

FOLLOWUS
College of Polymer Science and Engineering, State Key Laboratory of Polymer Materials Engineering, Sichuan University, Chengdu 610065, China
Feng Chen (陈枫), E-mail:fengchen@scu.edu.cn
Qiang Fu (傅强), E-mail:qiangfu@scu.edu.cn
Received:13 April 2017,
Revised:2017-05-15,
Accepted:26 May 2017,
Published:05 December 2017
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Yi-lan Guo, Run-zhi Zhang, Kai Wu, et al. Preparation of Nylon MXD6/EG/CNTs Ternary Composites with Excellent Thermal Conductivity and Electromagnetic Interference Shielding Effectiveness[J]. Chinese Journal of Polymer Science, 2017, 35(12): 1497-1507.
Yi-lan Guo, Run-zhi Zhang, Kai Wu, et al. Preparation of Nylon MXD6/EG/CNTs Ternary Composites with Excellent Thermal Conductivity and Electromagnetic Interference Shielding Effectiveness[J]. Chinese Journal of Polymer Science, 2017, 35(12): 1497-1507. DOI: 10.1007/s10118-017-1985-7.
In this article
hybrid fillers with different dimensions
namely
2-dimensional (2-D) expanded graphite (EG) and 1-dimensional (1-D) multi-walled carbon nanotubes (CNTs)
were added to aromatic nylon MXD6 matrix
via
melt-blending
to enhance its thermal and electrical conductivity as well as electromagnetic interference shielding effectiveness (EMI SE). For ternary composites of MXD6/EG/CNTs
the electrical conductivity reaches up nine orders of magnitude higher compared to that of the neat MXD6 sample
which turned the polymer-based composites from an insulator to a conductor
and the thermal conductivity has been enhanced by 477% compared with that of neat MXD6 sample. Meanwhile
the EMI SE of ternary composite reaches~50 dB at the overall filler loading of only 18 wt%. This work can provide guidance for the preparation of polymer composites with excellent thermal and electrical conductivity
via
using hybrid filler.
Levy, S., "Electromagnetic shielding effect of an infinite plane conducting sheet placed between circular coaxial coils", Institute of Radio Engineers, 1936, p. 923 http://ieeexplore.ieee.org/xpl/articleDetails.jsp?arnumber=1686176&sortType%3Dasc_p_Sequence%26filter%3DAND(p_IS_Number%3A35528)
K.J. Ji , H.H. Zhao , J. Zhang , J. Chen , Z.D. Dai . Appl. Surf. Sci. , 2014 . 311 351 DOI: 10.1016/j.apsusc.2014.05.067 http://doi.org/10.1016/j.apsusc.2014.05.067 .
Y.L. He , Y.L. Guo , R. He , T.X. Jin , F. Chen , Q. Fu , N. Zhou , J. Shen . Chinese J. Polym. Sci. , 2015 . 33 ( 8 ): 1176 DOI: 10.1007/s10118-015-1667-2 http://doi.org/10.1007/s10118-015-1667-2 .
B. Su , Y.S. Zhao , F. Chen , Q. Fu . Chinese J. Polym. Sci. , 2015 . 33 ( 7 ): 964 DOI: 10.1007/s10118-015-1649-4 http://doi.org/10.1007/s10118-015-1649-4 .
S. Deng , X.D. Qi , Y.L. Zhu , H.J. Zhou , F. Chen , Q. Fu . Chinese J. Polym. Sci. , 2016 . 34 ( 10 ): 1270 DOI: 10.1007/s10118-016-1836-y http://doi.org/10.1007/s10118-016-1836-y .
Rosato, D. V., "Plastics processing data handbook", Springer Science & Business Media, 2012, p. 32
K. Zhang , Y. Chai , M. Yuen , D. Xiao , P. Chan . IOP science , 2008 . 19 1 .
X.P. Zeng , J.J. Yang , W.X. Yuan . Eur. Polym. J. , 2012 . 48 ( 10 ): 1674 DOI: 10.1016/j.eurpolymj.2012.07.011 http://doi.org/10.1016/j.eurpolymj.2012.07.011 .
W.Y. Tu , H.Y. Zhang , H.Q. Hong , X.B. Zhang . Plastics , 2012 . 41 ( 5 ): 73 .
J. Chen , X.C. Du , W.B. Zhang , J.H. Yang , N. Zhang , T. Huang , Y. Wang . Compos. Sci. Technol. , 2013 . 81 1 DOI: 10.1016/j.compscitech.2013.03.014 http://doi.org/10.1016/j.compscitech.2013.03.014 .
C.H. Cui , D.X. Yan , H. Pang , L.C. Jia , Y. Bao , X. Jiang , Z.M. Li . Chinese J. Polym. Sci. , 2016 . 34 ( 12 ): 1490 DOI: 10.1007/s10118-016-1849-6 http://doi.org/10.1007/s10118-016-1849-6 .
H. Im , J. Kim . Carbon , 2012 . 50 ( 15 ): 5429 DOI: 10.1016/j.carbon.2012.07.029 http://doi.org/10.1016/j.carbon.2012.07.029 .
Y.J. Xiao , W.Y. Wang , T. Lin , X.J. Chen , Y.T. Zhang , J.H. Yang , Y. Wang , Z.W. Zhou . J. Phys. Chem. C , 2016 . 120 ( 12 ): 6344 DOI: 10.1021/acs.jpcc.5b12651 http://doi.org/10.1021/acs.jpcc.5b12651 .
W.B. Zhang , Z.X. Zhang , J.H. Yang , T. Huang , N. Zhang , X.T. Zheng , Y. Wang , Z.W. Zhou . Carbon , 2015 . 90 242 DOI: 10.1016/j.carbon.2015.04.040 http://doi.org/10.1016/j.carbon.2015.04.040 .
K. Wu , Y. Xue , W.X. Yang , S.G. Chai , F. Chen , Q. Fu . Compos. Sci. Technol , 2016 . 130 28 DOI: 10.1016/j.compscitech.2016.04.034 http://doi.org/10.1016/j.compscitech.2016.04.034 .
X.L. Cui , P. Ding , N. Zhuang , L.Y. Shi , N. Song , S.F. Tang . ACS Appl. Mater. Interfaces , 2015 . 7 ( 34 ): 19068 DOI: 10.1021/acsami.5b04444 http://doi.org/10.1021/acsami.5b04444 .
A. Celzard , J. Mareche , G. Furdin . Prog. Mater. Sci. , 2005 . 50 ( 1 ): 93 DOI: 10.1016/j.pmatsci.2004.01.001 http://doi.org/10.1016/j.pmatsci.2004.01.001 .
N. Moshe , L. Gershon , V. Anita , Z. Limor . J. Electrostat. , 1999 . 47 201 DOI: 10.1016/S0304-3886(99)00041-8 http://doi.org/10.1016/S0304-3886(99)00041-8 .
H. Deng , T. Skipa , E. Bilotti , R. Zhang , D. Lellinger , L. Mezzo , Q. Fu , I. Alig , T. Peijs . Adv. Funct. Mater. , 2010 . 20 ( 9 ): 1424 DOI: 10.1002/adfm.200902207 http://doi.org/10.1002/adfm.200902207 .
R. Rohini , S. Bose . ACS Appl. Mater. Interfaces , 2014 . 6 ( 14 ): 11302 DOI: 10.1021/am502641h http://doi.org/10.1021/am502641h .
S. Maiti , N.K. Shrivastava , S. Suin , B.B. Khatua . ACS Appl. Mater. Interfaces , 2013 . 5 ( 11 ): 4712 DOI: 10.1021/am400658h http://doi.org/10.1021/am400658h .
K. Yang , M.Y. Gu . Compos. Part A-Appl. S. , 2010 . 41 ( 2 ): 215 DOI: 10.1016/j.compositesa.2009.10.019 http://doi.org/10.1016/j.compositesa.2009.10.019 .
J.W. Tang , F. Wu , M.Y. Li . Plastic Packaging , 2008 . 18 ( 2 ): 47 .
Y.Q. Wang . Modern Plastics Processing, Applications , 1997 . 9 ( 3 ): 43 .
C. Thellen , S. Schirmer , J.A. Ratto , B. Finnigan , D. Schmidt . J. Membr. Sci. , 2009 . 340 ( 1-2 ): 45 DOI: 10.1016/j.memsci.2009.05.011 http://doi.org/10.1016/j.memsci.2009.05.011 .
Z.B. Bao , J. Wang , J. Pan , W.B. Xu . Engineering Plastics Application , 2013 . 41 ( 4 ): 67 .
B.Y. Zhang , Q.S. Ge , Z.X. Guo , J. Yu . Chinese J. Polym. Sci. , 2016 . 34 ( 8 ): 1032 DOI: 10.1007/s10118-016-1821-5 http://doi.org/10.1007/s10118-016-1821-5 .
M. Fereydoon , H.S. Tabatabaei , A. Ajji . Macromolecules , 2014 . 47 ( 7 ): 2384 DOI: 10.1021/ma402466c http://doi.org/10.1021/ma402466c .
D.C. Working , J.W. Connell , J.J.G. Smith , K.A. Watson , D.M. Delozier , Y.P. Sun , Y. Lin . High Perform. Polym. , 2006 . 961 .
K. Kalaitzidou , H. Fukushima , P. Askeland , L.T. Drzal . J. Mater. Sci. , 2007 . 43 ( 8 ): 2895 .
Balandin, A. A., "Thermal Properties of Graphene, Carbon Nanotubes and Nanostructured Carbon Materials", Thesis, University of California, 2011 http://arxiv.org/abs/1106.3789
A.P. Yu , P. Ramesh , M.E. Itkis , E. Bekyarova , R.C. Haddon . J. Phys. Chem. C , 2007 . 111 7565 DOI: 10.1021/jp071761s http://doi.org/10.1021/jp071761s .
H. Fukushima , L.T. Drzal , B.P. Rook , M.J. Rich . J. Therm. Anal. Calorim. , 2006 . 85 235 DOI: 10.1007/s10973-005-7344-x http://doi.org/10.1007/s10973-005-7344-x .
L.M. Veca , M.J. Meziani , W. Wang , X. Wang , F.S. Lu , P.Y. Zhang , Y. Lin , R. Fee , J.W. Connell , Y.P. Sun . Adv. Mater. , 2009 . 21 ( 20 ): 2088 DOI: 10.1002/adma.v21:20 http://doi.org/10.1002/adma.v21:20 .
M. Arjmand , T. Apperley , M. Okoniewski , U. Sundararaj . Carbon , 2012 . 50 ( 14 ): 5126 DOI: 10.1016/j.carbon.2012.06.053 http://doi.org/10.1016/j.carbon.2012.06.053 .
K. Ayesha . Chinese J. Polym. Sci. , 2013 . 32 ( 1 ): 64 .
H.D. Bao , Z.X. Guo , J. Yu . Chinese J. Polym. Sci. , 2009 . 27 ( 3 ): 393 DOI: 10.1142/S0256767909004059 http://doi.org/10.1142/S0256767909004059 .
K. Zhang , Y. Chai , M.M. Yuen , D.G. Xiao , P.C. Chan . Nanotechnology , 2008 . 19 ( 21 ): 215706 DOI: 10.1088/0957-4484/19/21/215706 http://doi.org/10.1088/0957-4484/19/21/215706 .
S.T. Zhou , Y. Chen , H.W. Zou , M. Liang . Thermochim. Acta , 2013 . 566 84 DOI: 10.1016/j.tca.2013.05.027 http://doi.org/10.1016/j.tca.2013.05.027 .
J.A. Heiser , J.A. King . Polym. Compos. , 2004 . 25 ( 2 ): 186 DOI: 10.1002/(ISSN)1548-0569 http://doi.org/10.1002/(ISSN)1548-0569 .
X.L. Yan , Y. Imai , D. Shimamoto , Y. Hotta . Polymer , 2014 . 55 ( 23 ): 6186 DOI: 10.1016/j.polymer.2014.09.052 http://doi.org/10.1016/j.polymer.2014.09.052 .
Y. Yoo , H.L. Lee , S.M. Ha , B.K. Jeon , J.C. Won , S.G. Lee . Polym. Int. , 2014 . 63 ( 1 ): 151 DOI: 10.1002/pi.2014.63.issue-1 http://doi.org/10.1002/pi.2014.63.issue-1 .
J. Joo , A.J. Epstein . Appl. Phys. Lett. , 1994 . 65 ( 18 ): 2278 DOI: 10.1063/1.112717 http://doi.org/10.1063/1.112717 .
N.F. Colaneri , L.W. Shacklette . IEEE T Instrum. Meas. , 1992 . 41 291 DOI: 10.1109/19.137363 http://doi.org/10.1109/19.137363 .
C.Z. Geng , X. Hu , G.H. Yang , Q. Zhang , F. Chen , Q. Fu . Chinese J. Polym. Sci. , 2014 . 33 ( 1 ): 61 .
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