Self-Healing Supramolecular Polymer Composites by Hydrogen Bonding Interactions between Hyperbranched Polymer and Graphene Oxide

Yi-Gang Luan; Xiao-A Zhang; Sheng-Ling Jiang; Jian-Huan Chen; Ya-Fei Lyu

doi:10.1007/s10118-018-2025-y

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Self-Healing Supramolecular Polymer Composites by Hydrogen Bonding Interactions between Hyperbranched Polymer and Graphene Oxide

Articles | Updated：2021-02-18

- Self-Healing Supramolecular Polymer Composites by Hydrogen Bonding Interactions between Hyperbranched Polymer and Graphene Oxide
- Chinese Journal of Polymer Science Vol. 36, Issue 5, Pages: 584-591(2018)
- Affiliations：
  
  Key Laboratory of Carbon Fiber and Functional Polymers of Ministry of Education, College of Materials Science and Engineering, Beijing University of Chemical Technology, Beijing 100029, China
- Author bio：
  
  Ya-Fei Lyu, E-mail ylu623@hotmail.com
- Funds：
- DOI：10.1007/s10118-018-2025-y
  CLC：
- Received：01 August 2017，
  
  Accepted：25 August 2017，
  
  Online First：18 January 2018，
  
  Published：2018-05
- Accepted：
Scan QR Code
Yi-Gang Luan, Xiao-A Zhang, Sheng-Ling Jiang, et al. Self-Healing Supramolecular Polymer Composites by Hydrogen Bonding Interactions between Hyperbranched Polymer and Graphene Oxide[J]. Chinese Journal of Polymer Science, 2018, 36(5): 584-591.
DOI：

Yi-Gang Luan, Xiao-A Zhang, Sheng-Ling Jiang, et al. Self-Healing Supramolecular Polymer Composites by Hydrogen Bonding Interactions between Hyperbranched Polymer and Graphene Oxide[J]. Chinese Journal of Polymer Science, 2018, 36(5): 584-591. DOI： 10.1007/s10118-018-2025-y.

摘要

Abstract

A self-healing supramolecular polymer composite (HSP-GO) was designed and prepared

via

incorporation of modified graphene oxide to hyperbranched polymer by hydrogen-bonding interactions. The polymer matrix based on amino-terminated hyperbranched polymer (HSP-NH

) was synthesized by carboxylation

Curtius rearrangement

and amination of hydroxyl-terminated hyperbranched polyester (HP-OH)

while the modified graphene oxide was prepared by transformation of hydroxyl to isocyanate and further to carbamate ester. Spectroscopic methods were utilized to characterize the obtained polymer composites. Stress-strain test was selected to carefully study the self-healing property of HSP-GO. It is found that a small amount of modified graphene oxide (up to 2 wt%) improves the glass transition temperature (

)

tensile strength

Young's modulus

and self-healing efficiency of the polymer composites. After healed at room temperature for 10 min

the addition of modified graphene oxide improves the self-healing efficiency to 37% of its original tensile strength. The experiment result shows that the self-healing efficiency is related to the density of hydrogen bonding site and the molecular movement.

关键词

Keywords

references

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