Single-material Solvent-sensitive Fluorescent Actuator from Carbon Dots Inverse Opals Based on Gradient Dewetting

Jun-chao Liu; Yuan-yuan Shang; Da-jie Zhang; Zheng Xie; Rui-xiang Hu; Jing-xia Wang

doi:10.1007/s10118-017-1981-y

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Single-material Solvent-sensitive Fluorescent Actuator from Carbon Dots Inverse Opals Based on Gradient Dewetting

Rapid Communication | Updated：2021-02-18

- Single-material Solvent-sensitive Fluorescent Actuator from Carbon Dots Inverse Opals Based on Gradient Dewetting
- Chinese Journal of Polymer Science Vol. 35, Issue 9, Pages: 1043-1050(2017)
- Affiliations：
  
  a.College of Chemistry and Chemical Engineering, Hunan Normal University, Changsha 410081, China
  b.Key Laboratory of Bio-inspired Materials and Interface Sciences, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, China
  c.Laboratory of Bioinspired materials, School of Future Technology, University of Chinese Academy of Sciences, Beijing 100049, China
- Author bio：
  
  Rui-xiang Hu (胡瑞祥), E-mail:hurx@hunnu.edu.cn
  Jing-xia Wang (王京霞), E-mail:jingxiawang@mail.ipc.ac.cn
- Funds：
- DOI：10.1007/s10118-017-1981-y
  CLC：
- Received：10 April 2017，
  
  Revised：2017-5-11，
  
  Accepted：17 May 2017，
  
  Published：05 September 2017
- Accepted：
Scan QR Code
Jun-chao Liu, Yuan-yuan Shang, Da-jie Zhang, et al. Single-material Solvent-sensitive Fluorescent Actuator from Carbon Dots Inverse Opals Based on Gradient Dewetting[J]. Chinese Journal of Polymer Science, 2017, 35(9): 1043-1050.
DOI：

Jun-chao Liu, Yuan-yuan Shang, Da-jie Zhang, et al. Single-material Solvent-sensitive Fluorescent Actuator from Carbon Dots Inverse Opals Based on Gradient Dewetting[J]. Chinese Journal of Polymer Science, 2017, 35(9): 1043-1050. DOI： 10.1007/s10118-017-1981-y.

摘要

Abstract

A novel solvent-sensitive fluorescent actuator with reversibility has been obtained from carbon dots (CDs) inverse opals

which is prepared

via

infiltrating CDs solution into the interstice of colloidal crystal template

thermal polymerization of CDs materials and removing the colloidal template. The as-prepared CDs inverse opal actuator shows a bending angle of 75° in 10.2 s

bending rate of 7.35 (°)·s

-1

. In particular

the fluorescence intensity of the films varies during the actuating process. The actuating behavior is attributed to the inhomogeneous swelling/shrinking of the film

which originates from the gradient dewetting by solvent evaporation and hydrogen-bonding interaction between the solvent molecules and oxygen/hydrogen ions of CDs side chain. The CDs inverse opal actuator has the advantages of quick response

good repeatability and strong fluorescence

which gives an important insight into the design and manufacture of novel and advanced solvent-actuators.

关键词

Keywords

references

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