Investigations on the Interactions between Li-TFSI and Glass Fibers in the Ternary PP/GF/Li-TFSI Composites

Sen-Lin Gu; Huan-Huan Liu; Huan Cao; Claude Mercier; Yong-Jin Li

doi:10.1007/s10118-018-2018-x

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Investigations on the Interactions between Li-TFSI and Glass Fibers in the Ternary PP/GF/Li-TFSI Composites

PAPERS | Updated：2021-02-18

- Investigations on the Interactions between Li-TFSI and Glass Fibers in the Ternary PP/GF/Li-TFSI Composites
- Chinese Journal of Polymer Science Vol. 36, Issue 1, Pages: 113-118(2018)
- Affiliations：
  
  a.College of Material, Chemistry and Chemical Engineering, Hangzhou Normal University, Hangzhou 310036, China
  b.Solvay Co. Ltd, Shanghai 201100, China
- Author bio：
  
  Yong-Jin Li, E-mail yongjin-li@hznu.edu.cn
- Funds：
- DOI：10.1007/s10118-018-2018-x
  CLC：
- Received：06 July 2017，
  
  Accepted：08 August 2017，
  
  Online First：30 October 2017，
  
  Published：05 January 2018
- Accepted：
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Sen-Lin Gu, Huan-Huan Liu, Huan Cao, et al. Investigations on the Interactions between Li-TFSI and Glass Fibers in the Ternary PP/GF/Li-TFSI Composites[J]. Chinese Journal of Polymer Science, 2018, 36(1): 113-118.
DOI：

Sen-Lin Gu, Huan-Huan Liu, Huan Cao, et al. Investigations on the Interactions between Li-TFSI and Glass Fibers in the Ternary PP/GF/Li-TFSI Composites[J]. Chinese Journal of Polymer Science, 2018, 36(1): 113-118. DOI： 10.1007/s10118-018-2018-x.

摘要

Abstract

The polypropylene/glass fiber (PP/GF) composites with excellent antistatic performance and improved mechanical properties have been reported by incorporation of a very small amount of the organic salt

lithium bis(trifluoromethanesulfonyl)imide (Li-TFSI)

into the PP/GF composites. It was considered that GF could play the role as the pathways for the movements of ions in the ternary composites. In this work

the interactions between Li-TFSI and glass fiber and the effects of such interactions on the physical properties of the composites have been systematically investigated. Three types of glass fibers with different-OH group concentrations have been prepared in order to compare the interactions between GF and Li-TFSI. It was found that the-OH group concentrations on the surface of glass fiber have significant effects on interactions between glass fibers and Li-TFSI. Such interactions are crucial for both the antistatic and mechanical performances of the final PP/GF/Li-TFSI composites. The investigation indicated that the GF with high-OH group concentrations confined the movement of TFSI

which decreased the antistatic properties of PP/GF/Li-TFSI composites. On the other hand

the GF with low-OH group concentrations inhibited the absorption of Li-TFSI onto the GF

which also hindered the formation of Li-TFSI conductive pathway. The best antistatic performance of the ternary composites can be achieved at the intermediate-OH concentrations on the GF.

关键词

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references

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