Effects of Shell Composition, Dosage and Alkali Type on the Morphology of Polymer Hollow Microspheres

Wei Deng; Hua-Chao Guo; Wei-Li Yu; Cheng-You Kan

doi:10.1007/s10118-018-2012-3

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Effects of Shell Composition, Dosage and Alkali Type on the Morphology of Polymer Hollow Microspheres

Papers | Updated：2021-02-18

- Effects of Shell Composition, Dosage and Alkali Type on the Morphology of Polymer Hollow Microspheres
- Chinese Journal of Polymer Science Vol. 36, Issue 1, Pages: 43-48(2018)
- Affiliations：
  
  a.Key Laboratory of Engineering Dielectrics and Its Application, Ministry of Education, School of Material Science and Engineering, Harbin University of Science and Technology, Harbin 150080, China
  b.Department of Chemical Engineering, Key Laboratory of Advanced Materials of Ministry of Education, Tsinghua University, Beijing 100084, China
- Author bio：
  
  E-mail weideng@hrbust.edu.cn (W.D.)
  E-mail kancy@tsinghua.edu.cn (C.Y.K.)
- Funds：
- DOI：10.1007/s10118-018-2012-3
  CLC：
- Received：11 May 2017，
  
  Revised：2017-7-15，
  
  Accepted：15 July 2017，
  
  Online First：08 October 2017，
  
  Published：05 January 2018
- Accepted：
Scan QR Code
Wei Deng, Hua-Chao Guo, Wei-Li Yu, et al. Effects of Shell Composition, Dosage and Alkali Type on the Morphology of Polymer Hollow Microspheres[J]. Chinese Journal of Polymer Science, 2018, 36(1): 43-48.
DOI：

Wei Deng, Hua-Chao Guo, Wei-Li Yu, et al. Effects of Shell Composition, Dosage and Alkali Type on the Morphology of Polymer Hollow Microspheres[J]. Chinese Journal of Polymer Science, 2018, 36(1): 43-48. DOI： 10.1007/s10118-018-2012-3.

摘要

Abstract

Polymer hollow microspheres were prepared by performing alkali treatment on the multilayer core/shell polymer latex particles containing carboxyl groups. Effects of the shell composition and dosage as well as alkali type on the morphology of the microspheres were investigated. Results showed that in comparison with acrylonitrile (AN) and methacrylic acid (MAA)

using butyl acrylate (BA) as the shell co-monomer decreased the glass transition temperature (

) of shell effectively and was beneficial to the formation of uniform and big hollow structure. Along with the increase of the shell dosage

the alkali-treated microspheres sequentially presented porous and hollow morphology

and the size of microspheres increased

while the hollow diameter increased first and then decreased

and the maximum hollow ratio reached 39.5%. Furthermore

the multilayer core/shell microspheres had better tolerance to NH

·H

O than to NaOH. When the molar ratio of alkali to methacrylic acid (MR

alkali/acid

) for NaOH ranged from 1.15 to 1.30 or MR

alkali/acid

for NH

·H

O ranged from 1.30 to 2.00

the regular polymer hollow microspheres could be obtained.

关键词

Keywords

references

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