Polythiophene-block-poly(phenyl isocyanide) Copolymers:One-pot Synthesis, Properties and Applications

Li Zhou; Zhi-qiang Jiang; Na Xu; Na Liu; Zong-quan Wu

doi:10.1007/s10118-017-2003-9

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Polythiophene-block-poly(phenyl isocyanide) Copolymers:One-pot Synthesis, Properties and Applications

Reviews | Updated：2021-02-18

- Polythiophene-block-poly(phenyl isocyanide) Copolymers:One-pot Synthesis, Properties and Applications
- Chinese Journal of Polymer Science Vol. 35, Issue 12, Pages: 1447-1456(2017)
- Affiliations：
  
  Department of Polymer Science and Engineering, School of Chemistry and Chemical Engineering, and Anhui Key Laboratory of Advanced Catalytic Materials and Reaction Engineering, Hefei University of Technology, Hefei 230009, China
- Author bio：
  
  Na Liu (刘娜), E-mail:liuna@hfut.edu.cn
  Zong-quan Wu (吴宗铨), E-mail:zqwu@hfut.edu.cn
- Funds：
- DOI：10.1007/s10118-017-2003-9
  CLC：
- Received：14 July 2017，
  
  Revised：2017-08-09，
  
  Accepted：17 August 2017，
  
  Published：05 December 2017
- Accepted：
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Li Zhou, Zhi-qiang Jiang, Na Xu, et al. Polythiophene-block-poly(phenyl isocyanide) Copolymers:One-pot Synthesis, Properties and Applications[J]. Chinese Journal of Polymer Science, 2017, 35(12): 1447-1456.
DOI：

Li Zhou, Zhi-qiang Jiang, Na Xu, et al. Polythiophene-block-poly(phenyl isocyanide) Copolymers:One-pot Synthesis, Properties and Applications[J]. Chinese Journal of Polymer Science, 2017, 35(12): 1447-1456. DOI： 10.1007/s10118-017-2003-9.

摘要

Abstract

Conjugated block copolymers have gained increasing interests in recent years. Development of a novel method for facile synthesis of conjugated block copolymers with desired structures and functions is greatly desired. In this mini review

we summarized the recent advances in one-pot synthesis of conjugated block copolymers containing

-conjugated polythiophene and helical polyisocyanide segments by using a nickel(Ⅱ) complex as single catalyst. The sequential living polymerization of the two monomers proceeded in a controlled manner

affording expected block copolymers in high yields with controlled molecular weights (

s) and narrow molecular weight distributions (M

s). By using this method

a family of block copolymers with expected structure and tunable compositions can be facilely prepared. Introducing functional groups onto the pendant

these block copolymers can exhibit interesting self-assembly property

tunable light emission and multi-responsiveness.

关键词

Keywords

references

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