Designing a Phthalonitrile/Benzoxazine Blend for the Advanced GFRP Composite Materials

Xu-Lin Yang; Kui Li; Ming-Zhen Xu; Xiao-Bo Liu

doi:10.1007/s10118-018-2033-y

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Designing a Phthalonitrile/Benzoxazine Blend for the Advanced GFRP Composite Materials

PAPERS | Updated：2021-02-18

- Designing a Phthalonitrile/Benzoxazine Blend for the Advanced GFRP Composite Materials
- Chinese Journal of Polymer Science Vol. 36, Issue 1, Pages: 106-112(2018)
- Affiliations：
  
  Research Branch of Functional Materials, Institute of Microelectronic & Solid State Electronic, University of Electronic Science and Technology of China, Chengdu 610054, China
- Author bio：
  
  E-mail mzxu628@uestc.edu.cn (M.Z.X.)
  E-mail liuxb@uestc.edu.cn (X.B.L.)
- Funds：
- DOI：10.1007/s10118-018-2033-y
  CLC：
- Received：30 June 2017，
  
  Accepted：05 September 2017，
  
  Online First：30 October 2017，
  
  Published：05 January 2018
- Accepted：
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Xu-Lin Yang, Kui Li, Ming-Zhen Xu, et al. Designing a Phthalonitrile/Benzoxazine Blend for the Advanced GFRP Composite Materials[J]. Chinese Journal of Polymer Science, 2018, 36(1): 106-112.
DOI：

Xu-Lin Yang, Kui Li, Ming-Zhen Xu, et al. Designing a Phthalonitrile/Benzoxazine Blend for the Advanced GFRP Composite Materials[J]. Chinese Journal of Polymer Science, 2018, 36(1): 106-112. DOI： 10.1007/s10118-018-2033-y.

摘要

Abstract

High performance resin must be used in the high performance glass fiber-reinforced plastic (GFRP) composites

but it is sometimes difficult to balance the processabilities and the final properties in the design of advanced thermoset GFRP composites. In this study

a phthalonitrile/benzoxazine (PPN/BZ) blend with excellent processability has been designed and applied in the GFRP composite materials. PPN/BZ blend with good solubility

low melt viscosity

appropriate gel condition and low-temperature curing behavior could enable their GFRP composite preparation with the prepreg-laminate method under a relatively mild condition. The resulted PPN/BZ GFRP composites exhibit excellent mechanical properties with flexural strength over 700 MPa and flexural modulus more than 19 GPa. Fracture surface morphologies of the PPN/BZ GFRP composites show that the interfacial adhesion between resin and GF is improved. The temperatures at weight loss 5% (

) and char residue at 800℃ of all PPN/BZ GFRP composites are over 435℃ and 65% respectively. PPN/BZ GFRP composites with high performance characteristics may find applications under some critical circumstances with requirements of high mechanical properties and high service temperatures.

关键词

Keywords

references

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