center of the catalysts (including zinc-cobalt(Ⅲ) double metal cyanide complex [Zn-Co(Ⅲ) DMCC]) for the copolymerization reaction of carbon dioxide (CO

) with epoxide are summarized. By comparing the active center

catalytic performance of the Zn-Co(Ⅲ) DMCC (and other catalysts) with HCAII enzyme in the organism for activating CO

(COS and CS

)

we proposed that the metal-hydroxide bond (M-OH)

which is the real catalytic center of human carbonic anhydride II (HCAII)

is also the catalytic (initiating) center for the copolymerization. It accelerates the copolymerization and forms a closed catalytic cycle through the chain transfer reaction to water (and thus strictly meets the definition of the catalyst). In addition

the metal-hydroxide bond catalysis could well explain the oxygen/sulfur exchange reaction (O/S ER) in metal (Zn

Cr)-catalyzed copolymerization of COS (and CS

) with epoxides. Therefore

it is very promising to learn from HCAII enzyme to develop biomimetic catalyst for highly active CO

/epoxide copolymerization in a well-controlled manner under mild conditions.

关键词

Keywords

references

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