Rapid Shape Memory and pH-modulated Spontaneous Actuation of Dopamine Containing Hydrogels

Jie-xin Liao; Jia-he Huang; Tao Wang; Wei-xiang Sun; Zhen Tong

doi:10.1007/s10118-017-1991-9

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Rapid Shape Memory and pH-modulated Spontaneous Actuation of Dopamine Containing Hydrogels

Papers | Updated：2021-02-18

- Rapid Shape Memory and pH-modulated Spontaneous Actuation of Dopamine Containing Hydrogels
- Chinese Journal of Polymer Science Vol. 35, Issue 10, Pages: 1297-1306(2017)
- Affiliations：
  
  a.Research Institute of Materials Science, South China University of Technology, Guangzhou 510640, China
  b.State Key Laboratory of Luminescent Materials and Devices, South China University of Technology, Guangzhou 510640, China
- Author bio：
  
  Tao Wang (王涛), E-mail:fetwang@scut.edu.cn
  Zhen Tong (童真), E-mail:mcztong@scut.edu.cn
- Funds：
- DOI：10.1007/s10118-017-1991-9
  CLC：
- Received：26 April 2017，
  
  Revised：2017-5-30，
  
  Accepted：06 June 2017，
  
  Published：05 October 2017
- Accepted：
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Jie-xin Liao, Jia-he Huang, Tao Wang, et al. Rapid Shape Memory and pH-modulated Spontaneous Actuation of Dopamine Containing Hydrogels[J]. Chinese Journal of Polymer Science, 2017, 35(10): 1297-1306.
DOI：

Jie-xin Liao, Jia-he Huang, Tao Wang, et al. Rapid Shape Memory and pH-modulated Spontaneous Actuation of Dopamine Containing Hydrogels[J]. Chinese Journal of Polymer Science, 2017, 35(10): 1297-1306. DOI： 10.1007/s10118-017-1991-9.

摘要

Abstract

The dopamine containing hydrogels with rapid responsive shape memory capability were synthesized by a one-pot method. The temporary shape of hydrogel was fixed within 20 s in NaOH solution by the tris-complex crosslinking of metal-ligand complex between Fe

ions and catechol groups

while the permanent shape was recovered completely in HCl solution within 60 s upon the change from tris-complex to mono-complex. The hydrogel showed unique spontaneous actuation behavior. It could curl spontaneously without further external force deformation when immersed in NaOH solution again after the first shape recovery in HCl solution. This might be attributed to the competitive result of swelling and additional tris-complex crosslinking formation when immersed in NaOH solution. In addition

the hydrogels also had proper modulus

elongation ratio and tensile strength. Such hydrogel provides a new candidate material for designing soft actuators and robots modulated with spontaneous actuating.

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references

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