Scalable Ambient Pressure Synthesis of Covalent Organic Frameworks and Their Colorimetric Nanocomposites through Dynamic Imine Exchange Reactions

Wei Zhao; Jia Qiao; Tian-Li Ning; Xi-Kui Liu

doi:10.1007/s10118-018-2010-5

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Scalable Ambient Pressure Synthesis of Covalent Organic Frameworks and Their Colorimetric Nanocomposites through Dynamic Imine Exchange Reactions

Rapid Communications | Updated：2021-02-18

- Scalable Ambient Pressure Synthesis of Covalent Organic Frameworks and Their Colorimetric Nanocomposites through Dynamic Imine Exchange Reactions
- Chinese Journal of Polymer Science Vol. 36, Issue 1, Pages: 1-7(2018)
- Affiliations：
  
  College of Polymer Science and Engineering, Sichuan University, Chengdu 610065, China
- Author bio：
  
  Xi-Kui Liu, E-mail xkliu@scu.edu.cn
- Funds：
- DOI：10.1007/s10118-018-2010-5
  CLC：
- Received：11 June 2017，
  
  Revised：2017-7-18，
  
  Accepted：18 July 2017，
  
  Online First：08 November 2017，
  
  Published：05 January 2018
- Accepted：
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Wei Zhao, Jia Qiao, Tian-Li Ning, et al. Scalable Ambient Pressure Synthesis of Covalent Organic Frameworks and Their Colorimetric Nanocomposites through Dynamic Imine Exchange Reactions[J]. Chinese Journal of Polymer Science, 2018, 36(1): 1-7.
DOI：

Wei Zhao, Jia Qiao, Tian-Li Ning, et al. Scalable Ambient Pressure Synthesis of Covalent Organic Frameworks and Their Colorimetric Nanocomposites through Dynamic Imine Exchange Reactions[J]. Chinese Journal of Polymer Science, 2018, 36(1): 1-7. DOI： 10.1007/s10118-018-2010-5.

摘要

Abstract

A novel scale-up ambient pressure synthetic strategy for the preparation of imine-based covalent organic frameworks (COFs) was proposed through dynamic imine exchange reaction mechanism. The obtained COFs exhibited good crystallinity and much higher porosity comparable to their solvothermally synthesized counterparts. Moreover

under ambient pressure

the COF nanofibers could readily grow on the surface of polyimide films

and the resulted nanocomposite film showed an interesting colorimetric acid-responsive behavior.

关键词

Keywords

references

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