Phthalonitrile-PPO Blends: Cure Behavior and Properties

Jing-Zhi Ma; Kang Cheng; Jiang-Bo Lv; Chang Chen; Jiang-Huai Hu; Ke Zeng; Gang Yang

doi:10.1007/s10118-018-2026-x

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Phthalonitrile-PPO Blends: Cure Behavior and Properties

Articles | Updated：2021-02-18

- Phthalonitrile-PPO Blends: Cure Behavior and Properties
- Chinese Journal of Polymer Science Vol. 36, Issue 4, Pages: 497-504(2018)
- Affiliations：
  
  State Key Laboratory of Polymer Materials Engineering, College of Polymer Science and Engineering, Sichuan University, Chengdu 610065, China
- Author bio：
  
  E-mail zk_ican@sina.com (K.Z.)
  E-mail yanggang65420@163.com (G.Y.)
- Funds：
- DOI：10.1007/s10118-018-2026-x
  CLC：
- Received：06 July 2017，
  
  Accepted：26 August 2017，
  
  Online First：16 November 2017，
  
  Published：05 April 2018
- Accepted：
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Jing-Zhi Ma, Kang Cheng, Jiang-Bo Lv, et al. Phthalonitrile-PPO Blends: Cure Behavior and Properties[J]. Chinese Journal of Polymer Science, 2018, 36(4): 497-504.
DOI：

Jing-Zhi Ma, Kang Cheng, Jiang-Bo Lv, et al. Phthalonitrile-PPO Blends: Cure Behavior and Properties[J]. Chinese Journal of Polymer Science, 2018, 36(4): 497-504. DOI： 10.1007/s10118-018-2026-x.

摘要

Abstract

Hydroxy-containing low molecular weight poly(2

6-dimethyl-1

4-phenylene oxide) (rPPO) and self-promoted hydroxy-containing phthalonitrile (HPPH) were prepared by redistribution reaction and the simple nucleophilic displacement of a nitro-substituent from 4-nitrophthalonitrile in a dipolar aprotic solvent respectively. The hydroxy-containing phthalonitriles modified by rPPO were prepared by mechanical blending without compatibilizer

followed by heating. The curing behavior was studied using dynamic rheological analysis

and the results showed that the rPPO-modified phthalonitrile exhibited a large processing window (over -67℃) and complex viscosity (0.18-0.8 Pa·s) at moderate temperatures. After curing at 300℃

the resulting polymers showed good thermal stability and high modulus as observed by thermogravimetric analysis (TGA) and dynamic mechanical analysis (DMA). The dielectric properties and the morphology of rPPO-modified phthalonitrile networks were studied by dielectric analysis and field-emission scanning electron microscopy (SEM).

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references

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