Mixed Matrix Membranes of Polysulfone/Polyimide Reinforced with Modified Zeolite Based Filler: Preparation, Properties and Application

Sedra Tul Muntha; Muhammad Siddiq; Ayesha Kausar; Anum Khan

doi:10.1007/s10118-018-2021-2

Your Location：

Home >

Browse articles >

Mixed Matrix Membranes of Polysulfone/Polyimide Reinforced with Modified Zeolite Based Filler: Preparation, Properties and Application

PAPERS | Updated：2021-02-18

- Mixed Matrix Membranes of Polysulfone/Polyimide Reinforced with Modified Zeolite Based Filler: Preparation, Properties and Application
- Chinese Journal of Polymer Science Vol. 36, Issue 1, Pages: 65-77(2018)
- Affiliations：
  
  a.Department of Chemistry, Quaid i Azam University, Islamabad 45320, Pakistan
  b.Department of Microbiology, Quaid i Azam University, Islamabad 45320, Pakistan
- Author bio：
  
  Muhammad Siddiq, E-mail m_sidiq12@yahoo.com
- Funds：
- DOI：10.1007/s10118-018-2021-2
  CLC：
- Received：21 July 2017，
  
  Accepted：17 August 2017，
  
  Online First：30 October 2017，
  
  Published：05 January 2018
- Accepted：
Scan QR Code
Sedra Tul Muntha, Muhammad Siddiq, Ayesha Kausar, et al. Mixed Matrix Membranes of Polysulfone/Polyimide Reinforced with Modified Zeolite Based Filler: Preparation, Properties and Application[J]. Chinese Journal of Polymer Science, 2018, 36(1): 65-77.
DOI：

Sedra Tul Muntha, Muhammad Siddiq, Ayesha Kausar, et al. Mixed Matrix Membranes of Polysulfone/Polyimide Reinforced with Modified Zeolite Based Filler: Preparation, Properties and Application[J]. Chinese Journal of Polymer Science, 2018, 36(1): 65-77. DOI： 10.1007/s10118-018-2021-2.

摘要

Abstract

In this work

polysulfone/polyimide (PSf/PI) mixed matrix membranes were fabricated by reinforcement of modified zeolite (MZ) particles through solution casting method for investigation of antibacterial activity against two gram negative bacteria (

Salmonella typhi

Klebsella pneumonia

) and two gram positive bacteria (

Staphylococcus aureus

Bacillus subtilis

). The modified zeolite particles were incorporated to PSf and PI matrix and the influence of these particles on thermal

mechanical and structural properties was evaluated. The morphological evolution was investigated through scanning electron microscopy (SEM) and transmission electron microscopy (TEM) analysis

which revealed good compatibility between organic polymer matrix and inorganic filler. Mechanical stability was investigated by tensile testing while thermal analysis was evaluated by thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC). This revealed improvement in thermal properties with increasing filler concentration from 1 wt% to 10 wt%. Structural analysis was successfully done using X-ray diffraction analysis (XRD) and Fourier transform infrared (FTIR) spectroscopy. Solvent content of fabricated mixed matrix membranes was observed to decrease while moving from more hydrophilic to less hydrophilic solvent. However

addition of filler content enhanced the porosity of fabricated membranes. The synthesized mixed matrix membranes exhibited good antibacterial activity and the highest activity was shown by PSf/PI/MZ mixed matrix membrane. Therefore

the combination effect of PSf

PI and MZ sufficiently enhanced the antibacterial activity of mixed matrix membranes.

关键词

Keywords

references

R. Das , S. Ghosh , M. K. Naskar . Synthesis of single crystal zeolite L rods with high aspect ratio using rice husk ash as silica source . Indian J. Chem. A , 2014 . 53 ( 7 ): 816 - 819 . http://nopr.niscair.res.in/handle/123456789/29066 http://nopr.niscair.res.in/handle/123456789/29066 , .

M. Jabłońska , A. Król , E. Kukulska-Zając , K. Tarach , V. Girman , L. Chmielarz , K. Góra-Marek . Zeolites Y modified with palladium as effective catalysts for low-temperature methanol incineration . Appl. Catal, B , 2015 . 166 353 - 365 . https://www.sciencedirect.com/science/article/pii/S0926337314007607 https://www.sciencedirect.com/science/article/pii/S0926337314007607 , .

J. Ren , D. Yu , L. Feng , G. Wang , G. Lv . Nanocable-structured polymer/carbon nanotube composite with low dielectric loss and high impedance . Compos Part A., Appl Sci Manuf. , 2017 . 98 66 - 75 . DOI: 10.1016/j.compositesa.2017.03.014 http://doi.org/10.1016/j.compositesa.2017.03.014 .

C. Wang , L. Chen , J. Li , S. Sun , L. Ma , G. Wu , F. Zhao , B. Jiang , Y. Huang . Enhancing the interfacial strength of carbon fiber reinforced epoxy composites by green grafting of poly (oxypropylene) diamines . Compos Part A, Appl Sci Manuf. , 2017 . 99 58 - 64 . DOI: 10.1016/j.compositesa.2017.04.003 http://doi.org/10.1016/j.compositesa.2017.04.003 .

L. Liu , F. Lv , Y. Zhang , P. Li , W. Tong , L. Ding , G. Zhang . Enhanced dielectric performance of polyimide composites with modified sandwich-like SiO 2 @GO hybrids . Compos Part A, Appl Sci Manuf. , 2017 . 99 41 - 47 . DOI: 10.1016/j.compositesa.2017.03.029 http://doi.org/10.1016/j.compositesa.2017.03.029 .

B. Seoane , J. Coronas , I. Gascon , M. E. Benavides , O. Karvan , J. Caro , J. Gascon . Metal-organic framework based mixed matrix membranes:a solution for highly efficient CO 2 capture . Chem. Soc. Rev. , 2015 . 44 ( 8 ): 2421 - 2454 . DOI: 10.1039/C4CS00437J http://doi.org/10.1039/C4CS00437J .

L. Richtera , D. Chudobova , K. Cihalova , M. Kremplova , V. Milosavljevic , P. Kopel , I. Blazkova , D. Hynek , V. Adam , R. Kizek . The composites of graphene oxide with metal or semimetal nanoparticles and their effect on pathogenic microorganisms . Materials , 2015 . 8 ( 6 ): 2994 - 3011 . DOI: 10.3390/ma8062994 http://doi.org/10.3390/ma8062994 .

M. Ghaemy , R. Alizadeh , H. Behmadi . Synthesis of soluble and thermally stable polyimide from new diamine bearing N -[4-(9 H -carbazol-9-yl) phenyl] formamide pendent group . Eur. Polym. J. , 2009 . 45 ( 11 ): 3108 - 3115 . DOI: 10.1016/j.eurpolymj.2009.08.012 http://doi.org/10.1016/j.eurpolymj.2009.08.012 .

S. Rafiq , Z. Man , S. Maitra , A. Maulud , F. Ahmad , N. Muhammad . Preparation of asymmetric polysulfone/polyimide blended membranes for CO 2 separation . Korean J. Chem. Eng. , 2011 . 28 ( 10 ): 2050 - 2056 . DOI: 10.1007/s11814-011-0053-1 http://doi.org/10.1007/s11814-011-0053-1 .

F. Dorosti , M. R. Omidkhah , M. Z. Pedram , F. Moghadam . Fabrication and characterization of polysulfone/polyimidezeolite mixed matrix membrane for gas separation . Chem. Eng. J. , 2011 . 171 ( 3 ): 1469 - 1476 . DOI: 10.1016/j.cej.2011.05.081 http://doi.org/10.1016/j.cej.2011.05.081 .

M. Rezakazemi , A. E. Amooghin , M. M. Montazer-Rahmati , A. F. Ismail , T. Matsuura . State-of-the-art membrane based CO 2 separation using mixed matrix membranes (MMMs):an overview on current status and future directions . Prog. Polym. Sci. , 2014 . 39 ( 5 ): 817 - 861 . DOI: 10.1016/j.progpolymsci.2014.01.003 http://doi.org/10.1016/j.progpolymsci.2014.01.003 .

H. Yuan , X. Liu , L. Ma , Z. Yang , H. Wang , J. Wang , S. Yang . Application of two-dimensional MoS 2 nanosheets in the property improvement of polyimide matrix:mechanical and thermal aspects . Compos Part A, Appl Sci Manuf. , 2017 . 95 220 - 228 . DOI: 10.1016/j.compositesa.2017.01.018 http://doi.org/10.1016/j.compositesa.2017.01.018 .

A. Lateef , R. Nazir , N. Jamil , S. Alam , R. Shah , M. N Khan , M. Saleem . Synthesis and characterization of zeolite based nano-composite:an environment friendly slow release fertilizer. Micropo . Micropor. Mesopor. Mat. , 2016 . 232 174 - 183 . DOI: 10.1016/j.micromeso.2016.06.020 http://doi.org/10.1016/j.micromeso.2016.06.020 .

C. J. van-Oers , K. Góra-Marek , K. Sadowska , M. Mertens , V. Meynen , J. Datka , P. Cool . In situ IR spectroscopic study to reveal the impact of the synthesis conditions of zeolite β nanoparticles on the acidic properties of the resulting zeolite . Chem. Eng. J. , 2014 . 237 372 - 379 . DOI: 10.1016/j.cej.2013.10.041 http://doi.org/10.1016/j.cej.2013.10.041 .

K. Góra-Marek , K. Brylewska , K.A. Tarach , M. Rutkowska , M. Jabłońska , M. Choi , L. Chmielarz . IR studies of Fe modified ZSM-5 zeolites of diverse mesopore topologies in the terms of their catalytic performance in NH 3 -SCR and NH 3 -SCO processes . Appl. Catal., B Environ. , 2015 . 179 589 - 598 . DOI: 10.1016/j.apcatb.2015.05.053 http://doi.org/10.1016/j.apcatb.2015.05.053 .

M. Moreno-González , T. Blasco , K. Góra-Marek , A. E. Palomares , A. Corma . Study of propane oxidation on Cu-zeolite catalysts by in - situ EPR and IR spectroscopies . Catal Today. , 2014 . 227 123 - 129 . DOI: 10.1016/j.cattod.2013.10.055 http://doi.org/10.1016/j.cattod.2013.10.055 .

C. Marambio-Jones , E. M. Hoek . A review of the antibacterial effects of silver nanomaterials and potential implications for human health and the environment . J. Nanopart. Res. , 2010 . 12 ( 5 ): 1531 - 1551 . DOI: 10.1007/s11051-010-9900-y http://doi.org/10.1007/s11051-010-9900-y .

A. E. Amooghin , M. Omidkhah , A. Kargari . The effects of aminosilane grafting on NaY zeolite-Matrimid ® 5218 mixed matrix membranes for CO 2 /CH 4 separation . J. Member. Sci. , 2015 . 490 364 - 379 . DOI: 10.1016/j.memsci.2015.04.070 http://doi.org/10.1016/j.memsci.2015.04.070 .

M. Fathizadeh , A. Aroujalian , A. Raisi . Effect of added NaX nano-zeolite into polyamide as a top thin layer of membrane on water flux and salt rejection in a reverse osmosis process . J. Member. Sci. , 2011 . 375 ( 1 ): 88 - 95 . https://www.sciencedirect.com/science/article/pii/S0376738811001840 https://www.sciencedirect.com/science/article/pii/S0376738811001840 , .

M. Rezakazemi , K. Shahidi , T. Mohammadi . Hydrogen separation and purification using crosslinkable PDMS/zeolite A nanoparticles mixed matrix membranes . Int. J. Hydrogen Energy , 2012 . 37 ( 19 ): 14576 - 14589 . DOI: 10.1016/j.ijhydene.2012.06.104 http://doi.org/10.1016/j.ijhydene.2012.06.104 .

O. G. Nik , X. Y. Chen , S. Kaliaguine . Amine-functionalized zeolite FAU/EMT-polyimide mixed matrix membranes for CO 2 /CH 4 separation . J. Member. Sci. , 2011 . 379 ( 1 ): 468 - 478 . http://www.doc88.com/p-4087778424008.html http://www.doc88.com/p-4087778424008.html , .

J. S. Taurozzi , H. Arul , V. Z. Bosak , A. F. Burban , T. C. Voice , M. L. Bruening , V. V. Tarabara . Effect of filler incorporation route on the properties of polysulfone-silver nanocomposite membranes of different porosities . J. Member. Sci. , 2008 . 325 ( 1 ): 58 - 68 . DOI: 10.1016/j.memsci.2008.07.010 http://doi.org/10.1016/j.memsci.2008.07.010 .

S. Liu , T. H. Zeng , M. Hofmann , E. Burcombe , J. Wei , R. Jiang , Y. Chen . Antibacterial activity of graphite, graphite oxide, graphene oxide, and reduced graphene oxide:membrane and oxidative stress . ACS Nano , 2011 . 5 ( 9 ): 6971 - 6980 . DOI: 10.1021/nn202451x http://doi.org/10.1021/nn202451x .

A. Kausar , S. Zulfiqar , Z. Ahmad , M. I. Sarwar . Facile synthesis and properties of a new generation of soluble and thermally stable polyimides . Polym. Degrad. Stab. , 2010 . 95 ( 12 ): 2603 - 2610 . DOI: 10.1016/j.polymdegradstab.2010.07.025 http://doi.org/10.1016/j.polymdegradstab.2010.07.025 .

M. Biçen , N. Kayaman-Apohan , S. Karataş , F. Dumludağ , A. Güngör . The effect of surface modification of zeolite 4A on the physical and electrical properties of copolyimide hybrid films . Micropor Mesopor Mat. , 2015 . 218 79 - 87 . DOI: 10.1016/j.micromeso.2015.06.034 http://doi.org/10.1016/j.micromeso.2015.06.034 .

N. N. Ahmad , C. P. Leo , A. W. Mohammad , A. L. Ahmad . Modification of gas selective SAPO zeolites using imidazolium ionic liquid to develop polysulfone mixed matrix membrane for CO 2 gas separation . Micropor Mesopor Mater. , 2017 . 244 21 - 30 . DOI: 10.1016/j.micromeso.2016.10.001 http://doi.org/10.1016/j.micromeso.2016.10.001 .

Y. Ding , B. Bikson . Macro and meso porous polymeric materials from miscible polysulfone/polyimide blends by chemical decomposition of polyimides . Polymer , 2010 . 51 ( 1 ): 46 - 52 . DOI: 10.1016/j.polymer.2009.11.043 http://doi.org/10.1016/j.polymer.2009.11.043 .

M. U. Junaidi , C. P. Leo , A. L. Ahmad , S. N. Kamal , T. L. Chew . Carbon dioxide separation using asymmetric polysulfone mixed matrix membranes incorporated with SAPO-34 zeolite . Fuel Process Technol. , 2014 . 118 125 - 132 . DOI: 10.1016/j.fuproc.2013.08.009 http://doi.org/10.1016/j.fuproc.2013.08.009 .

R. Leyva-Ramos , A. Jacobo-Azuara , P. E. Diaz-Flores , R. M. GuerreroCoronado , J. Mendoza-Barron , M. S. Berber-Mendoza . Adsorption of chromium (Ⅵ) from an aqueous solution on a surfactant-modified zeolite . Colloid Surf. A Physicochem. Eng. Asp. , 2008 . 330 ( 1 ): 35 - 41 . DOI: 10.1016/j.colsurfa.2008.07.025 http://doi.org/10.1016/j.colsurfa.2008.07.025 .

M. Jabłońska , A. Król , E. Kukulska-Zając , K. Tarach , V. Girman , L. Chmielarz , K. Góra-Marek . Zeolites Y modified with palladium as effective catalysts for low-temperature methanol incineration . Appl. Catal., B , 2015 . 166 353 - 365 . https://www.sciencedirect.com/science/article/pii/S0926337314007607 https://www.sciencedirect.com/science/article/pii/S0926337314007607 , .

M. J. Jiménez-Cedillo , M. T. Olguín , C. Fall , A. Colín . Adsorption capacity of iron-or iron-manganese-modified zeolite-rich tuffs for As(Ⅲ) and As(Ⅴ) water pollutants . Appl. Clay Sci. , 2011 . 54 ( 3 ): 206 - 216 . https://www.sciencedirect.com/science/article/pii/S0959652617317419 https://www.sciencedirect.com/science/article/pii/S0959652617317419 , .

A. Kausar . Nanocomposite membranes of poly (ethylene glycol) diamine cured DGEBA/poly (vinylidene fluoride) reinforced with poly (methyl methacrylate) coated gold nanoparticles . Int. J. Plast. Technol, , 2015 . 19 ( 1 ): 106 - 123 . DOI: 10.1007/s12588-015-9107-2 http://doi.org/10.1007/s12588-015-9107-2 .

A. Jomekian , M. Pakizeh , A. R. Shafiee , S. A. Mansoori . Fabrication or preparation and characterization of new modified MCM-41/PSf nanocomposite membrane coated by PDMS . Sep. Purif. Technol. , 2011 . 80 ( 3 ): 556 - 565 . DOI: 10.1016/j.seppur.2011.06.011 http://doi.org/10.1016/j.seppur.2011.06.011 .

P. Kubica , A. Wolinska-Grabczyk , E. Grabiec , M. Libera , M. Wojtyniak , S. Czajkowska , M. Domański . Gas transport through mixed matrix membranes composed of polysulfone and copper terephthalate particles . Micropor. Mesopor. Mat. , 2016 . 235 120 - 134 . DOI: 10.1016/j.micromeso.2016.07.037 http://doi.org/10.1016/j.micromeso.2016.07.037 .

H. Shirzadi , A. Nezamzadeh-Ejhieh . An efficient modified zeolite for simultaneous removal of Pb(Ⅱ) and Hg(Ⅱ) from aqueous solution . J. Mol. Liq. , 2017 . 230 221 - 229 . DOI: 10.1016/j.molliq.2017.01.029 http://doi.org/10.1016/j.molliq.2017.01.029 .

A. Kausar . Novel water purification membranes of polystyrene/multi-walled carbon nanotube-grafted-graphene oxide hybrids . Am. J. Polym. Sci. , 2014 . 4 ( 3 ): 63 - 72 . http://article.sapub.org/10.5923.j.ajps.20140403.01.html http://article.sapub.org/10.5923.j.ajps.20140403.01.html , .

A. Mollahosseini , A. Rahimpour , M. Jahamshahi , M. Peyravi , M. Khavarpour . The effect of silver nanoparticle size on performance and antibacteriality of polysulfone ultrafiltration membrane . Desalination , 2012 . 306 41 - 50 . DOI: 10.1016/j.desal.2012.08.035 http://doi.org/10.1016/j.desal.2012.08.035 .

Views

411

Downloads

CSCD

Alert me when the article has been cited

Submit

Tools

Publicity Resources

Surface-engineered Cationic Copolymer Microspheres with Nano-multiple Humps Topography for Enhancing Antibacterial Efficacy

Facile Fabrication of Hyperbranched Polyacetal Quaternary Ammonium with pH-Responsive Curcumin Release for Synergistic Antibacterial Activity

Engineering Antibacterial Activities and Biocompatibility of Hyperbranched Lysine-based Random Copolymers

On-demand Peelable UV-curable Adhesives with Superior Bonding Strength: Rational Molecular Engineering of Cohesion-adhesion Synergy

Advances in Polymer-based Circularly Polarized Luminescent Materials

Related Author

Peng-Fei Song

Yu-Feng He

Rong-Min Wang

Ya-Ping Zhang

Tian Li

Jun Li

Xiao-Qi Cheng

De-Cheng Wu

Related Institution

Key Laboratory of Eco-functional Polymer Materials of the Ministry of Education, Institute of Polymers, College of Chemistry & Chemical Engineering, Northwest Normal University

Beijing National Laboratory for Molecular Sciences, State Key Laboratory of Polymer Physics & Chemistry, Institute of Chemistry, Chinese Academy of Sciences

University of Chinese Academy of Sciences

Department of Biomedical Engineering, Southern University of Science and Technology

University of Science and Technology of China

⁰