Study on Melting and Recrystallization of Poly(butylene succinate) Lamellar Crystals <italic style="font-style: italic">via</italic> Step Heating Differential Scanning Calorimetry

Zhi-yu Lv; Michael C. Zhang; Yang Zhang; Bao-hua Guo; Jun Xu

doi:10.1007/s10118-017-1986-6

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Study on Melting and Recrystallization of Poly(butylene succinate) Lamellar Crystals via Step Heating Differential Scanning Calorimetry

Papers | Updated：2021-02-18

- Study on Melting and Recrystallization of Poly(butylene succinate) Lamellar Crystals via Step Heating Differential Scanning Calorimetry
- Chinese Journal of Polymer Science Vol. 35, Issue 12, Pages: 1552-1560(2017)
- Affiliations：
  
  Key Laboratory of Advanced Materials(Ministry of Education), Department of Chemical Engineering, Tsinghua University, Beijing 100084, China
- Author bio：
  
  Jun Xu (徐军), E-mail:jun-xu@mail.tsinghua.edu.cn
- Funds：
- DOI：10.1007/s10118-017-1986-6
  CLC：
- Received：10 April 2017，
  
  Revised：2017-05-07，
  
  Accepted：17 May 2017，
  
  Published：05 December 2017
- Accepted：
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Zhi-yu Lv, Michael C. Zhang, Yang Zhang, et al. Study on Melting and Recrystallization of Poly(butylene succinate) Lamellar Crystals via Step Heating Differential Scanning Calorimetry[J]. Chinese Journal of Polymer Science, 2017, 35(12): 1552-1560. DOI: 10.1007/s10118-017-1986-6.
DOI：

Zhi-yu Lv, Michael C. Zhang, Yang Zhang, et al. Study on Melting and Recrystallization of Poly(butylene succinate) Lamellar Crystals via Step Heating Differential Scanning Calorimetry[J]. Chinese Journal of Polymer Science, 2017, 35(12): 1552-1560. DOI: 10.1007/s10118-017-1986-6. DOI：

摘要

Abstract

Differential scanning calorimetry (DSC) has been widely applied to study crystallization and melting of materials. However

for polymeric lamellar crystals

the melting thermogram during heating process usually exhibits a broad endothermic peak or even multiple endotherms

which may result from changes of metastability

via

recrystallization process. Sometimes

the recrystallization exotherm cannot be observed due to its overlapping with the melting endotherm. In this work

we employed a step heating procedure consisting of successive heating and temperature holding stages to measure the metastability of isothermally crystallized poly(butylene succinate) (PBS) crystals. With this approach we could gain the fraction of crystals melted at different temperature ranges and quantitatively detect the melting-recrystallization behavior. The melting-recrystallization behavior depends on the polymer chain structure and the crystallization temperature. For instance

PBS block copolymer hardly shows recrystallization behavior while PBS oligomer and high molecular weight PBS homopolymer demonstrate remarkable melting-recrystallization phenomenon. High molecular weight PBS isothermally crystallized in the low temperature range shows multiple melting-recrystallization while those isothermally crystallized at elevated temperatures do not exhibit observable recrystallization behavior. Furthermore

the melting endotherms were fitted

via

the melting kinetics equations. The original isothermally crystallized lamellae demonstrate quite different melting kinetics from the recrystallized lamellar crystals that melt at the highest temperature range

which is attributed to the different degrees of stabilization. Finally

the mechanism of melting-recrystallization is briefly discussed. We propose that apparent melt-recrystallization phenomenon be observed when melting of preformed lamellar crystals and recrystallization of thicker lamellae have similar free energy barrier.

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Study on Melting and Recrystallization of Poly(butylene succinate) Lamellar Crystals via Step Heating Differential Scanning Calorimetry

DOI：10.1007/s10118-017-1986-6

摘要

Abstract

关键词

Keywords

references