Enhanced Crystallization Rate of Biodegradable Poly(<italic style="font-style: italic">ε</italic>-caprolactone) by Cyanuric Acid as an Efficient Nucleating Agent

Kang-jing Zhang; Zhao-bin Qiu

doi:10.1007/s10118-017-1993-7

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Enhanced Crystallization Rate of Biodegradable Poly(ε-caprolactone) by Cyanuric Acid as an Efficient Nucleating Agent

Papers | Updated：2021-02-18

- Enhanced Crystallization Rate of Biodegradable Poly(ε-caprolactone) by Cyanuric Acid as an Efficient Nucleating Agent
- Chinese Journal of Polymer Science Vol. 35, Issue 12, Pages: 1517-1523(2017)
- Affiliations：
  
  State Key Laboratory of Chemical Resource Engineering, Ministry of Education Key Laboratory of Carbon Fiber and Functional Polymers, Beijing University of Chemical Technology, Beijing 100029, China
- Author bio：
  
  Zhao-bin Qiu (邱兆斌), E-mail:qiuzb@mail.buct.edu.cn
- Funds：
- DOI：10.1007/s10118-017-1993-7
  CLC：
- Received：09 May 2017，
  
  Revised：2017-06-09，
  
  Accepted：13 June 2017，
  
  Published：2017-12
- Accepted：
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Kang-jing Zhang, Zhao-bin Qiu. Enhanced Crystallization Rate of Biodegradable Poly(ε-caprolactone) by Cyanuric Acid as an Efficient Nucleating Agent[J]. Chinese Journal of Polymer Science, 2017, 35(12): 1517-1523. DOI: 10.1007/s10118-017-1993-7.
DOI：

Kang-jing Zhang, Zhao-bin Qiu. Enhanced Crystallization Rate of Biodegradable Poly(ε-caprolactone) by Cyanuric Acid as an Efficient Nucleating Agent[J]. Chinese Journal of Polymer Science, 2017, 35(12): 1517-1523. DOI: 10.1007/s10118-017-1993-7. DOI：

摘要

Abstract

The influence of cyanuric acid (CA) as an efficient nucleating agent on the crystallization behavior and morphology of biodegradable poly(

-caprolactone) (PCL) was extensively studied in this work with several techniques for the first time. The nonisothermal melt crystallization behavior and overall isothermal melt crystallization rate of PCL were significantly enhanced by only a small amount of CA. The addition of CA apparently improved the nonisothermal melt crystallization peak temperature

overall isothermal melt crystallization rate

and nucleation density of PCL spherulites

but did not modify the crystallization mechanism and crystal structure of PCL

indicating that CA was an efficient nucleating agent for the crystallization of PCL. The possible nucleation mechanism of CA on the crystallization of PCL was also discussed on the basis of their crystal structures.

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Enhanced Crystallization Rate of Biodegradable Poly(ε-caprolactone) by Cyanuric Acid as an Efficient Nucleating Agent

DOI：10.1007/s10118-017-1993-7

摘要

Abstract

关键词

Keywords

references