Insights into Phthalonitrile/Epoxy Blends Modification System from Non-competitive Cure System Based on Alicyclic Anhydride

Jiang-bo Lv; Jing-zhi Ma; Kang Cheng; Chang Chen; Jiang-huai Hu; Ke Zeng; Gang Yang

doi:10.1007/s10118-017-1992-8

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Insights into Phthalonitrile/Epoxy Blends Modification System from Non-competitive Cure System Based on Alicyclic Anhydride

Papers | Updated：2021-02-18

- Insights into Phthalonitrile/Epoxy Blends Modification System from Non-competitive Cure System Based on Alicyclic Anhydride
- Chinese Journal of Polymer Science Vol. 35, Issue 12, Pages: 1561-1571(2017)
- Affiliations：
  
  State Key Laboratory of Polymer Materials Engineering, College of Polymer Science and Engineering, Sichuan University, Chengdu 610065, China
- Author bio：
  
  Ke Zeng (曾科), E-mail:zk_ican@sina.com
  Gang Yang (杨刚), E-mail:yanggang65420@163.com
- Funds：
- DOI：10.1007/s10118-017-1992-8
  CLC：
- Received：15 May 2017，
  
  Accepted：12 June 2017，
  
  Published：05 December 2017
- Accepted：
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Jiang-bo Lv, Jing-zhi Ma, Kang Cheng, et al. Insights into Phthalonitrile/Epoxy Blends Modification System from Non-competitive Cure System Based on Alicyclic Anhydride[J]. Chinese Journal of Polymer Science, 2017, 35(12): 1561-1571.
DOI：

Jiang-bo Lv, Jing-zhi Ma, Kang Cheng, et al. Insights into Phthalonitrile/Epoxy Blends Modification System from Non-competitive Cure System Based on Alicyclic Anhydride[J]. Chinese Journal of Polymer Science, 2017, 35(12): 1561-1571. DOI： 10.1007/s10118-017-1992-8.

摘要

Abstract

A series of polymer blends were prepared from 1

3-bis(3

4-dicyanophenoxy)benzene (3BOCN) and epoxy resin with methyl tetrahydrophthalic anhydride as curing agent. The curing behavior and curing kinetics of the blends were studied by differential scanning calorimetry. The apparent activation energy of the blends with various contents of 3BOCN was higher than that of the blends without 3BOCN. A model experiment suggested that there is no obvious reaction between phthalonitrile and epoxy. The thermal and mechanical properties of the polymer blends were evaluated. The polymer blends exhibit high storage modulus and char yield compared with the neat epoxy. The polymer blends show ductile fracture morphology by scanning electron microscopy (SEM) images.

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references

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