Synthesis and Characterization of Carborane-containing Poly(hydroxy ethers) with Excellent Thermal Stability

Zhen Yang; Ning Li; Xiao-xue Yang; Xiao-a Zhang; Sheng-ling Jiang; Ya-fei Lyu

doi:10.1007/s10118-017-1994-6

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Synthesis and Characterization of Carborane-containing Poly(hydroxy ethers) with Excellent Thermal Stability

Papers | Updated：2021-02-18

- Synthesis and Characterization of Carborane-containing Poly(hydroxy ethers) with Excellent Thermal Stability
- Chinese Journal of Polymer Science Vol. 35, Issue 12, Pages: 1463-1473(2017)
- Affiliations：
  
  a.Key Laboratory of Carbon Fiber and Functional Polymers of Ministry of Education, College of Materials Science and Engineering, Beijing University of Chemical Technology, Beijing 100029, China
  b.School of Chemical Engineering and Technology, Harbin Institute of Technology, Harbin 150001, China
- Author bio：
  
  Xiao-a Zhang (张孝阿), E-mail:zhangxiaoa1982@163.com
- Funds：
- DOI：10.1007/s10118-017-1994-6
  CLC：
- Received：07 May 2017，
  
  Revised：2017-06-06，
  
  Accepted：16 June 2017，
  
  Published：05 December 2017
- Accepted：
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Zhen Yang, Ning Li, Xiao-xue Yang, et al. Synthesis and Characterization of Carborane-containing Poly(hydroxy ethers) with Excellent Thermal Stability[J]. Chinese Journal of Polymer Science, 2017, 35(12): 1463-1473.
DOI：

Zhen Yang, Ning Li, Xiao-xue Yang, et al. Synthesis and Characterization of Carborane-containing Poly(hydroxy ethers) with Excellent Thermal Stability[J]. Chinese Journal of Polymer Science, 2017, 35(12): 1463-1473. DOI： 10.1007/s10118-017-1994-6.

摘要

Abstract

-Carborane-containing poly(hydroxy ethers) (

and

) were synthesized

via

"advancement reaction" of

-carborane-containing bisphenol (

) and diglycidyl ether of bisphenols (DGEBA and

). FTIR and

H-

C-

and

B-NMR were utilized to characterize the obtained polymers. TGA test was conducted under nitrogen and air. It is found that the shielding effect of carborane moiety on its adjacent aromatic structures contributes to high initial decomposition temperatures

while oxygen in air has an adverse effect on the initial decomposition temperature. The oxygen can combine with polymer chain to form peroxide and hydroperoxide groups

which are more reactive during the degradation process. Besides

o-carborane-containing poly(hydroxy ethers) have high char yield at elevated temperatures. The boron atom combines with oxygen from the polymer structure or/and from air

thus to form a three-dimensional network linked with B-O-B and B-C bonds

and retain the polymer weight to a large extent.

关键词

Keywords

references

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