D-A Copolymers Based on a Pentacyclic Acceptor Unit and a 3, 3'-Difluoro-2, 2'-bithiophene for Solar Cells

Jia-min Cao; Liu Qian; Dan He; Zuo Xiao; Li-ming Ding

doi:10.1007/s10118-017-1996-4

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D-A Copolymers Based on a Pentacyclic Acceptor Unit and a 3, 3'-Difluoro-2, 2'-bithiophene for Solar Cells

Papers | Updated：2021-02-18

- D-A Copolymers Based on a Pentacyclic Acceptor Unit and a 3, 3'-Difluoro-2, 2'-bithiophene for Solar Cells
- Chinese Journal of Polymer Science Vol. 35, Issue 12, Pages: 1457-1462(2017)
- Affiliations：
  
  Center for Excellence in Nanoscience(Chinese Academy of Sciences), Key Laboratory of Nanosystem and Hierarchical Fabrication(Chinese Academy of Sciences), National Center for Nanoscience and Technology, Beijing 100190, China
- Author bio：
  
  Li-ming Ding (丁黎明), E-mail:ding@nanoctr.cn
- Funds：
- DOI：10.1007/s10118-017-1996-4
  CLC：
- Received：03 May 2017，
  
  Revised：2017-06-12，
  
  Accepted：16 June 2017，
  
  Published：05 December 2017
- Accepted：
Scan QR Code
Jia-min Cao, Liu Qian, Dan He, et al. D-A Copolymers Based on a Pentacyclic Acceptor Unit and a 3, 3'-Difluoro-2, 2'-bithiophene for Solar Cells[J]. Chinese Journal of Polymer Science, 2017, 35(12): 1457-1462.
DOI：

Jia-min Cao, Liu Qian, Dan He, et al. D-A Copolymers Based on a Pentacyclic Acceptor Unit and a 3, 3'-Difluoro-2, 2'-bithiophene for Solar Cells[J]. Chinese Journal of Polymer Science, 2017, 35(12): 1457-1462. DOI： 10.1007/s10118-017-1996-4.

摘要

Abstract

A D-A copolymer

P2FBTTPTI

was developed by copolymerizing a pentacyclic acceptor unit

thieno[2'

3':5

6]pyrido[3

]thieno[3

]isoquinoline-5

11(4

)-dione (TPTI)

with 3

3'-difluoro-2

2'-bithiophene (2FBT). P2FBTTPTI possessed a low highest occupied molecular orbital (HOMO) energy level (-5.50 eV) and a good hole mobility (4.14×10

-4

·V

-1

·s

-1

). P2FBTTPTI:PC

BM solar cells gave a decent power conversion efficiency (PCE) of 7.64% and a high open-circuit voltage (

) of 0.95 V.

关键词

Keywords

references

W. Zhao , S. Li , S. Zhang , X. Liu , J. Hou . Adv. Mater. , 2016 . DOI: 10.1002/adma.201604059 http://doi.org/10.1002/adma.201604059 .

F. Zhao , S. Dai , Y. Wu , Q. Zhang , J. Wang , L. Jiang , Q. Ling , Z. Wei , W. Ma , W. You , C. Wang , X. Zhan . Adv. Mater. , 2017 . DOI: 10.1002/adma.201700144 http://doi.org/10.1002/adma.201700144 .

J.S. Wu , S.W. Cheng , Y.J. Cheng , C.S. Hsu . Chem. Soc. Rev. , 2015 . 44 1113 DOI: 10.1039/C4CS00250D http://doi.org/10.1039/C4CS00250D .

X. Guo , A. Facchetti , T.J. Marks . Chem. Rev. , 2014 . 114 8943 DOI: 10.1021/cr500225d http://doi.org/10.1021/cr500225d .

H.Y. Chen , J. Hou , S. Zhang , Y. Liang , G. Yang , Y. Yang , L. Yu , Y. Wu , G. Li . Nat. Photon. , 2009 . 3 649 DOI: 10.1038/nphoton.2009.192 http://doi.org/10.1038/nphoton.2009.192 .

S.C. Price , A.C. Stuart , L. Yang , H. Zhou , W. You . J. Am. Chem. Soc. , 2011 . 133 4625 DOI: 10.1021/ja1112595 http://doi.org/10.1021/ja1112595 .

B. Carsten , J.M. Szarko , H.J. Son , W. Wang , L. Lu , F. He , B.S. Rolczynski , S.J. Lou , L.X. Chen , L. Yu . J. Am. Chem. Soc. , 2011 . 133 20468 DOI: 10.1021/ja208642b http://doi.org/10.1021/ja208642b .

J.W. Jo , J.W. Jung , H.W. Wang , P. Kim , T.P. Russell , W.H. Jo . Chem. Mater. , 2014 . 26 4214 DOI: 10.1021/cm502229k http://doi.org/10.1021/cm502229k .

Y. Liu , J. Zhao , Z. Li , C. Mu , W. Ma , H. Hu , K. Jiang , H. Lin , H. Ade , H. Yan . Nat. Commun. , 2014 . 5 5293 DOI: 10.1038/ncomms6293 http://doi.org/10.1038/ncomms6293 .

S. Zhang , Y. Qin , M.A. Uddin , B. Jang , W. Zhao , D. Liu , H.Y. Woo , J. Hou . Macromolecules , 2016 . 49 2993 DOI: 10.1021/acs.macromol.6b00248 http://doi.org/10.1021/acs.macromol.6b00248 .

Q. Fan , W. Su , X. Guo , B. Guo , W. Li , Y. Zhang , K. Wang , M. Zhang , Y. Li . Adv. Energy Mater. , 2016 . 6 1600430 DOI: 10.1002/aenm.201600430 http://doi.org/10.1002/aenm.201600430 .

N. Jiao , D. He , L. Qian , Z. Lei , L. Ding . Sci. China Chem. , 2017 . 60 251 DOI: 10.1007/s11426-016-0244-3 http://doi.org/10.1007/s11426-016-0244-3 .

J. Cao , Q. Liao , X. Du , J. Chen , Z. Xiao , Q. Zuo , L. Ding . Energy Environ. Sci. , 2013 . 6 3224 DOI: 10.1039/c3ee41948g http://doi.org/10.1039/c3ee41948g .

H. Li , J. Cao , Q. Zhou , L. Ding , J. Wang . Nano Energy , 2015 . 15 125 DOI: 10.1016/j.nanoen.2015.04.016 http://doi.org/10.1016/j.nanoen.2015.04.016 .

C. Zuo , J. Cao , L. Ding . Macromol. Rapid Commun. , 2014 . 35 1362 DOI: 10.1002/marc.v35.15 http://doi.org/10.1002/marc.v35.15 .

J. Cao , L. Qian , F. Lu , J. Zhang , Y. Feng , X. Qiu , H.L. Yip , L. Ding . Chem. Commun. , 2015 . 51 11830 DOI: 10.1039/C5CC03620H http://doi.org/10.1039/C5CC03620H .

H. Li , D. He , P. Mao , Y. Wei , L. Ding , J. Wang . Adv. Energy Mater. , 2017 . DOI: 10.1002/aenm.201602663 http://doi.org/10.1002/aenm.201602663 .

X. Du , O. Lytken , M.S. Killian , J. Cao , T. Stubhan , M. Turbiez , P. Schmuki , H.P. Steinrück , L. Ding , R.H. Fink , N. Li , C.J. Brabec . Adv. Energy Mater. , 2017 . 7 1601959 DOI: 10.1002/aenm.201601959 http://doi.org/10.1002/aenm.201601959 .

K. Zhang , K. Gao , R. Xia , Z. Wu , C. Sun , J. Cao , L. Qian , W. Li , S. Liu , F. Huang , X. Peng , L. Ding , H.L. Yip , Y. Cao . Adv. Mater. , 2016 . 28 4817 DOI: 10.1002/adma.v28.24 http://doi.org/10.1002/adma.v28.24 .

J. Cao , C. Zuo , B. Du , X. Qiu , L. Ding . Chem. Commun. , 2015 . 51 12122 DOI: 10.1039/C5CC04375A http://doi.org/10.1039/C5CC04375A .

L. Qian , J. Cao , L. Ding . J. Mater. Chem. A , 2015 . 3 24211 DOI: 10.1039/C5TA07942J http://doi.org/10.1039/C5TA07942J .

J. Cao , L. Qian , L. Ding . Polym. Chem. , 2016 . 7 1027 DOI: 10.1039/C5PY01761K http://doi.org/10.1039/C5PY01761K .

Y. Sun , J.H. Seo , C.J. Takacs , J. Seifter , A.J. Heeger . Adv. Mater. , 2011 . 23 1679 DOI: 10.1002/adma.201004301 http://doi.org/10.1002/adma.201004301 .

X. Xu , G. Zhang , Y. Zhao , J. Liu , Y. Li , Q. Peng . Chinese J. Polym. Sci. , 2017 . 35 ( 2 ): 249 DOI: 10.1007/s10118-017-1877-x http://doi.org/10.1007/s10118-017-1877-x .

A. Islam , Z. Liu , R. Peng , W. Jiang , T. Lei , W. Li , L. Zhang , R. Yang , Q. Guan , Z. Ge . Chinese J. Polym. Sci. , 2017 . 35 ( 2 ): 171 DOI: 10.1007/s10118-017-1886-9 http://doi.org/10.1007/s10118-017-1886-9 .

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