Visualized Bond Scission in Mechanically Activated Polymers

Yuan Yuan; Yu-lan Chen

doi:10.1007/s10118-017-2002-x

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Visualized Bond Scission in Mechanically Activated Polymers

Reviews | Updated：2021-02-18

- Visualized Bond Scission in Mechanically Activated Polymers
- Chinese Journal of Polymer Science Vol. 35, Issue 11, Pages: 1315-1327(2017)
- Affiliations：
  
  Department of Chemistry, Tianjin Key Laboratory of Molecular Optoelectronic Sciences, Tianjin University, and Collaborative Innovation Center of Chemical Science and Engineering, Tianjin 300072, China
- Author bio：
  
  Yu-lan Chen(陈于蓝), E-mail:yulan.chen@tju.edu.cn
- Funds：
- DOI：10.1007/s10118-017-2002-x
  CLC：
- Received：27 June 2017，
  
  Revised：2017-7-18，
  
  Accepted：20 July 2017，
  
  Published：05 November 2017
- Accepted：
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Yuan Yuan, Yu-lan Chen. Visualized Bond Scission in Mechanically Activated Polymers[J]. Chinese Journal of Polymer Science, 2017, 35(11): 1315-1327.
DOI：

Yuan Yuan, Yu-lan Chen. Visualized Bond Scission in Mechanically Activated Polymers[J]. Chinese Journal of Polymer Science, 2017, 35(11): 1315-1327. DOI： 10.1007/s10118-017-2002-x.

摘要

Abstract

Visualization and quantitative evaluation of covalent bond scission in polymeric materials are critical in understanding their failure mechanisms and improving the toughness and reliability of the materials. Mechano-responsive polymers with the ability of molecular-level transduction of force into chromism and luminescence have evoked major interest and experienced significant progress. In the current review

we highlight the recent achievements in covalent mechanochromic and mechanoluminescent polymers

leading to a bridge between macroscopic mechanical properties and microscopic bond scission events. After a general introduction concerning polymer mechanochemistry

various examples that illustrate the strategies of design and incorporation of functional and weak covalent bonds in polymers were presented

the mechanisms underlying the optical phenomenon were introduced and their potential applications as stress sensors were discussed. This review concludes with a comment on the opportunities and challenges of the field.

关键词

Keywords

references

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