Cyclodextrin-functionalized Ordered Porous Block Copolymer Films: Preparation and Property

Jing Dang; Yuan-Wei Su; Wei Tian

doi:10.1007/s10118-018-2005-2

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Cyclodextrin-functionalized Ordered Porous Block Copolymer Films: Preparation and Property

Papers | Updated：2021-02-18

- Cyclodextrin-functionalized Ordered Porous Block Copolymer Films: Preparation and Property
- Chinese Journal of Polymer Science Vol. 36, Issue 1, Pages: 34-42(2018)
- Affiliations：
  
  Ministry of Education Key Laboratory of Material Physics and Chemistry under Extraordinary Conditions and Shaanxi Key Laboratory of Macromolecular Science and Technology, School of Science, Northwestern Polytechnical University, Xi'an 710072, China
- Author bio：
  
  Wei Tian, E-mail happytw_3000@nwpu.edu.cn
- Funds：
- DOI：10.1007/s10118-018-2005-2
  CLC：
- Received：09 May 2017，
  
  Revised：2017-7-3，
  
  Accepted：03 July 2017，
  
  Online First：22 September 2017，
  
  Published：05 January 2018
- Accepted：
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Jing Dang, Yuan-Wei Su, Wei Tian. Cyclodextrin-functionalized Ordered Porous Block Copolymer Films: Preparation and Property[J]. Chinese Journal of Polymer Science, 2018, 36(1): 34-42.
DOI：

Jing Dang, Yuan-Wei Su, Wei Tian. Cyclodextrin-functionalized Ordered Porous Block Copolymer Films: Preparation and Property[J]. Chinese Journal of Polymer Science, 2018, 36(1): 34-42. DOI： 10.1007/s10118-018-2005-2.

摘要

Abstract

Ordered porous block copolymer films (PBCFs) have attracted much attention because of their potential applications in several fields. In this paper

we first reported a non-destructive

controllable

and efficient approach for preparation of

-cyclodextrin (

-CD)-functionalized PBCFs (

-CD-PBCFs). The key point of the approach is to incorporate

-CD units into the hydrophilic segment of amphiphilic block copolymers before the preparation of films.

-CD-PBCFs with structural integrity and controllable pore parameters were fabricated through combining of self-assembly and breath figure methods. And then

the effective adsorption capacity of

-CD-PBCFs toward Congo red was confirmed through UV-Vis spectroscopy and was found to be affected by

-CD content and solution pH values. Adsorption kinetic results showed that the adsorption behavior of

-CD-PBCFs was consistent with the pseudo-second-order kinetic model and the chemisorption mechanism.

关键词

Keywords

references

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